摘要:
A fuel, an oxidant, and a diluent can be introduced to a combustion zone, wherein the oxidant comprises air, oxygen-enriched air, or oxygen-lean air. At least a portion of the fuel can be combusted to produce an exhaust gas comprising, nitrogen, nitrogen oxides, and carbon monoxide. The exhaust gas can be expanded to produce mechanical power and an expanded exhaust gas. A concentration of at least one of oxygen, hydrogen, nitrogen oxides and carbon monoxide, in the exhaust gas or the expanded exhaust gas or both can be determined, and an amount of the oxidant or the fuel introduced to the combustion zone, or both, can be adjusted based on the determined concentration to produce an exhaust gas containing a combined amount of oxygen and carbon monoxide of less than about 2 mol % and a nitrogen concentration ranging from 20 mol % to 75 mol %. The diluent to the combustion zone can include at least a portion of the exhaust gas containing a combined amount of oxygen and carbon monoxide of less than 2 mol % and a nitrogen concentration ranging from 20 mol % to 75 mol %.
摘要:
Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant derived from enriched air and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a recycle exhaust stream and drive a main compressor. A boost compressor receives and increases the pressure of the recycle exhaust stream and prior to being compressed in a compressor configured to generate the compressed recycle exhaust gas. To promote the stoichiometric combustion of the fuel and increase the CO2 content in the recycle exhaust gas, the enriched air can have an increased oxygen concentration.
摘要:
Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant derived from enriched air and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a recycle exhaust stream and drive a main compressor. A boost compressor receives and increases the pressure of the recycle exhaust stream and prior to being compressed in a compressor configured to generate the compressed recycle exhaust gas. To promote the stoichiometric combustion of the fuel and increase the CO2 content in the recycle exhaust gas, the enriched air can have an increased oxygen concentration.
摘要:
Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a gaseous exhaust stream and drive a main compressor. A boost compressor can receive and increase the pressure of the gaseous exhaust stream and inject it into an evaporative cooling tower configured to use an exhaust nitrogen gas having a low relative humidity as an evaporative cooling media. The cooled gaseous exhaust stream is then compressed and recirculated through the system as a diluent to moderate the temperature of the stoichiometric combustion.
摘要:
Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes a gas turbine system configured to stoichiometrically combust a compressed oxidant and a fuel in the presence of a compressed recycle exhaust gas and expand the discharge in an expander to generate a gaseous exhaust stream and drive a main compressor. A boost compressor can receive and increase the pressure of the gaseous exhaust stream and inject it into an evaporative cooling tower configured to use an exhaust nitrogen gas having a low relative humidity as an evaporative cooling media. The cooled gaseous exhaust stream is then compressed and recirculated through the system as a diluent to moderate the temperature of the stoichiometric combustion.
摘要:
Methods and systems for enhanced carbon dioxide capture in a combined cycle plant are described. A method includes compressing a recycle exhaust gas from a gas turbine system, thereby producing a compressed recycle exhaust gas stream. A purge stream is extracted from the compressed recycle exhaust gas stream. Carbon dioxide is removed from the extracted purge stream using a solid sorbent.
摘要:
Systems and methods are provided for processing a heavy oil feed, such as an atmospheric or vacuum resid, using a combination of solvent assisted hydroprocessing and slurry hydroconversion of a heavy oil feed. The systems and methods allow for conversion and desulfurization/denitrogenation of a feed to form fuels and gas oil (or lubricant base oil) boiling range fractions while reducing the portion of the teed that is exposed to the high severity conditions present in slurry hydroconversion.
摘要:
The present invention provides a high capacity adsorbent for removing sulfur from hydrocarbon streams. The adsorbent comprises a composite material containing particles of a nickel phosphide complex NixP. The adsorbent is utilized in a sulfur removal process that does not require added hydrogen, and run at relatively low temperatures ranging from about 150° C. to about 400° C. The process of this invention enables “ultra-deep” desulfurization down to levels of about 1 ppm and less.
摘要:
A reaction-based process developed for the selective removal of CO2 from a multicomponent gas mixture to provide a gaseous stream depleted in CO2 compared to the inlet CO2 concentration. The proposed process effects the separation of CO2 from a mixture of gases by its reaction with metal oxides. The Calcium based Reaction Separation for CO2 (CaRS-CO2) process consists of contacting CO2 laden gas with CaO in a reactor such that CaO captures CO2 by the formation of CaCO3. CaCO3 is regenerated by calcination leading to the formation of fresh CaO sorbent and the evolution of a concentrated stream of CO2. The “regenerated” CaO is then recycled for the further capture of CO2. This carbonation-calcination cycle forms the basis of the CaRS-CO2 process. This process also may use a mesoporous CaCO3 structure that attains >90% conversion over multiple carbonation and calcination cycles.