公开(公告)号：US5595634A

公开(公告)日：1997-01-21

申请号：US500101

申请日：1995-07-10

Applicant: Dennis Hearn ,  Gary R. Gildert ,  Hugh M. Putman

Inventor： Dennis Hearn ,  Gary R. Gildert ,  Hugh M. Putman

IPC: B01D3/00 ,  B01J8/04 ,  B01J23/56 ,  B01J23/755 ,  C07B61/00 ,  C07C5/13 ,  C07C7/163 ,  C07C7/167 ,  C07C11/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/40 ,  C10G65/00 ,  C10G65/06 ,  C10G67/02 ,  B01D3/34 ,  C01G7/00 ,  C07C5/22

CPC classification number: C07C7/167 ,  B01D3/009 ,  B01J8/0453 ,  C07C7/163 ,  C07C2523/44 ,  C07C2523/755 ,  C10G2300/4087 ,  C10G2400/02 ,  Y02P20/127 ,  Y10S203/06

Abstract: A process for treating C.sub.3 to C.sub.12 petroleum fractions, such as a light cracked naphtha to be used as an etherification feed stock in which H.sub.2 S is removed by distillation of at least the C.sub.3 fraction and mercaptans and diolefins are removed simultaneously in a distillation column reactor using a dual catalyst bed. The mercaptans and H.sub.2 S are reacted with the diolefins in the presence of a reduced nickel catalyst to form sulfides which are higher boiling than the portion of the feed which is fractionated to an upper hydrogenation catalyst bed of palladium for hydrogenating diolefins and acetylenes. The higher boiling sulfides are removed as bottoms along with heavier materials. Any diolefins not converted to sulfides and acetylenes are selectively hydrogenated to mono-olefins in the presence of a palladium oxide catalyst in an upper bed, producing overheads, substantially free of sulfur compounds, diolefins and acetylenes.

Abstract translation: 一种用于处理C3至C12石油馏分的方法，例如用作通过蒸馏至少C3馏分和硫醇和二烯烃除去H 2 S的醚化原料的轻质裂化石脑油，在蒸馏塔反应器中同时除去，使用 双催化剂床。 在还原的镍催化剂的存在下，硫醇和H 2 S与二烯烃反应形成沸点高于进料的部分沸点的硫化物，该部分被分馏到用于氢化二烯烃和乙炔的钯的上加氢催化剂床。 较高沸点的硫化物作为底部以及更重的材料被去除。 任何未转化为硫化物和炔烃的二烯烃在上层床中在氧化钯催化剂存在下选择性氢化成单烯烃，产生基本上不含硫化合物，二烯烃和炔烃的塔顶馏出物。

公开(公告)号：US07196035B2

公开(公告)日：2007-03-27

申请号：US11249867

申请日：2005-10-13

Applicant: J. Yong Ryu ,  Hugh M. Putman

Inventor： J. Yong Ryu ,  Hugh M. Putman

IPC: B01J23/755

CPC classification number: C07C5/05 ,  C07C5/09 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/84 ,  C07C2523/85 ,  C07C2523/885

Abstract: Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

Abstract translation: 公开了用于氢化反应的改进的Ni催化剂。 该催化剂可用于氢化，例如在粗烯烃和二烯烃流中的炔属杂质的选择性氢化。 催化剂通过在具有以下具体物理性质的多孔载体上沉积镍来制备; BET表面积为30至约100m 2 / g，总氮孔体积为0.4至约0.9cc / g，平均孔径为约110至450有或没有 一种或多种选自Cu，Re，Pd，Zn，Mg，Mo，Ca和Bi的元素的改性剂。

公开(公告)号：US5877363A

公开(公告)日：1999-03-02

申请号：US717934

申请日：1996-09-23

Applicant: Gary R. Gildert ,  Hugh M. Putman ,  Dennis Hearn

Inventor： Gary R. Gildert ,  Hugh M. Putman ,  Dennis Hearn

IPC: B01J23/38 ,  B01D3/00 ,  C07C7/10 ,  C07C7/163 ,  C07C7/167 ,  C07C9/02 ,  C10G7/00 ,  C10G45/32 ,  C10G45/40 ,  C10G70/02 ,  C07C5/08 ,  B01D3/34

