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公开(公告)号：US5300613A
公开(公告)日：1994-04-05
申请号：US69847
申请日：1993-06-01
申请人： Hirofumi Kishita , Shinichi Sato , Takashi Matsuda
发明人： Hirofumi Kishita , Shinichi Sato , Takashi Matsuda
CPC分类号： C07F7/0854 , C07F7/21
摘要： Fluorine-containing organosilicon compounds having the following general formula:CH.sub.2 .dbd.CHCH.sub.2 NHCO--[Rf--CONH(CH.sub.2).sub.3 --Q--(CH.sub.2).sub.3 NHCO].sub.a --Rf--CONHCH.sub.2 CH .dbd.CH.sub.2wherein a is an integer of 1 or above, Rf is a divalent perfluoropolyether group, and Rf is a divalent cyclosiloxane group containing an unsubstituted or substituted monovalent hydrocarbon group without an aliphatically unsaturated bond. The compounds are of use as a starting material in synthesizing rubbers or mold release agents which are high in such properties as solvent resistance, chemical resistance and the like.
摘要翻译： 具有以下通式的含氟有机硅化合物：CH 2 = CHCH 2 NHCO-（R f-CONH（CH 2）3-Q-（CH 2）3 NHCO）a-R f -CONHCH 2 CH = CH 2其中a为1或更高的整数，Rf为 二价全氟聚醚基，Rf是含有未被取代或取代的没有脂族不饱和键的一价烃基的二价环硅氧烷基团。 该化合物可用作合成橡胶或脱模剂的原料，其具有耐溶剂性，耐化学性等特性。
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公开(公告)号：US5117026A
公开(公告)日：1992-05-26
申请号：US723980
申请日：1991-07-01
申请人： Hirofumi Kishita , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito , Shinichi Sato , Kenichi Fukuda , Nobuyuki Kobayashi
发明人： Hirofumi Kishita , Kouichi Yamaguchi , Hideki Fujii , Shuji Suganuma , Yoshikazu Saito , Shinichi Sato , Kenichi Fukuda , Nobuyuki Kobayashi
IPC分类号： C07F7/12
CPC分类号： C07F7/12
摘要： The synthesis and use of a fluorine-containing organic silicon compound represented by: ##STR1## wherein each R.sup.1 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms, and each R.sup.2 independently represents a monovalent hydrocarbon group of 1-10 carbon atoms or a CH.sub.2 CH.sub.2 Rf group, such that at least one R.sup.2 is CH.sub.2 CH.sub.2 Rf, wherein Rf is a perfluoroalkyl group of 1-10 carbon atoms; the compounds of formula (I) are useful in the preparation of fluorine-containing polysilethylenesiloxanes having excellent solvent-resisting and surface-lubricating properties.
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公开(公告)号：US5817746A
公开(公告)日：1998-10-06
申请号：US940965
申请日：1997-09-30
CPC分类号： C08G65/226
摘要： In polymerizing hexafluoropropene oxide (HFPO) into a fluorinated polyether, a liquefied gas of fluorocarbon having 1 to 4 carbon atoms is added to a reactor. HFPO is polymerized in the reactor while maintaining a gas phase in the reactor under a pressure lower than the vapor pressure of the liquefied gas and allowing the liquefied gas to evaporate from the polymerization system. Heat of polymerization can be efficiently removed from the HFPO polymerization system of high viscosity, and the polymerization temperature is kept low.
摘要翻译： 在将六氟丙烯氧化物（HFPO）聚合成氟化聚醚的过程中，将碳氟化碳碳氢化合物的液化气体加入到反应器中。 将HFPO在反应器中聚合，同时在低于液化气体的蒸汽压力的压力下保持反应器中的气相，并允许液化气体从聚合系统蒸发。 可以从高粘度的HFPO聚合体系中有效地除去聚合热，聚合温度保持不变。
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公开(公告)号：US5177131A
公开(公告)日：1993-01-05
申请号：US727120
申请日：1991-07-09
申请人： Toshio Takago , Hiroshi Inomata , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Koichi Yamaguchi , Takashi Matsuda , Hirokazu Yamada
发明人： Toshio Takago , Hiroshi Inomata , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Koichi Yamaguchi , Takashi Matsuda , Hirokazu Yamada
CPC分类号： B01D69/148 , B01D67/0048 , C08K5/0008 , C08L83/14 , B01D2323/08 , B01D2323/12 , B01D2325/30 , B01D71/027 , B01D71/70 , Y10S528/901
摘要： The present room temperature curing composition comprises an organopolysilethylenesiloxane represented by the following general formula: ##STR1## wherein R.sup.1 to R.sup.4 each represent an alkyl having up to 8 carbon atoms or a phenyl group and n is an integer of 10 or above, and an organosilane or an organosiloxane having two or more hydrolyzable groups such as alkoxy groups in the molecule. The composition can form a cured product high in rubber strength and excellent in chemical resistance.
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5.发明授权Perfluoropolyether rubber composition and ion-conducting polymer electrolyte membrane 有权全氟聚醚橡胶组合物和离子导电高分子电解质膜公开(公告)号：US07838616B2
公开(公告)日：2010-11-23
申请号：US11924181
申请日：2007-10-25
IPC分类号： C08G77/12
CPC分类号： C08L71/02 , C08G65/007 , C08G2650/48 , C08J5/2275 , C08J5/2281 , C08J2371/02 , C08J2383/08 , H01M8/1027 , H01M8/103 , H01M8/1037 , H01M8/1039 , H01M8/1072 , Y02P70/56 , C08L83/00
摘要： A perfluoropolyether rubber composition is useful for forming a polymer electrolyte membrane, comprising (A) an alkenyl-containing perfluoropolyether, (B) a silicon-oxygen crosslinked structure having ionic conduction, and (C) a peroxide crosslinker. The silicon-oxygen crosslinked structure is obtained by simultaneously effecting oxidation and hydrolysis on an organoxysilane having an epoxy group and an organoxysilane having a mercapto group for thereby converting the mercapto group into a sulfonic group, and neutralizing the resulting sulfonic group-containing siloxane with a nitrogen-containing compound.
摘要翻译： 全氟聚醚橡胶组合物可用于形成聚合物电解质膜，其包含（A）含烯基的全氟聚醚，（B）具有离子导电性的硅 - 氧交联结构和（C）过氧化物交联剂。 通过在具有环氧基的有机氧基硅烷和具有巯基的有机氧基硅烷上同时进行氧化和水解，从而将巯基转化为磺酸基，并将所得的含磺酸基的硅氧烷中和，得到硅 - 氧交联结构 含氮化合物。
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公开(公告)号：US20100272910A1
公开(公告)日：2010-10-28
申请号：US12765343
申请日：2010-04-22
申请人： Hirofumi KISHITA , Shinichi Sato
发明人： Hirofumi KISHITA , Shinichi Sato
CPC分类号： C09D183/04 , C09D5/165
摘要： A coating composition comprising (A) a hydroxyl end-capped diorganopolysiloxane, (B) an organosilicon compound having at least three silicon-bonded hydrolyzable groups in a molecule, and (C) a perfluoropolyether compound having a perfluoropolyether group at one end and a hydrolyzable group at the other end is effective for preventing fouling of a substrate in a marine environment.
摘要翻译： 一种涂料组合物，其包含（A）羟基封端的二有机聚硅氧烷，（B）分子中具有至少三个与硅键合的可水解基团的有机硅化合物，和（C）在一端具有全氟聚醚基团的全氟聚醚化合物和可水解的 在另一端的组对于防止海洋环境中的基底的结垢是有效的。
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公开(公告)号：US5420189A
公开(公告)日：1995-05-30
申请号：US205115
申请日：1994-03-03
申请人： Hirofumi Kishita , Kouichi Yamaguchi , Takashi Matsuda , Kenichi Fukuda , Nobuyuki Kobayashi , Shinichi Sato , Hitoshi Kinami
发明人： Hirofumi Kishita , Kouichi Yamaguchi , Takashi Matsuda , Kenichi Fukuda , Nobuyuki Kobayashi , Shinichi Sato , Hitoshi Kinami
IPC分类号： C08L83/05 , C08K5/549 , C08L83/04 , C08L83/07 , C08L83/08 , C08L83/12 , C09D183/04 , C09D183/08 , C09J183/00 , C09J183/08 , C08G77/08
CPC分类号： C08L83/08 , C09D183/08
摘要： An organopolysiloxane composition comprising (A) a linear, alkenyl-containing, fluorinated organopolysiloxane, (B) a cyclic fluorinated organosiloxane as a tackifier, (C) an organohydrogenpolysiloxane having at least two hydrogen atoms attached to a silicon atom in a molecule, and (D) a platinum group metal catalyst has excellent properties inherent to fluorinated silicone rubber, and cures into products having adhesion and close contact to various materials including metals, glass and resins.
