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1.发明授权Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion 失效在含氧化合物转化中使用含有小孔非沸石分子筛催化剂的碱土金属
公开(公告)号：US6040264A
公开(公告)日：2000-03-21
申请号：US627522
申请日：1996-04-04
IPC分类号： B01J29/04 , B01J29/85 , C07B37/00 , C07B61/00 , C07C1/24 , C07C11/02 , B01J27/182 , B01J21/08 , C01B15/16 , C07C1/00
CPC分类号： B01J29/85 , Y10S423/30
摘要： A method for converting starting material to olefins comprising contacting the starting material with a small pore non-zeolitic molecular sieve catalyst under effective conditions to produce olefins, wherein the non-zeolitic molecular sieve has been prepared in-situ or modified after synthesis by incorporation using an alkaline earth metal compound, wherein the alkaline earth metal ion is selected from the group consisting of strontium, calcium, barium, and mixtures thereof.
摘要翻译： 一种将起始原料转化为烯烃的方法，包括在有效条件下使原料与小孔非沸石分子筛催化剂接触以制备烯烃，其中非沸石分子筛已经通过原位合成制备而被修饰， 碱土金属化合物，其中碱土金属离子选自锶，钙，钡及其混合物。
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公开(公告)号：US4851507A
公开(公告)日：1989-07-25
申请号：US171054
申请日：1988-03-21
CPC分类号： C08G64/0208 , C08G64/34
摘要： The addition of a small amount of a second epoxide to the copolymerization of ethylene oxide or propylene oxide with carbon dioxide can give a melt processable polyalkylene carbonate terpolymer which can be processed without extensive thermal decomposition. This invention has particular utility in thermoplastic applications such as injection molding, blow molding, and film manufacture.
摘要翻译： 在环氧乙烷或环氧丙烷与二氧化碳的共聚合中加入少量第二环氧化物可以得到可熔融加工的聚亚烷基碳酸酯三元共聚物，可以在没有广泛热分解的情况下进行加工。 本发明在诸如注塑，吹塑和薄膜制造的热塑性应用中具有特别的用途。
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公开(公告)号：US06717023B2
公开(公告)日：2004-04-06
申请号：US10350502
申请日：2003-01-24
IPC分类号： C07C1207
CPC分类号： C10G3/60 , B01J29/85 , B01J29/90 , B01J38/30 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/62 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/20 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention provides a method for converting a feed containing oxygenates to olefins and comprises the following steps: providing a feed including an oxygenate; contacting the feed in a reactor apparatus with a catalyst including a molecular sieve, the contacting taking place under conditions effective to convert the oxygenate to a product including a light olefin, the conditions including a gas superficial velocity of at least two meters per second at at least one point in the reaction zone; and recirculating a first portion of the catalyst to recontact the feed.
摘要翻译： 本发明提供一种将含有含氧物的进料转化为烯烃的方法，包括以下步骤：提供包含含氧化合物的进料; 将反应器装置中的进料与包含分子筛的催化剂接触，在有效地将含氧化合物转化为包含轻质烯烃的产物的条件下进行接触，所述条件包括在至少两米/秒的气体空塔速度 反应区至少有一点; 并再循环催化剂的第一部分以重新进料。
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4.发明授权Method for producing a vanadium-titanium-tin catalyst exhibiting improved intrinsic surface area 失效显示改善的本征表面积的钒 - 钛 - 锡催化剂的制备方法
公开(公告)号：US4448898A
公开(公告)日：1984-05-15
申请号：US386168
申请日：1982-06-07
申请人： Hsiang-Ning Sun
发明人： Hsiang-Ning Sun
CPC分类号： B01J23/22
摘要： Mixed vanadium-titanium-tin oxides catalysts having intrinsic surface areas before surface modification, greater than about 40 m.sup.2 /gram are disclosed. These catalysts are suitable for use in the preparation of acetic acid by gas-phase oxidation of butenes.
