摘要:
The present application relates to a production method for a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), in which monomer components including the monomer (a) and the monomer (b) are polymerized using a peroxide and a reductant as polymerization initiators in combination while the pH during polymerization is controlled to 3 or less in the presence of a pH adjustor. The present application also relates to a polycarboxylic acid-based copolymer for a high-performance cement admixture including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), and a nonpolymerizable organic sulfonic acid having a molecular weight of 300 or less and/or a salt thereof.
摘要:
Provided is a production method for a polycarboxylic acid-based copolymer including a structural unit derived from an unsaturated polyalkylene glycol ether-based monomer and a structural unit derived from an unsaturated carboxylic acid-based monomer, by which the production cost of the copolymer is reduced and an unprecedentedly high-performance cement admixture can be provided. Also provided is a copolymer composition for a cement admixture, including a structural unit derived from an unsaturated polyalkylene glycol ether-based monomer and a structural unit derived from an unsaturated carboxylic acid-based monomer, with which an unprecedentedly high-performance cement admixture can be provided. The production method for a polycarboxylic acid-based copolymer of the present invention is a production method for a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), in which monomer components including the monomer (a) and the monomer (b) are polymerized using a peroxide and a reductant as polymerization initiators in combination while the pH during polymerization is controlled to 3 or less in the presence of a pH adjustor. The copolymer composition for a cement admixture of the present invention includes a polycarboxylic acid-based copolymer including a structural unit (I) derived from an unsaturated polyalkylene glycol ether-based monomer (a) and a structural unit (II) derived from an unsaturated carboxylic acid-based monomer (b), and a nonpolymerizable organic sulfonic acid having a molecular weight of 300 or less and/or a salt thereof.
摘要:
It is an object of the present invention to provide a novel method for producing (1R,2S)/(1S,2R)-1-amino-1-alkoxycarbonyl-2-vinylcyclopropane which is useful as a synthetic intermediate of therapeutic agents for hepatitis C and a synthetic intermediate thereof. According to the present invention, when a trans-2-butene derivative having a leaving group at each of the 1- and 4-positions is reacted with a malonic ester in the presence of a base, a specific amount of an alkali metal alkoxide or an alkali metal hydride is used as the base, and further a specific amount of a malonic ester is used to produce a cyclopropane diester, and further, chiral or achiral 1-amino-1-alkoxy-carbonyl-2-vinylcyclopropane and a salt thereof are synthesized using the cyclopropane diester.
摘要:
Management server 16 may obtain application programs from content server 20 in response to requests of mobile terminal 11. Management server 16 may transmit the obtained application programs to mobile terminal 11 with information concerning reliabilities of the application programs. After mobile terminal 11 receives the application programs from management server 16, mobile terminal 11 manages operations of the application programs. Operations of the application programs are coordinated with operations of other programs using the information concerning the reliabilities corresponding to the application programs. Management of the coordinated operations of the application programs avoids problems concerning information security, where valuable information may be distributed unexpectedly because of operations of low reliable application programs. As a result, convenience of users of mobile terminals 11 can be improved without deteriorating the information security of mobile terminals 11.
摘要:
A rear discharge mower comprising: a first shaft; a first blade that is rotated in unison with the first shaft; a second shaft that is configured to be rotated in a direction opposite from a rotational direction of the first shaft; a second blade that is rotated in unison with the second shaft, wherein a grass-clippings discharge path is formed through which grass clippings are discharged in a rearward direction from the area between the first shaft and second shaft; an enclosing casing that supports the blade shafts; and a power train that is accommodated in the enclosing casing and that transmits power to the first and second blade shafts.
摘要:
Management server 16 may obtain application programs from content server 20 in response to requests of mobile terminal 11. Management server 16 may transmit the obtained application programs to mobile terminal 11 with information concerning reliabilities of the application programs. After mobile terminal 11 receives the application programs from management server 16, mobile terminal 11 manages operations of the application programs. Operations of the application programs are coordinated with operations of other programs using the information concerning the reliabilities corresponding to the application programs. Management of the coordinated operations of the application programs avoids problems concerning information security, where valuable information may be distributed unexpectedly because of operations of low reliable application programs. As a result, convenience of users of mobile terminals 11 can be improved without deteriorating the information security of mobile terminals 11.
摘要:
In a communication terminal using UIM, when a message disabling use of a content is received not by a communication terminal containing the content to disabled, but by another communication terminal containing the same content, the content stored in a storage unit of the communication terminal which has received the message is not disabled. Mobile phone 100-1 using UIM stores a program in correlation with a telephone number stored in the UIM. When mobile phone 100-1 receives a management message to delete a program, mobile phone 100-1 interprets the content of the management message. Mobile phone 100-1 obtains a telephone number from the UIM, and deletes the content stored in correlation with the telephone number according to the management message interpreted.
摘要:
The object of the present invention is to provide 3-hydroxy-3-(2-thienyl)propionamides useful as synthesis intermediates of pharmaceutical preparations and the like and a method for obtaining optically active 3-amino-1-(2-thienyl)-1-propanols using the same with high reaction yield, high optical yield and industrially low cost.According to the present invention, 3-amino-1-(2-thienyl)-1-propanols are obtained by carrying out asymmetric reduction of a β-ketocarbonyl compound having thiophene ring in the presence of a catalyst constituted from a compound of a group VIII or IX metal in the periodic table (e.g., a ruthenium compound) and an asymmetric ligand represented by a specified optically active diamine derivative (e.g., a diphenylethylenediamine derivative), or using a cell, a treated product of said cell or the like of a microorganism, and as occasion demands, carrying out amidation of the ester group and then carrying out reduction of the amido group. (each of the substituents is as described in claim 1).
摘要:
A rear discharge mower comprising: a first shaft; a first blade that is rotated in unison with the first shaft; a second shaft that is configured to be rotated in a direction opposite from a rotational direction of the first shaft; a second blade that is rotated in unison with the second shaft, wherein a grass-clippings discharge path is formed through which grass clippings are discharged in a rearward direction from the area between the first shaft and second shaft; an enclosing casing that supports the blade shafts; and a power train that is accommodated in the enclosing casing and that transmits power to the first and second blade shafts.
摘要:
It is an object of the present invention to provide an inexpensive and efficient industrial method for obtaining (S)-2-pentanol, (S)-2-hexanol, 1-methylalkyl malonic acid and 3-methyl carboxylic acid at a high optical purity. The present invention provides a method of producing (S)-2-pentanol or (S)-2-hexanol which comprises allowing certain types of microorganisms or transformed cells, a product obtained by treating said microorganisms or cells, a culture solution of said microorganisms or cells, and/or a crude purified product or purified product of a carbonyl reductase fraction obtained from said microorganisms or cells, to act on 2-pentanone or 2-hexanone.