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1.发明授权
公开(公告)号：US4778624A
公开(公告)日：1988-10-18
申请号：US897309
申请日：1986-08-15
申请人： Hiroshi Ohashi , Kiyohiro Kondow , Fumio Okada , Masaki Tanaka
发明人： Hiroshi Ohashi , Kiyohiro Kondow , Fumio Okada , Masaki Tanaka
IPC分类号： C08G77/00 , B01F17/00 , B01F17/54 , C08G77/06 , C08J3/03 , C08L83/00 , C08L83/04 , C09D5/02 , C09D183/04 , B01J13/02
CPC分类号： C08J3/03 , B01F17/00 , C08G77/06 , C08J2383/04
摘要： The invention provides a method for the preparation of a stable aqueous emulsion of a poly(silsesquioxane) without formation of gelled particles. In the method, a trialkoxysilane compound as the starting material is first emulsified in an aqueous medium containing a cationic surface active agent and a non-ionic surface active agent having a specified HLB value in the range from 16 to 20 in combination followed by the addition of an alkali catalyst and heating to effect hydrolysis and polycondensation of the trialkoxysilane.
摘要翻译： 本发明提供了一种制备聚（倍半硅氧烷）稳定的水性乳液而不形成凝胶状颗粒的方法。 在该方法中，作为起始原料的三烷氧基硅烷化合物首先在包含阳离子表面活性剂和非离子表面活性剂的水性介质中乳化，所述阳离子表面活性剂和非离子表面活性剂的特定HLB值在16至20的范围内，然后加入 的碱催化剂并加热以进行三烷氧基硅烷的水解和缩聚。
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公开(公告)号：US4726964A
公开(公告)日：1988-02-23
申请号：US848814
申请日：1986-04-04
申请人： Kenichi Isobe , Hisashi Aoki , Yasuaki Hara , Meguru Kashida , Kiyohiro Kondow
发明人： Kenichi Isobe , Hisashi Aoki , Yasuaki Hara , Meguru Kashida , Kiyohiro Kondow
CPC分类号： D21H19/32 , C08L83/04 , C09J7/0228 , C08G77/12 , C08G77/20 , C09J2205/31 , C09J2483/005
摘要： The invention provides a method for imparting releasability to the surface of a plastic film or paper by coating the surface with an organopolysiloxane composition followed by curing, in which the curing is complete by heating at a relatively low temperature and the cured surface film of the composition is very stable and free from the problem of transfer to another body in contact therewith. The composition comprises a vinyl-containing organopolysiloxane, an organohydrogenpolysiloxane and a platinum compound to catalyze the addition reaction between the silicon-bonded vinyl groups and silicon-bonded hydrogen atoms. Different from conventional organohydrogenpolysiloxane having a linear molecular structure, the organohydrogenpolysiloxane used in the invention is represented by the general unit formula (RSiO.sub.1.5).sub.m (RHSiO.sub.0.5).sub.n, in which R is a monovalent hydrocarbon group free form unsaturation and m and n are each a positive integer with the proviso that the ratio of n/m is from 0.1 to 3.0, or a combination thereof with a linear organohydrogenpolysiloxane.
摘要翻译： 本发明提供了一种通过用有机聚硅氧烷组合物涂覆表面然后进行固化来赋予塑料膜或纸的表面释放性的方法，其中通过在相对低的温度下加热固化，并且组合物的固化表面膜 非常稳定，没有转移到与其接触的另一身体的问题。 该组合物包含含乙烯基的有机聚硅氧烷，有机氢聚硅氧烷和铂化合物，以催化与硅键合的乙烯基和与硅键合的氢原子之间的加成反应。 与具有直链分子结构的常规有机氢聚硅氧烷不同，本发明中使用的有机氢聚硅氧烷由通式（RSiO 1.5）m（R HSiO 0.5）n表示，其中R是一价烃基不饱和键，m和 n各自为正整数，条件是n / m的比例为0.1至3.0，或其与线性有机氢聚硅氧烷的组合。
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公开(公告)号：US4689384A
公开(公告)日：1987-08-25
申请号：US842531
申请日：1986-03-21
申请人： Kiyohiro Kondow , Takeshi Mihama , Yasuaki Hara , Hisashi Aoki , Nobuyuki Hasebe
发明人： Kiyohiro Kondow , Takeshi Mihama , Yasuaki Hara , Hisashi Aoki , Nobuyuki Hasebe
CPC分类号： C08K5/02
摘要： So-called addition-type curable organopolysiloxane compositions curable by the hydrosilation reaction between vinyl groups of a dimethylpolysiloxane and hydrogen atoms directly bonded to the silicon atoms in a methylhydrogenpolysiloxane in the presence of a platinum catalyst can be imparted with a greatly increased pot life to have improved workability when the composition is admixed with a halogen- or alkoxy-substituted olefinic organic compound such as allyl halides, 1,3- and 2,3-dihalogenopropenes, 2-alkyl-3-halogenopropenes, 1,3- and 1,4-dihalogenobutenes-2 and alkyl allyl ethers as a moderator of the crosslinking reaction without any adverse effect on the curability of the composition.
