公开(公告)号：US06605344B1

公开(公告)日：2003-08-12

申请号：US09673086

申请日：2000-10-11

申请人： Hiroyuki Ohba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa ,  Toru Saika

发明人： Hiroyuki Ohba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa ,  Toru Saika

IPC分类号： B32B2730

CPC分类号： C08J7/045 ,  B32B27/18 ,  B32B27/30 ,  C08J7/047 ,  C08J2433/00 ,  Y10T428/26 ,  Y10T428/31692 ,  Y10T428/31928 ,  Y10T428/31935

摘要： The present invention provides a gas-barrier film which is produced through applying a layer containing a metallic compound to a surface of a processed-polymer layer produced from a mixture of a polyalcohol and at least one poly(meth)acrylic polymer selected from the group consisting of poly(meth)acrylic acids and partially neutralized poly(meth)acrylic acids. The invention also provides a laminated gas-barrier film containing the aforementioned gas-barrier film either surface of which is laminated on with a plastic film. The gas-barrier film exhibits excellent gas-barrier properties and can be produced through a simple, convenient process.

摘要翻译： 本发明提供一种阻气膜，其通过将由含有金属化合物的层施加到由多元醇和至少一种选自下组的聚（甲基）丙烯酸类聚合物的混合物制成的加工聚合物层的表面上而制备： 由聚（甲基）丙烯酸和部分中和的聚（甲基）丙烯酸组成。 本发明还提供了含有上述阻气膜的层压阻气膜，其表面层叠有塑料膜。 阻气膜表现出优异的阻气性，并且可以通过简单方便的工艺制造。

公开(公告)号：US6022913A

公开(公告)日：2000-02-08

申请号：US68584

申请日：1998-05-06

申请人： Hideaki Tanaka ,  Hiroyuki Ohba ,  Tomoaki Sato ,  Tomohisa Hasegawa

发明人： Hideaki Tanaka ,  Hiroyuki Ohba ,  Tomoaki Sato ,  Tomohisa Hasegawa

IPC分类号： B32B27/08 ,  B32B27/36 ,  B65D65/40 ,  B65D81/34 ,  C08J5/18 ,  B65D81/24 ,  C08G81/02

CPC分类号： C08J5/18 ,  B32B27/08 ,  B32B27/36 ,  B65D81/3415 ,  Y10S525/933 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/31855

摘要： The present invention provides a container for retort packaging comprising a laminated film having an outermost layer comprising a layer formed of a cross-linked structure containing ester bonds between poly(meth)acrylic acid (A) and polyalcoholic polymer (B); a resin composition having at least the chemical structures (X) [poly(meth)acrylic acid (A) residue], (Y) [poly(meth)acrylic acid (A)-polyalcoholic polymer (B) residue] and (Z) [metal cross-linked ionic residues], wherein the degree of esterification defined by the equation: degree of esterification=c/(b+c+d) is from 0.01 to 0.5 and the degree of ionization defined by the equation: degree of ionization=c/(b+c+d) is from 0.01 to 0.9 (wherein b, c and d represent the molar ratios of the carbon-oxygen double bond in the chemical structure of the resin composition; and a gas barrier film comprising the same.

摘要翻译： PCT No.PCT / JP97 / 03131 Sec。 371日期：1998年3月19日 102（e）1998年3月19日PCT PCT 1997年9月5日PCT公布。 第WO98 / 09813号公报 日期：1998年3月12日本发明提供一种蒸煮包装用容器，其特征在于，具有层叠膜，所述层叠膜具有包含由聚（甲基）丙烯酸（A）和多元醇聚合物（B）之间的酯键的交联结构形成的层的最外层 ）; 至少具有化学结构（X）[聚（甲基）丙烯酸（A）残基]，（Y）[聚（甲基）丙烯酸（A） - 多元醇聚合物（B）残基]和（Z） [金属交联离子性残基]，其中酯化度由下式定义：c /（b + c + d）为0.01〜0.5，电离度由下式定义：电离度 = c /（b + c + d）为0.01〜0.9（其中b，c和d表示树脂组合物的化学结构中的碳 - 氧双键的摩尔比; 。

