摘要:
A curable silicone composition comprising:(A) an alkenyl group-containing organopolysiloxane containing silicon-bonded alkenyl groups and a silicon-bonded fluorine-containing substituent having the general formula (1):Rf--O--Y-- (1) wherein Rf is a perfluoroalkenyl group having 5 to 10 carbon atoms, and Y represents a divalent organic group,(B) an organohydrogenpolysiloxane, and(C) a catalyst for addition reaction between components (A) and (B). This composition can form a cured coating which adheres firmly to various substrates and has good release properties, stability in the release properties, water- and oil-repellency, and solvent resistance. The coating exhibits good release properties even against pressure sensitive adhesives comprising a dimetylpolysiloxane.
摘要:
A purification method of a fluorine-containing alkylethylene comprises reacting the fluorine-containing alkylethylene with powdered metallic zinc in the presence of an aqueous acetic acid solution. By this method, fluorine-containing alkyl iodide and fluorine-containing alkylethyl iodide, contained as impurities in the fluorine-containing alkylethylene, can be removed effectively, for example, to a level of 1 ppm or below.
摘要:
The synthesis and use of a fluorine-containing organic silicon compound represented by: ##STR1## wherein each R.sup.1 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms, and each R.sup.2 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms or a CH.sub.2 CH.sub.2 Rf group, such that at least one R.sup.2 is CH.sub.2 CH.sub.2 Rf, wherein Rf is a perfluoroalkyl group of 1-10 carbon atoms; the compounds of formula (I) are useful in the preparation of fluorine-containing polysilethylenesiloxanes having excellent solvent-resisting and surface-lubricating properties.
摘要:
A fluorine containing organosilicon compound represented by the following general formula: ##STR1## wherein R represents an alkyl group or an aryl group, a is an integer of 1 to 7, b is an integer of 2 to 8, and c is an integer of 1 to 3. This compound is useful as a surface treating agent for silicas, an adhesive improver for resists, an oil or water-repellent treating agent, and a raw material for synthesis of various silicone compounds.
摘要:
The present compound is a novel perfluoropolyether represented by the following general formula: ##STR1## wherein m is an integer of 1 to 3 and n is an integer of 2 to 6. This compound is quite useful as an inert liquid used as a heat transfer mediums in the filed of electronic materials.
摘要:
A curable silicone composition comprising as a basic component an organopolysiloxane having at least two silicon-bonded alkenyl groups, a silicon-bonded fluorine-containing substituent of the formula (I): ##STR1## wherein m is an integer of from 1 to 4, and n is an integer of from 1 to 6, and/or the formula (II): ##STR2## wherein m and n are as defined above, and at least one silicon-bonded fluorine-containing substituent of the formula (III):C.sub.l F.sub.2l+1 (CH.sub.2).sub.k -- (III)wherein k is an integer of from 1 to 4, and l is an integer of from 1 to 10, and/or the formula (IV):C.sub.l F.sub.2l+1 --(--CH.sub.2 --).sub.k --O--(--CH.sub.2 --).sub.m --(IV)wherein k, l and m are as defined above, and further comprising an organohydrogenpolysiloxane, and a platinum family metal catalyst. This composition can form a coating film having a low surface energy and therefore having good release properties, etc.
摘要:
The fluorine-containing organosilicon compound of the present invention is represented by the following formula: ##STR1## wherein Rf is a perfluoroalkyl group. This compound is quite useful as a raw material for the production of polysilethylenesiloxanes excellent in solvent resistance.
摘要:
The present polysilethylenesiloxane is a liquid polymer represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 each represent a lower alkyl group and R.sup.3 and R.sup.4 each represent a perfluoroalkylethyl group, and n is an integer of 10 to 1,000. This polymer is quite useful as a major component of elastomer compositions having chemical resistance, electrical properties, and high strength.
摘要:
Fluorinated cyclic organic silicon compounds of the general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are independently selected from alkyl groups having 1 to 6 carbon atoms and n is an integer of from 1 to 6 are novel and susceptible to ring-opening polymerization to form chain siloxane polymers having improved properties. The cyclic compounds are produced by reacting disiloxane diols with fluorinated organic silicon compounds in the presence of amine catalysts.
摘要:
A novel perfluoropolyether-modified aminosilane cures into a film having improved water and oil repellency, parting and anti-staining properties. A surface treating agent comprising the aminosilane, and an article with a coating of the aminosilane are also provided.