摘要翻译： 通过在二甲基聚硅氧烷的乙烯基之间的氢化硅烷化合物可固化的所谓的加成型可固化的有机基聚硅氧烷组合物和在铂催化剂存在下直接键合到甲基氢聚硅氧烷中的硅原子的氢原子之间，可赋予具有大大增加的适用期 当组合物与卤素或烷氧基取代的烯属有机化合物如烯丙基卤化物，1,3-和2,3-二卤代丙烯，2-烷基-3-卤代丙烯，1,3-和1,4 - 二卤代丁烯-2和烷基烯丙基醚作为交联反应的缓和剂，对组合物的固化性没有任何不利影响。
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公开(公告)号：US4584342A
公开(公告)日：1986-04-22
申请号：US705566
申请日：1985-02-26
申请人： Kiyohiro Kondow
发明人： Kiyohiro Kondow
IPC分类号： C08G59/00 , C08G59/18 , C08G59/20 , C08G59/30 , C08G59/40 , C08L63/00 , C08L79/00 , C08L79/04 , C08L83/06 , C08L83/07 , C08L83/08 , H01B3/46
摘要： A liquid silicone rubber composition comprising (A) an organopolysiloxane containing epoxy groups, (B) an organopolysiloxane containing amino groups and (C) a curing catalyst for epoxy compounds is proposed in which the compounding ratio of the component (A) to the component (B) is in the range of from 0.2 to 5.0 relative to the epoxy/amino molar ratio and which further contains optionally an organic solvent such as xylene and a silica flour. The composition is cured rapidly without the problem of catalyst poisoning even at room temperatures to be converted into a cured article with low volume resistivity and excellent antistatic performance as well as surface releasability. The composition is useful as casting materials, electric insulating materials, paint vehicles, coating materials, molding compositions and the like.
摘要翻译： 一种液体硅橡胶组合物，其包含（A）含环氧基的有机聚硅氧烷，（B）含氨基的有机聚硅氧烷和（C）环氧化合物的固化催化剂，其中组分（A）与组分 B）相对于环氧/氨基摩尔比在0.2至5.0的范围内，并且还任选地含有有机溶剂如二甲苯和二氧化硅粉。 快速固化组合物，即使在室温下也不会引起催化剂中毒的问题，可以将其转化为具有低体积电阻率和优异的抗静电性能以及表面剥离性的固化物。 该组合物可用作铸造材料，电绝缘材料，涂料载体，涂料，模塑组合物等。
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5.发明授权Dry photosensitive lithographic plate comprising a silicon rubber layer containing an aromatic aminosilane 失效包含含有芳族氨基硅烷的硅橡胶层的干式光敏平版印刷版
公开(公告)号：US4826752A
公开(公告)日：1989-05-02
申请号：US63470
申请日：1987-06-18
CPC分类号： G03F7/0752
摘要： A dry photosensitive lithographic printing plate has a base, a photosensitive layer formed on the base and a silicone rubber layer formed on the photosensitive layer. The silicone rubber layer is formed from a silicon rubber composition containing an organopolysiloxane and a reactive aromatic aminosilane compound.
摘要翻译： 干感光性平版印刷版具有基材，形成在基材上的感光层和形成在感光层上的硅橡胶层。 硅橡胶层由含有有机聚硅氧烷和反应性芳族氨基硅烷化合物的硅橡胶组合物形成。
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公开(公告)号：US4660927A
公开(公告)日：1987-04-28
申请号：US524089
申请日：1983-08-17
申请人： Kiyohiro Kondow , Nobuo Takasaka , Yoshinori Hida
发明人： Kiyohiro Kondow , Nobuo Takasaka , Yoshinori Hida
CPC分类号： C03C25/106 , Y10T428/2962 , Y10T428/2964 , Y10T428/31612
摘要： The invention provides a novel silicone-coated, quartz glass-made optical fiber which is very advantageous in the high efficiency of the coating process as well as in the improved workability in the connecting works of the fiber terminals for extension of the communication lines by virtue of the excellent peelability of the coating layer from the surface of the quartz glass fiber even by mere drawing the coated fiber between fingers. The coating layer is formed of a radiation- or UV-cured silicone composition comprising (A-a) an organopolysiloxane having aliphatic unsaturation, e.g. vinyl, and/or (A-b) an organopolysiloxane having mercaptoalkyl groups, e.g. 3-mercaptopropyl groups, and (B) a curing accelerator.