公开(公告)号：US6143384A

公开(公告)日：2000-11-07

申请号：US438156

申请日：1999-11-10

申请人： Hideaki Tanaka ,  Hiroyuki Ohba ,  Tomoaki Sato ,  Tomohisa Hasegawa

发明人： Hideaki Tanaka ,  Hiroyuki Ohba ,  Tomoaki Sato ,  Tomohisa Hasegawa

IPC分类号： B32B27/08 ,  B32B27/36 ,  B65D65/40 ,  B65D81/34 ,  C08J5/18 ,  B29D22/00 ,  C08L3/00

CPC分类号： C08J5/18 ,  B32B27/08 ,  B32B27/36 ,  B65D81/3415 ,  Y10S525/933 ,  Y10T428/1352 ,  Y10T428/1355

摘要： The present invention provides a container for retort packaging comprising a laminated film having an outermost layer comprising a layer formed of a cross-linked structure containing ester bonds between poly(meth)acrylic acid (A) and polyalcoholic polymer (B); a resin composition having at least the chemical structures (X) [poly(meth)acrylic acid (A) residue], (Y) [poly(meth)acrylic acid (A)-polyalcoholic polymer (B) residue] and (Z) [metal cross-linked ionic residues], wherein the degree of esterification defined by the equation: degree of esterification=c/(b+c+d) is from 0.01 to 0.5 and the degree of ionization defined by the equation: degree of ionization=c/(b+c+d) is from 0.01 to 0.9 (wherein b, c and d represent the molar ratios of the carbon-oxygen double bond in the chemical structure of the resin composition; and a gas barrier film comprising the same.

摘要翻译： 本发明提供了一种用于蒸煮包装的容器，其包括具有最外层的层压膜，该最外层包含由在聚（甲基）丙烯酸（A）和聚醇聚合物（B）之间含有酯键的交联结构形成的层; 至少具有化学结构（X）[聚（甲基）丙烯酸（A）残基]，（Y）[聚（甲基）丙烯酸（A） - 多元醇聚合物（B）残基]和（Z） [金属交联离子性残基]，其中酯化度由下式定义：c /（b + c + d）为0.01〜0.5，电离度由下式定义：电离度 = c /（b + c + d）为0.01〜0.9（其中b，c和d表示树脂组合物的化学结构中的碳 - 氧双键的摩尔比; 。

公开(公告)号：US5897960A

公开(公告)日：1999-04-27

申请号：US813394

申请日：1997-03-10

申请人： Hiroyuki Oba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa

发明人： Hiroyuki Oba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa

IPC分类号： B05D3/02 ,  B05D5/00 ,  B05D7/04 ,  B29C71/02 ,  B29K33/00 ,  B29K101/12 ,  B29L9/00 ,  B32B27/08 ,  B32B27/30 ,  C08J7/04 ,  C08L1/00 ,  C08L1/02 ,  C08L3/00 ,  C08L3/02 ,  C08L33/04 ,  C08L33/06 ,  B32B23/08

CPC分类号： B32B27/08 ,  B32B27/30 ,  C08J7/047 ,  B32B2307/50 ,  C08J2433/00 ,  Y10T428/1341 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/31855 ,  Y10T428/3188 ,  Y10T428/31884 ,  Y10T428/31888 ,  Y10T428/31909 ,  Y10T428/3192 ,  Y10T428/31971

摘要： A laminate having a laminated structure of at least two layers includes a gas barrier film (A) formed from a mixture containing at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products thereof and a saccharide in a weight ratio of 95:5 to 20:80, and having an oxygen permeability constant of 5.00.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C. and 80% relative humidity, and a layer (B) formed from a thermoplastic resin. The film (A) and the layer (B) are laminated contiguously to each other. A process for the production of a laminate having a laminated structure of at least two layers comprises a step of forming a gas barrier film (A) having an oxygen permeability constant of 5.00.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C. and 80% RH, wherein a solution containing at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products thereof and a saccharide in a weight ratio of 95:5 to 20:80 is coated on a layer (B) formed from a thermoplastic resin, the solution coated is dried to form a film, and the film is then subjected to a heat treatment at a temperature of at least 100.degree. C. (373K). The film (A) and the layer (B) are contiguous to each other.