摘要翻译： 公开了在表面改性之前具有大于约40m 2 / g的固有表面积的混合的钒 - 钛 - 锡氧化物催化剂。 这些催化剂适用于通过丁烯气相氧化制备乙酸。
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公开(公告)号：US07102051B2
公开(公告)日：2006-09-05
申请号：US10910813
申请日：2004-08-03
申请人： Stephen N. Vaughn , John Di-Yi Ou , Jar-Lin Kao , Hsiang-Ning Sun
发明人： Stephen N. Vaughn , John Di-Yi Ou , Jar-Lin Kao , Hsiang-Ning Sun
IPC分类号： C07C1/00
CPC分类号： C10G3/49 , B01J29/04 , B01J29/06 , B01J29/70 , B01J29/85 , B01J31/0274 , B01J2229/123 , B01J2229/16 , B01J2229/32 , C01B37/00 , C01B39/026 , C07C1/20 , C07C2529/70 , C07C2529/85 , C10G2300/4012 , C10G2300/4018 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： This invention is directed to a molecular sieve composition or a catalyst containing molecular sieve which has a relatively high residual silica index, preferably at least about 1.5. The molecular sieve or catalyst can be made by contacting a template-containing molecular sieve with a silicon containing material having an average kinetic diameter that is larger than the average pore diameter of the sieve or catalyst, and heating to leave residual silica at the sieve or catalyst surface. The molecular sieve or catalyst is particularly effective in making an olefin product from an oxygenate feedstock.
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6.发明授权Formation of discrete polyalkylene carbonate particles by solvent/non-solvent precipitation 失效通过溶剂/非溶剂沉淀法形成离散聚碳酸亚烷基酯颗粒
公开(公告)号：US4975525A
公开(公告)日：1990-12-04
申请号：US329238
申请日：1989-03-27
CPC分类号： C08J3/14 , C08J3/091 , C08J2369/00
摘要： Discrete, non-agglomerating particles of polyalkylene carbonate are produced by solvent/non-solvent precipitation using certain solvent/non-solvent systems. The free-flowing particles obtaine are from 30 to 3000 microns in diameter and are suitable for use in a variety of applications, particularly the preparation of foamed articles.
摘要翻译： 通过使用某些溶剂/非溶剂系统的溶剂/非溶剂沉淀来制备聚碳酸亚烷基酯的离散的非聚集颗粒。 自由流动的颗粒直径为30至3000微米，适用于各种应用，特别是泡沫制品的制备。
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7.发明授权Process for preparing polycarbonate terpolymer foam suitable for lost foam casting 失效制备适合于失去泡沫塑料的聚碳酸酯三元共聚物泡沫的方法
公开(公告)号：US4763715A
公开(公告)日：1988-08-16
申请号：US132098
申请日：1987-12-14
CPC分类号： C08J9/18 , B22C7/023 , C08G64/0208 , C08J2369/00
摘要： The evaporative casting of molten metals has been shown to produce castings having smooth surfaces without any sign of carbon deposits thereon by using a terpolymer polycarbonate prepared from cyclopentene oxide or cyclohexene oxide, ethylene oxide, propylene oxide, or butylene oxide, and carbon dioxide in making patterns for the lost foam casting process.
摘要翻译： 熔融金属的蒸发铸造已经显示出通过使用由环戊烯氧化物或环氧环己烷，环氧乙烷，环氧丙烷或环氧丁烷制备的三元共聚物和二氧化碳制备具有光滑表面的铸件，而没有碳沉积在其上的任何迹象。 失去泡沫铸造工艺的图案。
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公开(公告)号：US06455747B1
公开(公告)日：2002-09-24
申请号：US09414256
申请日：1999-10-07
IPC分类号： C07C170
CPC分类号： C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/60 , C10G3/62 , C10G2300/4006 , C10G2300/4018 , C10G2300/4081 , C10G2300/802 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The present invention provides a method for converting a feed containing oxygenates to olefins and comprises the following steps: providing a feed including an oxygenate; contacting the feed in a reactor apparatus with a catalyst including a molecular sieve, the contacting taking place under conditions effective to convert the oxygenate to a product including a light olefin, the conditions including a gas superficial velocity of at least two meters per second; and recirculating a first portion of the catalyst to recontact the feed.
摘要翻译： 本发明提供一种将含有含氧物的进料转化为烯烃的方法，包括以下步骤：提供包含含氧化合物的进料; 使反应器装置中的进料与包含分子筛的催化剂接触，在有效地将含氧化合物转化为包含轻质烯烃的产物的条件下进行接触，所述条件包括至少两米/秒的气体空塔速度; 并再循环催化剂的第一部分以重新进料。
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公开(公告)号：US06448460B2
公开(公告)日：2002-09-10
申请号：US09805215
申请日：2001-03-14
申请人： Marcel J. G. Janssen , Machteld M. Mertens , Cornelius W. M. Van Oorschot , Stephen N. Vaughn , Hsiang-Ning Sun , David R. Lumgair
发明人： Marcel J. G. Janssen , Machteld M. Mertens , Cornelius W. M. Van Oorschot , Stephen N. Vaughn , Hsiang-Ning Sun , David R. Lumgair
IPC分类号： C07C120
CPC分类号： C10G3/49 , B01J29/85 , B01J37/082 , B01J37/084 , B01J37/14 , B01J2229/40 , C07C1/20 , C07C2529/85 , C10G2300/703 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： This invention is directed to a molecular sieve having acid catalyst sites and a method of maintaining the acid catalyst sites of a template-containing silicoaluminophosphate molecular sieve. The method comprises providing a template-containing silicoaluminophosphate molecular sieve and heating the molecular sieve in an oxygen depleted environment under conditions effective to maintain or preserve the number of acid catalyst sites. The heated molecular sieve exhibits at least one peak in the infrared region in a range of from 3630 cm−1 to 3580 cm−1. Preferably, the heated molecular sieve exhibits a combined peak area in the 3630 cm−1 to 3580 cm−1 range of at least 10% of a total peak area of all peaks in an infrared region between 4000 cm−1 to 3400 cm−1.
摘要翻译： 本发明涉及具有酸催化剂位点的分子筛和保持含有模板的硅铝磷酸盐分子筛的酸催化剂位点的方法。 该方法包括提供含模板的硅铝磷酸盐分子筛，并在有效维持或保持酸催化剂位点的数量的条件下在贫氧环境中加热分子筛。 加热的分子筛在3630cm-1至3580cm -1的范围内显示红外区域中的至少一个峰。 优选地，加热的分子筛表现出在3630cm -1至3580cm -1范围内的组合峰面积，其在4000cm -1至3400cm -1之间的红外区域中的所有峰的总峰面积的至少10％ 。
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公开(公告)号：US06225254B1
公开(公告)日：2001-05-01
申请号：US09392981
申请日：1999-09-09
申请人： Marcel J. G. Janssen , Machteld M. Mertens , Cornelius W. M. Van Oorschot , Stephen N. Vaughn , Hsiang-Ning Sun , David R. Lumgair
发明人： Marcel J. G. Janssen , Machteld M. Mertens , Cornelius W. M. Van Oorschot , Stephen N. Vaughn , Hsiang-Ning Sun , David R. Lumgair
IPC分类号： B01J27182
CPC分类号： C10G3/49 , B01J29/85 , B01J37/082 , B01J37/084 , B01J37/14 , B01J2229/40 , C07C1/20 , C07C2529/85 , C10G2300/703 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： This invention is directed to a molecular sieve having acid catalyst sites and a method of maintaining the acid catalyst sites of a template-containing silicoaluminophosphate molecular sieve. The method comprises providing a template-containing silicoaluminophosphate molecular sieve and heating the molecular sieve in an oxygen depleted environment under conditions effective to maintain or preserve the number of acid catalyst sites. The heated molecular sieve exhibits at least one peak in the infrared region in a range of from 3630 cm−1 to 3580 cm−1. Preferably, the heated molecular sieve exhibits a combined peak area in the 3630 cm−1 to 3580 cm−1 range of at least 10% of a total peak area of all peaks in an infrared region between 4000 cm−1 to 3400 cm−1.
摘要翻译： 本发明涉及具有酸催化剂位点的分子筛和保持含有模板的硅铝磷酸盐分子筛的酸催化剂位点的方法。 该方法包括提供含模板的硅铝磷酸盐分子筛，并在有效维持或保持酸催化剂位点的数量的条件下在贫氧环境中加热分子筛。 加热的分子筛在3630cm-1至3580cm -1的范围内显示红外区域中的至少一个峰。 优选地，加热的分子筛表现出在3630cm -1至3580cm -1范围内的组合峰面积，其在4000cm -1至3400cm -1之间的红外区域中的所有峰的总峰面积的至少10％ 。
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