摘要翻译： 一种有机聚硅氧烷组合物，其包含（A）直链，含链烯基的氟化有机聚硅氧烷，（B）作为增粘剂的环状氟化有机硅氧烷，（C）分子中具有至少两个氢原子的有机氢聚硅氧烷，和 D）铂族金属催化剂具有氟化硅橡胶固有的优异性能，并固化成与各种材料（包括金属，玻璃和树脂）具有粘合性和紧密接触的产品。
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公开(公告)号：US5386049A
公开(公告)日：1995-01-31
申请号：US18510
申请日：1993-02-17
CPC分类号： C08G77/50
摘要： Organic silicone compounds of this invention are expressed by the following general chemical formula: ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group with 1 to 4 carbon atoms, R.sup.2 is substituted or unsubstituted monovalent hydrocarbon group, X is either a hydrogen atom or a triorganosilyl group which is expressed by the following general chemical formula (2): ##STR2## wherein R.sup.3, R.sup.4 and R.sup.5 are a substituted or unsubstituted monovalent hydrocarbon group with 1 to 8 carbon atoms, each of which may be the same or different, p is an integer from 4 to 16, m is an integer from 0 to 1000, and n is an integer from 1 to 1000. The organic silicon compounds of this invention are extremely useful as raw material of rubber cured products with high strength and a superior transparency.
摘要翻译： 本发明的有机硅氧烷化合物由以下通式表示：其中R 1为取代或未取代的碳原子数1〜4的烷基，R 2为取代或未取代的一价烃基，X为氢原子或 由以下一般化学式（2）表示的三有机甲硅烷基：其中R 3，R 4和R 5是具有1至8个碳原子的取代或未取代的一价烃基，其各自可以相同或不同， p为4〜16的整数，m为0〜1000的整数，n为1〜1000的整数。本发明的有机硅化合物作为高强度的橡胶固化物的原料非常有用， 透明度高。
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公开(公告)号：US5288829A
公开(公告)日：1994-02-22
申请号：US917291
申请日：1992-07-23
申请人： Toshio Takago , Horishi Inomata , Shinichi Sato , Noriyuki Koike , Takashi Matsuda , Hirofumi Kishita
发明人： Toshio Takago , Horishi Inomata , Shinichi Sato , Noriyuki Koike , Takashi Matsuda , Hirofumi Kishita
CPC分类号： G03F7/0757 , C08L83/12 , C08L83/14
摘要： A curable silicone composition, comprising (A) a fluorosilicone represented by the following general formula (1): ##STR1## wherein Rf represents a perfluoroalkylene group or perfluoropolyether group having 11 to 30 carbon atoms, R.sup.1, R.sup.2, and R.sup.3 each represent a monovalent hydrocarbon group, a and p are each an integer of 2 or over, b and c are each an integer of 0 or over, and X is a triorganosilyl group, (B) an organohydrogensiloxane containing two or more Si--H groups in the molecule, and (C) a platinum family metal catalyst. This composition upon curing gives a rubberlike elastic product excellent in solvent resistance, chemical resistance, water repellency, and oil repellency and low in moisture permeability.
摘要翻译： 一种可固化有机硅组合物，其包含（A）由以下通式（1）表示的氟硅酮：（*化学结构*）（1）其中Rf表示具有11至30个碳原子的全氟亚烷基或全氟聚醚基，R1，R2， 和R 3各自表示一价烃基，a和p各自为2以上的整数，b和c各自为0以上的整数，X为三有机甲硅烷基，（B）含有2个以上Si的有机氢硅氧烷 -H基团，和（C）铂族金属催化剂。 固化后的这种组合物产生耐溶剂性，耐化学性，防水性，拒油性和透湿性低的橡胶状弹性体。
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公开(公告)号：US5118828A
公开(公告)日：1992-06-02
申请号：US723317
申请日：1991-06-28
申请人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
发明人： Toshio Takago , Hirofumi Kishita , Shinichi Sato , Hitoshi Kinami , Shuji Suganuma , Koichi Yamaguchi , Kenichi Fukuda , Hirokazu Yamada
IPC分类号： C07F7/08
CPC分类号： C07F7/0841
摘要： The fluorine-containing organosilicon compound of the present invention is represented by the following formula: ##STR1## wherein Rf is a perfluoroalkyl group. This compound is quite useful as a raw material for the production of polysilethylenesiloxanes excellent in solvent resistance.
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