摘要翻译： 具有至少两层的层压结构的层压体包括由含有至少一种选自聚（甲基）丙烯酸和部分中和产物的聚（甲基）丙烯酸聚合物的混合物形成的阻气膜（A） 以及重量比为95:5至20:80的糖类，并且在30℃的条件下测量的氧透过率常数为5.00×10 -3 ml（STP）×cm / m 2×h xatm {Pa}或更小， 80％的相对湿度和由热塑性树脂形成的层（B）。 膜（A）和层（B）彼此相邻地层叠。 制备具有至少两层的叠层结构的层压体的方法包括形成氧透过率常数为5.00×10 -3 ml（STP）×cm / m 2×h xatm {Pa}的阻气膜（A）或 在30℃和80％RH的条件下测量的较小，其中含有至少一种选自聚（甲基）丙烯酸和其部分中和产物的聚（甲基）丙烯酸聚合物的溶液和在 将重量比为95:5至20:80涂覆在由热塑性树脂形成的层（B）上，将涂布的溶液干燥以形成膜，然后将膜在温度为 至少100℃（373K）。 膜（A）和层（B）彼此邻接。

公开(公告)号：US5709951A

公开(公告)日：1998-01-20

申请号：US502033

申请日：1995-07-13

申请人： Tomoaki Sato ,  Hiroyuki Oba ,  Hideaki Tanaka ,  Tomohisa Hasegawa

发明人： Tomoaki Sato ,  Hiroyuki Oba ,  Hideaki Tanaka ,  Tomohisa Hasegawa

IPC分类号： B32B9/00 ,  B32B27/30 ,  C08J7/04 ,  C23C14/06 ,  B32B17/08 ,  B32B23/00

CPC分类号： C08J7/045 ,  Y10T428/1321 ,  Y10T428/1359 ,  Y10T428/31616 ,  Y10T428/31623 ,  Y10T428/31645 ,  Y10T428/31649 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31971

摘要： A composite deposited film including (A) a polymeric film substrate; (B) a deposit of an inorganic material formed on at least one side of the polymeric film substrate (A); and (C) a water-resistant film laminated on the deposit (B) and formed from a mixture containing a polycarboxylic acid or a partially neutralized product thereof and a saccharide in a weight ratio of 95:5 to 20:80 is provided. A production process of a composite deposited film, which includes the steps of forming a deposit (B) of an inorganic material on at least one side of a polymeric film substrate (A); casting a solution of a mixture containing a polycarboxylic acid or a partially neutralized product thereof and a saccharide in a weight ratio of 95:5 to 20:80 on the deposit (B); drying the mixture to form a film; and then subjecting the resultant dry film to a heat treatment at a temperature not lower than 100.degree. C. (373 K), thereby forming a water-resistant film (C) on the deposit (B), is also provided.

摘要翻译： 一种复合沉积膜，包括（A）聚合物膜基材; （B）形成在聚合物膜基材（A）的至少一侧上的无机材料的沉积物; 和（C）层压在沉积物（B）上并由含有多元羧酸或其部分中和产物和重量比为95:5至20:80的糖的混合物形成的防水膜。 复合沉积膜的制造方法，包括在聚合物膜基材（A）的至少一面上形成无机材料的沉积物（B）的步骤; 在沉积物（B）上浇铸含有多元羧酸或其部分中和产物和糖的重量比为95:5至20:80的混合物的溶液; 干燥混合物以形成膜; 然后在不低于100℃（373K）的温度下对所得干膜进行热处理，从而在沉积物（B）上形成防水膜（C）。

公开(公告)号：US5560988A

公开(公告)日：1996-10-01

申请号：US378215

申请日：1995-01-25

申请人： Hiroyuki Oba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa ,  Kazuhiko Hirose

发明人： Hiroyuki Oba ,  Hideaki Tanaka ,  Tomoaki Sato ,  Tomohisa Hasegawa ,  Kazuhiko Hirose

IPC分类号： B65D65/40 ,  B29C71/02 ,  B29K33/00 ,  B29L7/00 ,  B32B27/30 ,  C08J7/04 ,  C08L29/04 ,  C08L33/02

CPC分类号： C08L29/04 ,  C08J7/047 ,  C08L33/02 ,  C08J2429/00 ,  C08J2433/00 ,  Y10T428/2958 ,  Y10T428/31913 ,  Y10T428/3192 ,  Y10T428/31928

摘要： A gas barrier laminate having a laminated structure of at least two layers includes a gas barrier film (A) formed from a mixture containing polyvinyl alcohol and poly(meth)acrylic acid or a partially neutralized product thereof in a weight ratio ranging from 95:5 to 10:90, and having an oxygen permeability constant of 1.25.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C. and 80% relative humidity, and a layer (B) formed from a thermoplastic resin. The film (A) and layer (B) are laminated contiguously to each other. A process for the production of a gas barrier laminate having a laminated structure of at least two layers comprises a step of forming a gas barrier film (A) having an oxygen permeability constant of 1.25.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C. and 80% relative humidity, wherein a solution containing polyvinyl alcohol and poly(meth)acrylic acid or a partially neutralized product thereof in a weight ratio ranging from 95:5 to 10:90 is cast on a layer (B) formed from a thermoplastic resin, the solution cast is dried to form a film, and the dry film is then subjected to a heat treatment at a temperature of at least 100.degree. C. (373 K). The gas barrier film (A) and the layer (B) are contiguous to each other.

摘要翻译： 具有至少两层的叠层结构的阻气性层叠体包括由含有聚乙烯醇和聚（甲基）丙烯酸的混合物或其部分中和物形成的阻气膜（A），其重量比为95:5 至10:90，并且在30℃和80％相对湿度的条件下测量的氧气渗透常数为1.25×10 -3 ml（STP）×cm / m 2×h×（t Pa）或更小，形成层（B） 来自热塑性树脂。 膜（A）和层（B）彼此相邻地层叠。 制备具有至少两层的叠层结构的阻气性层压体的方法包括形成氧气渗透常数为1.25×10 -3 ml（STP）×cm / m 2×h×（Pa）的阻气膜（A）的工序 }或更小，在30℃和80％相对湿度的条件下测量，其中包含聚乙烯醇和聚（甲基）丙烯酸或其部分中和产物的溶液的重量比为95:5至10:90 浇铸在由热塑性树脂形成的层（B）上，将溶液流延干燥以形成膜，然后在至少100℃（373K）的温度下对干膜进行热处理。 阻气膜（A）和层（B）彼此邻接。

公开(公告)号：US5621026A

公开(公告)日：1997-04-15

申请号：US567512

申请日：1995-12-05

申请人： Hideaki Tanaka ,  Hiroyuki Oba ,  Tomoaki Sato ,  Tomohisa Hasegawa

发明人： Hideaki Tanaka ,  Hiroyuki Oba ,  Tomoaki Sato ,  Tomohisa Hasegawa

IPC分类号： B29C71/02 ,  C08J5/18 ,  C08L3/00 ,  C08L3/02 ,  C08L5/00 ,  C08L33/02

CPC分类号： C08J5/18 ,  C08L3/00 ,  C08L33/02 ,  C08L5/00 ,  C08J2303/00 ,  C08J2333/02

摘要： Disclosed herein is a gas barrier film formed from a mixture containing (A) at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products of poly(meth)acrylic acid and (B) a saccharide in a weight ratio of 95:5 to 20:80, and having an oxygen gas permeability coefficient of 5.00.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or lower as measured under conditions of 30.degree. C. and 80% relative humidity. A production process of the gas barrier film, in which a film is formed from the mixture, and then subjected to a heat treatment under specific conditions, is also disclosed.

摘要翻译： 本文公开了一种阻气膜，其由含有（A）至少一种聚（甲基）丙烯酸聚合物的混合物形成，所述聚（甲基）丙烯酸聚合物选自聚（甲基）丙烯酸和聚（甲基）丙烯酸的部分中和产物和（ B）重量比为95:5至20:80的糖类，并且在30℃的条件下测得的氧气渗透系数为5.00×10 -3 ml（STP）×cm / m 2×H x atm {Pa}以下。 和80％相对湿度。 还公开了从混合物形成膜，然后在特定条件下进行热处理的阻气膜的制造方法。