CPC classification number: B01D3/009 ,  C07C7/163 ,  C07C7/167 ,  C10G45/32 ,  C10G45/40 ,  C10G70/02 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  Y02P20/127 ,  Y10S203/06

Abstract: A process for the removal of vinylacetylene, ethylacetylene and 1,2-butadiene from C.sub.4 aliphatic hydrocarbon streams comprising, concurrently: (1) feeding hydrogen and a hydrocarbon stream comprising C.sub.4 hydrocarbons including butanes, butenes, butadienes and vinylacetylene to a distillation column reactor containing a bed comprising a hydrogenation catalyst of the type characterized by platinum, palladium or rhodium which is prepared as a distillation structure to selectively hydrogenate a portion of the vinylacetylene and the 1,2-butadiene and (2) fractionally distilling the reaction mixture to remove a heavier fraction and removing a fraction overhead comprising substantially all of the C.sub.4.

Abstract translation: 一种从C4脂族烃流中除去乙烯基乙炔，乙乙炔和1,2-丁二烯的方法，包括同时：（1）将含有C4烃的氢气和烃流，包括丁烷，丁烯，丁二烯和乙烯基乙炔加入到含有 包含以铂，钯或铑为特征的类型的加氢催化剂的床，其被制备为蒸馏结构以选择性氢化一部分乙烯基乙炔和1,2-丁二烯，和（2）分级蒸馏反应混合物以除去 较重的馏分并除去基本上全部C4的塔顶馏分。

公开(公告)号：US5773670A

公开(公告)日：1998-06-30

申请号：US398690

申请日：1995-03-06

Applicant: Gary R. Gildert ,  Dennis Hearn ,  Hugh M. Putman

Inventor： Gary R. Gildert ,  Dennis Hearn ,  Hugh M. Putman

IPC: B01D3/00 ,  C07C5/10 ,  C07C209/72

CPC classification number: C07C209/72 ,  B01D3/009 ,  C07C5/10 ,  C07C2101/14 ,  Y02P20/127 ,  Y10S203/06

Abstract: A process for the hydrogenation of unsaturated cyclic and polycyclic compounds to saturates is provided wherein the reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed. Although no separation is obtained all of the advantages of concurrent reaction with distillation are achieved.

Abstract translation: 提供了将不饱和环和多环化合物氢化成饱和物的方法，其中反应器在压力下操作，其中反应混合物在0至350℃的约0.1psi至小于70psia的低氢分压下沸腾 psig 提供催化剂作为催化蒸馏结构，使得反应同时进行蒸馏。 塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。 虽然没有分离，但是实现了与蒸馏同时反应的所有优点。

公开(公告)号：US07297824B2

公开(公告)日：2007-11-20

申请号：US11171797

申请日：2005-06-30

Applicant: J. Yong Ryu ,  Hugh M. Putman

Inventor： J. Yong Ryu ,  Hugh M. Putman

IPC: C07C5/08

CPC classification number: C07C5/05 ,  C07C5/09 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/84 ,  C07C2523/85 ,  C07C2523/885

Abstract: Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

公开(公告)号：US5961815A

公开(公告)日：1999-10-05

申请号：US717935

申请日：1996-09-23

Applicant: Thomas P. Hickey ,  Dennis Hearn ,  Hugh M. Putman

Inventor： Thomas P. Hickey ,  Dennis Hearn ,  Hugh M. Putman

IPC: B01J23/85 ,  B01D3/00 ,  B01J8/02 ,  B01J23/88 ,  C10G45/00 ,  C10G47/00 ,  C10G47/02 ,  C10G11/02 ,  C10G29/04

CPC classification number: B01D3/009 ,  C10G47/00

Abstract: The hydroconversion of heavy petroliferous stocks boiling mainly above 400.degree. F. is carried out in a distillation column reactor where concurrently a petroleum stream is fed into a feed zone; hydrogen is fed at a point below said feed zone; the petroleum stream is distilled and contacted in the presence of a cracking catalyst prepared in the form of a catalytic distillation structure at total pressure of less than about 300 psig and a hydrogen partial pressure in the range of 1.0 to less than 70 psia and a temperature in the range of 400 to 1000.degree. F. whereby a portion of the petroleum stream is cracked to lighter products boiling below the boiling point of the feed and products are distilled to remove a vaporous overhead stream comprising products mainly boiling below the boiling point of the feed and a liquid bottoms stream.