摘要翻译： 本发明提供了一种新颖的有机硅涂覆的石英玻璃制造的光纤，其在涂覆过程的高效率以及在通过线路延长的光纤端子的连接工作中的改进的可操作性方面是非常有利的 即使仅通过在手指之间拉伸被覆纤维，涂层从石英玻璃纤维的表面也具有优异的剥离性。 涂层由辐射或UV固化的硅氧烷组合物形成，其包含（A-a）具有脂肪族不饱和键的有机聚硅氧烷，例如 乙烯基和/或（A-b）具有巯基烷基的有机聚硅氧烷，例如 3-巯基丙基，（B）固化促进剂。
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公开(公告)号：US4328150A
公开(公告)日：1982-05-04
申请号：US243251
申请日：1981-03-12
申请人： Kiyohiro Kondow , Tetuo Yoshida , Yuki Tateyama
发明人： Kiyohiro Kondow , Tetuo Yoshida , Yuki Tateyama
CPC分类号： H01L23/295 , C08G59/688 , C08L63/00 , H01L2924/0002
摘要： The invention provides a novel epoxy-based curable resin composition suitable for encapsulation of electronic devices such as transistors, ICs, LSIs and the like. The composition comprises an epoxy compound, a novolac-type phenolic resin as the curing agent, an organophosphine compound such as triphenylphosphine and trilaurylphosphine as a curing accelerator and an inorganic filler. The advantages obtained by the combined use of the novolac-type phenolic resin and the organophosphine compound are very specific and the resin composition is imparted with remarkable flowability in molding and stability in storage in addition to the excellent electric properties at high temperatures and anti-moisture resistance of the cured shaped articles molded therefrom.
摘要翻译： 本发明提供一种适用于电子器件如晶体管，IC，LSI等的封装的新型环氧系固化树脂组合物。 组合物包含环氧化合物，酚醛清漆型酚醛树脂作为固化剂，有机膦化合物如三苯基膦和三月桂基膦作为固化促进剂和无机填料。 通过组合使用酚醛清漆型酚醛树脂和有机膦化合物获得的优点是非常特异的，除了具有优异的高温电气性能和抗湿性之外，树脂组合物在模塑中赋予显着的流动性和储存稳定性 由其模制的固化的成形制品的电阻。
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公开(公告)号：US4743527A
公开(公告)日：1988-05-10
申请号：US813430
申请日：1985-12-26
CPC分类号： G03F7/0752
摘要： A presensitized plate for use in making a planographic printing plate requiring no dampening water which comprises a support having provided thereon, in order, a light-sensitive layer comprising a photodimerizable resin and a silicone rubber layer comprising an organopolysiloxane cured with a crosslinking agent comprising a reactive silane compound having a carbon-carbon double bond to which a silicon atom is not directly linked. The presensitized plate shows excellent developing properties and fine dot reproduction.
摘要翻译： 一种用于制造不需要润版水的平版印刷版的预定版，其包括其上提供的载体，依次包含可光聚合树脂的光敏层和包含用交联剂固化的有机聚硅氧烷的硅酮橡胶层，所述有机聚硅氧烷含有 硅原子未直接连接的具有碳 - 碳双键的反应性硅烷化合物。 预感板显示出优异的显影性能和细小的点再现性。
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9.发明授权Radiation curable organic silicon compounds and releasing cured films comprising cured products of said compounds 失效可辐射固化的有机硅化合物和释放包含所述化合物的固化产物的固化膜
公开(公告)号：US4603086A
公开(公告)日：1986-07-29
申请号：US707679
申请日：1985-03-04
申请人： Hitoshi Fujii , Hideo Fujimura , Hisashi Aoki , Kiyohiro Kondow
发明人： Hitoshi Fujii , Hideo Fujimura , Hisashi Aoki , Kiyohiro Kondow
IPC分类号： C09J7/02 , C07F7/18 , C08F283/12 , C08F290/00 , C08F299/00 , C08F299/08 , C08G77/00 , C08G77/04 , C08G77/38 , C08G77/388 , C08G77/48 , C08G77/54 , C08L83/04 , C08L83/08 , C09D183/04 , C09D183/08 , B32B9/04
CPC分类号： C08L83/08 , C08F283/122 , C08G77/388 , Y10T428/31663
摘要： The present invention relates to an organopolysiloxane material which is cured rapidly by irradiating it with radiation such as ultraviolet rays, electron beam and X-rays to provide a film having good characteristics, which can be readily produced synthetically and which is stable, as well as the material's cured releasing film. The material is obtained by the reaction of (A), an organic silicon compound having a specific formula and having at least one amino group, and (B), an acrylic compound having at least two acrylate groups.
摘要翻译： 本发明涉及通过用紫外线，电子束和X射线等辐射照射而快速固化的有机聚硅氧烷材料，以提供具有良好特性的膜，其可以容易地合成并且稳定，以及 该材料的固化释放膜。 该材料通过（A）与具有至少一个氨基的具体化学式的有机硅化合物和（B），具有至少两个丙烯酸酯基团的丙烯酸类化合物反应而获得。
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