公开(公告)号：US5498662A

公开(公告)日：1996-03-12

申请号：US324541

申请日：1994-10-18

申请人： Hideaki Tanaka ,  Hiroyuki Oba ,  Tomoaki Sato ,  Tomohisa Hasegawa

发明人： Hideaki Tanaka ,  Hiroyuki Oba ,  Tomoaki Sato ,  Tomohisa Hasegawa

IPC分类号： B29C71/02 ,  C08J5/18 ,  C08L3/00 ,  C08L3/02 ,  C08L5/00 ,  C08L33/02

CPC分类号： C08J5/18 ,  C08L3/00 ,  C08L33/02 ,  C08L5/00 ,  C08J2303/00 ,  C08J2333/02

摘要： Disclosed herein is a gas barrier film formed from a mixture containing (A) at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products of poly(meth)acrylic acid and (B) a saccharide in a weight ratio of 95:5 to 20:80, and having an oxygen gas permeability coefficient of 5.00.times.10.sup.-3 ml(STP).cm/m.sup.2.h. atm {Pa} or lower as measured under conditions of 30.degree. C. and 80% relative humidity. A production process of the gas barrier film, in which a film is formed from the mixture, and then subjected to a heat treatment under specific conditions, is also disclosed.

摘要翻译： 本文公开了一种阻气膜，其由含有（A）至少一种聚（甲基）丙烯酸聚合物的混合物形成，所述聚（甲基）丙烯酸聚合物选自聚（甲基）丙烯酸和聚（甲基）丙烯酸的部分中和产物和（ B）重量比为95:5至20:80的糖类，氧气渗透系数为5.00×10 -3 ml（STP）.cm / m2.h。 atm {Pa}或更低，在30℃和80％相对湿度的条件下测量。 还公开了从混合物形成膜然后在特定条件下进行热处理的阻气膜的制造方法。

公开(公告)号：US07864413B2

公开(公告)日：2011-01-04

申请号：US11840449

申请日：2007-08-17

申请人： Yoshihisa Tanikawa ,  Tomoaki Sato ,  Ikuko Sakai

发明人： Yoshihisa Tanikawa ,  Tomoaki Sato ,  Ikuko Sakai

IPC分类号： G02B21/36

CPC分类号： G02B21/367

摘要： An examination apparatus that observes a specimen in a stationary state while suppressing the blurring caused by a control delay. The apparatus includes a first optical system and a second optical system for imaging light produced in a specimen, a first image-acquisition unit with a plurality of first image-acquisition devices for detecting an image formed by the first optical system, a second image-acquisition unit with a second image-acquisition device for acquiring an image formed by the second optical system, and a driving unit that causes the images to be formed at the same position in the second image-acquisition unit. The value obtained by dividing the pixel size Y of the first image-acquisition devices by the magnification X of the first optical system is smaller than the value obtained by dividing the pixel size Y′ of the second image-acquisition device by the magnification X′ of the second optical system.

摘要翻译： 一种在抑制由控制延迟引起的模糊的同时在静止状态下观察样本的检查装置。 该装置包括第一光学系统和用于对在样本中产生的光进行成像的第二光学系统，具有用于检测由第一光学系统形成的图像的多个第一图像获取装置的第一图像获取单元， 获取单元，具有用于获取由第二光学系统形成的图像的第二图像获取装置，以及使图像形成在第二图像获取单元中的相同位置的驱动单元。 通过将第一图像采集装置的像素大小Y除以第一光学系统的倍率X而获得的值小于通过将第二图像获取装置的像素尺寸Y'除以倍率X'而获得的值， 的第二光学系统。

公开(公告)号：US20070021928A1

公开(公告)日：2007-01-25

申请号：US11288167

申请日：2005-11-29

申请人： Tomoaki Sato ,  Mutsuyo Yamaguchi

发明人： Tomoaki Sato ,  Mutsuyo Yamaguchi

IPC分类号： G06F19/00

CPC分类号： G06F19/26 ,  G06F19/20

摘要： Pie charts are respectively displayed at coordinate locations in each upper left corner of image data that indicates genes on a network diagram N by a genetic information display apparatus. These pie charts can also be displayed semi-transparently. Numerical values of gene expression information (including a first expression level, its expression level ratio, a second expression level and its expression level ratio) prior to a scale conversion can also be displayed by pointing to image data using a pointing device. Accordingly, the legibility of the gene expression information is enhanced, and can be understood intuitively and clearly.

摘要翻译： 饼图分别显示在由遗传信息显示装置指示网络图N上的基因的图像数据的每个左上角的坐标位置处。 这些饼图也可以半透明地显示。 在比例转换之前的基因表达信息（包括第一表达水平，其表达水平比，第二表达水平及其表达水平比）的数值也可以通过使用指示装置指向图像数据来显示。 因此，提高了基因表达信息的易读性，并且可以直观且清楚地理解。