Abstract translation: 主要在400°F以上沸腾的重质含油量的加氢转化在蒸馏塔反应器中进行，同时将石油流进料到进料区; 氢在所述进料区下方的一点进料; 在催化蒸馏结构形式的裂化催化剂存在下蒸馏并接触石油物流，其总压力小于约300psig，氢分压为1.0至小于70psia，温度为 在400至1000°F的范围内，由此一部分石油流裂化成低于进料沸点沸点的较轻的产物，并将产物蒸馏以除去蒸气塔顶物流，其包含主要沸点低于 饲料和液体底部物流。

公开(公告)号：US5779883A

公开(公告)日：1998-07-14

申请号：US819491

申请日：1997-03-17

Applicant: Dennis Hearn ,  Hugh M. Putman

Inventor： Dennis Hearn ,  Hugh M. Putman

IPC: B01D3/00 ,  B01J3/00 ,  B01J8/02 ,  C10G45/04 ,  C10G45/02

CPC classification number: C10G45/04 ,  B01D3/009 ,  B01J3/006 ,  B01J8/02 ,  B01J2208/00247 ,  B01J2208/00539 ,  B01J2208/00557

Abstract: A process for the hydrodesulfurization of petroleum streams is disclosed wherein the sulfur containing petroleum stream is contacted along with hydrogen at a partial pressure of less than 70 psig in a distillation column reactor containing a hydrodesulfurization catalyst in the form of a catalytic distillation structure.

Abstract translation: 公开了一种用于石油流加氢脱硫的方法，其中在含有催化蒸馏结构形式的加氢脱硫催化剂的蒸馏塔反应器中，含硫石油物流与低于70psig分压的氢气一起接触。

公开(公告)号：US08227650B2

公开(公告)日：2012-07-24

申请号：US12859975

申请日：2010-08-20

Applicant: Hugh M. Putman ,  John R. Adams

Inventor： Hugh M. Putman ,  John R. Adams

IPC: C07C5/09

CPC classification number: C10G45/38 ,  B01J23/755 ,  B01J23/78 ,  B01J23/80 ,  B01J23/8437 ,  B01J23/883 ,  B01J23/892 ,  B01J35/1014 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  C10G45/36 ,  C10G45/40 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/4087 ,  C10G2400/20

Abstract: A process for the selective hydrogenation of dienes and acetylenes in a mixed hydrocarbon stream from a pyrolysis steam cracker in which a front end a one step acetylene hydrogenation is carried out using catalyst comprising (A) 1 to 30 wt. % based on the total weight of the catalyst of a catalytic component of nickel only or nickel and one or more elements selected from the group consisting of copper, rhenium, palladium, zinc, gold, silver, magnesium, molybdenum, calcium and bismuth deposited on (B) a support having the a BET surface area of from 1 to about 100 m2/gram, total nitrogen pore volume of from 0.2 to about 0.9 cc/gram and an average pore diameter of from about 110 to 450 Å under conditions of temperature and pressure to selectively hydrogenate acetylenes and dienes. The process hydrogenates the dienes and acetylenes to olefins without loss of ethylene and propylene in the light and heavy products which eliminates the need for further processing of the heavier stream. In addition the amount of polymerization in the lower part of the distillation column reactor is reduced.

Abstract translation: 在来自热解蒸汽裂化器的混合烃流中二烯和乙炔的选择性加氢的方法，其中前端使用包含（A）1-30重量％的催化剂进行一步乙炔氢化。 基于仅镍或镍的催化组分的催化剂的总重量和选自铜，铼，钯，锌，金，银，镁，钼，钙和铋的一种或多种元素的％ （B）具有1至约100m 2 / g的BET表面积，0.2至约0.9cc / g的总氮孔体积和约110至450的平均孔径的载体在温度条件下 以及选择性氢化炔烃和二烯烃的压力。 该方法将二烯和乙炔氢化成烯烃，而在轻质和重质产物中不损失乙烯和丙烯，这消除了对较重物流的进一步加工的需要。 此外，蒸馏塔反应器下部的聚合量降低。

公开(公告)号：US06583325B1

公开(公告)日：2003-06-24

申请号：US10087371

申请日：2002-03-01

Applicant: Lawrence A. Smith, Jr. ,  Hugh M. Putman ,  Henry J. Semerak ,  Clifford S. Crossland

Inventor： Lawrence A. