POLY(ARYLENE ETHER) COMPOSITION AND A COVERED CONDUCTOR WITH FLEXIBLE COVERING WALL AND LARGE SIZE CONDUCTOR
    3.
    发明申请
    POLY(ARYLENE ETHER) COMPOSITION AND A COVERED CONDUCTOR WITH FLEXIBLE COVERING WALL AND LARGE SIZE CONDUCTOR 有权
    POLY(ARYLENE ETHER)组合物和具有柔性覆盖壁和大尺寸导体的覆盖导体

    公开(公告)号:US20100122845A1

    公开(公告)日:2010-05-20

    申请号:US12273792

    申请日:2008-11-19

    摘要: Disclosed herein is covered conductors with a normal to large conductor cross-section area (AWG 5 to AWG 24). The thickness of the coating can be, for example, 0.25 to 8.0 millimeter (mm). Also disclosed are a thermoplastic composition comprising a poly(arylene ether) having an intrinsic viscosity greater than 0.25 dl/g as measured in chloroform at 25° C., a styrenic resin, a polyolefin resin, and optionally a flame retardant, a compatibilizer, or a combination of a flame retardant and a compatibilizer. The coating comprises the thermoplastic composition described above.

    摘要翻译: 这里公开了具有法向大导体横截面积(AWG 5至AWG 24)的被覆导体。 涂层的厚度可以是例如0.25至8.0毫米(mm)。 还公开了一种热塑性组合物,其包含在25℃在氯仿中测定的特性粘度大于0.25dl / g的聚(亚芳基醚),苯乙烯树脂,聚烯烃树脂和任选的阻燃剂,增容剂, 或阻燃剂和增容剂的组合。 涂层包含上述热塑性组合物。

    POLY(ARYLENE ETHER) COMPOSITION AND A COVERED CONDUCTOR WITH THIN WALL AND SMALL SIZE CONDUCTOR
    4.
    发明申请
    POLY(ARYLENE ETHER) COMPOSITION AND A COVERED CONDUCTOR WITH THIN WALL AND SMALL SIZE CONDUCTOR 审中-公开
    POLY(ARYLENE ETHER)组合物和带有薄壁和小尺寸导体的覆盖导体

    公开(公告)号:US20100012373A1

    公开(公告)日:2010-01-21

    申请号:US12503869

    申请日:2009-07-16

    IPC分类号: H01B7/00 H01B3/30

    摘要: A covered conductor comprising: a conductor; and a covering comprising a thermoplastic composition and the thermoplastic composition comprises: a poly(arylene ether) having an intrinsic viscosity greater than 0.25 dl/g as measured in chloroform at 25° C., a poly(alkenyl aromatic)polymer, a polyolefin resin and optionally a flame retardant and a compatibilizer, wherein the covered conductor essentially meets the performance requirement of ISO 6722, wherein the covering is disposed over the conductor, wherein the conductor has a cross section that meets as least one of following: (i) American Wire Gauge (AWG) from AWG 56 to AWG 26, (ii) a cross-section area from 0.000122 to 0.128 mm2 (corresponding to AWG 56 to AWG 26 according to ASTM B256-02); (iii) a nominal diameter from 0.0124 to 0.404 mm (corresponding to AWG 56 to AWG 26 according to UL 1581, 4th edition, Table 20.1). The covering of the covered conductor has a thickness from about 0.010 to about 0.85 mm. An automotive wire harness assembly comprises the covered conductor. An “end use equipment” comprises the wire assembly.

    摘要翻译: 一种覆盖导体,包括:导体; 和包含热塑性组合物和热塑性组合物的覆盖物包括:在25℃在氯仿中测定的特性粘度大于0.25dl / g的聚(亚芳基醚),聚(链烯基芳族)聚合物,聚烯烃树脂 以及任选的阻燃剂和相容剂,其中所述被覆盖的导体基本上满足ISO 6722的性能要求,其中所述覆盖物设置在所述导体上,其中所述导体具有满足以下至少一个的横截面:(i)美国 从AWG 56到AWG 26的线规(AWG),(ii)0.000122至0.128mm 2的横截面积(对应于根据ASTM B256-02的AWG 56至AWG 26); (iii)公称直径为0.0124至0.404mm(对应于根据UL 1581的AWG 56至AWG 26,第4版,表20.1)。 覆盖导体的覆盖层具有约0.010至约0.85mm的厚度。 汽车线束组件包括被覆导体。 “最终用途设备”包括电线组件。

    Poly(phenylene ether)-polysiloxane composition and method
    5.
    发明授权
    Poly(phenylene ether)-polysiloxane composition and method 有权
    聚(苯醚) - 聚硅氧烷组合物和方法

    公开(公告)号:US08722837B2

    公开(公告)日:2014-05-13

    申请号:US13362426

    申请日:2012-01-31

    IPC分类号: C08G65/38 C08G77/46

    摘要: A composition is prepared by oxidative copolymerization of specific amounts of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and a hydroxyaryl-terminated polysiloxane. The composition exhibits an increased heat resistance relative to a corresponding composition prepared by copolymerizing 2,6-dimethylphenol and hydroxyaryl-terminated polysiloxane, without 2,3,6-trimethylphenol. The composition is useful as a flame-retardant additive in polymer compositions that require high heat resistance.

    摘要翻译: 通过特定量的2,6-二甲基苯酚,2,3,6-三甲基苯酚和羟基芳基封端的聚硅氧烷的氧化共聚制备组合物。 该组合物相对于不含2,3,6-三甲基苯酚共聚2,6-二甲基苯酚和羟基芳基封端的聚硅氧烷制备的相应组合物,具有增加的耐热性。 该组合物可用作需要高耐热性的聚合物组合物中的阻燃添加剂。

    Poly(arylene ether)-polysiloxane composition and method
    6.
    发明授权
    Poly(arylene ether)-polysiloxane composition and method 有权
    聚(亚芳基醚) - 聚硅氧烷组合物和方法

    公开(公告)号:US08669332B2

    公开(公告)日:2014-03-11

    申请号:US13169137

    申请日:2011-06-27

    IPC分类号: C08L71/12 C08G77/46

    摘要: A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

    摘要翻译: 包括聚(亚芳基醚) - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间,其特征在于第一温度,加入时间之后的生成周期,并且特征在于大于第一温度的第二温度,以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间,温度以每分钟约0.01至约0.35℃的平均速率增加,这提高了聚(亚芳基醚) - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD
    7.
    发明申请
    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD 有权
    聚(亚乙基醚) - 聚硅氧烷组合物和方法

    公开(公告)号:US20120329961A1

    公开(公告)日:2012-12-27

    申请号:US13169137

    申请日:2011-06-27

    摘要: A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

    摘要翻译: 包含聚(亚芳基醚) - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间,其特征在于第一温度,加入时间之后的生成周期,并且特征在于大于第一温度的第二温度,以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间,温度以每分钟约0.01至约0.35℃的平均速率增加,这提高了聚(亚芳基醚) - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

    Morpholine-substituted poly(arylene ether) and method for the preparation thereof
    9.
    发明授权
    Morpholine-substituted poly(arylene ether) and method for the preparation thereof 有权
    吗啉取代的聚(亚芳基醚)及其制备方法

    公开(公告)号:US08017716B2

    公开(公告)日:2011-09-13

    申请号:US12495980

    申请日:2009-07-01

    IPC分类号: C08G65/38 C08G63/02

    CPC分类号: C08G65/46

    摘要: A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

    摘要翻译: 使用含吗啉的聚合催化剂制备的聚(2,6-二甲基-1,4-亚苯基醚)具有单分子分子量分布,具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚(2,6-二甲基-1,4-亚苯基醚)相比,聚(2,6-二甲基-1,4-亚苯基醚) 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚(2,6-二甲基-1,4-亚苯基醚)相比,本发明的聚(2,6-二甲基-1,4-亚苯基醚)表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。

    MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF
    10.
    发明申请
    MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF 有权
    吗啉取代的聚(亚乙基醚)及其制备方法

    公开(公告)号:US20110003962A1

    公开(公告)日:2011-01-06

    申请号:US12495980

    申请日:2009-07-01

    IPC分类号: C08G65/00

    CPC分类号: C08G65/46

    摘要: A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

    摘要翻译: 使用含吗啉的聚合催化剂制备的聚(2,6-二甲基-1,4-亚苯基醚)具有单分子分子量分布,具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚(2,6-二甲基-1,4-亚苯基醚)相比,聚(2,6-二甲基-1,4-亚苯基醚) 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚(2,6-二甲基-1,4-亚苯基醚)相比,本发明的聚(2,6-二甲基-1,4-亚苯基醚)表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。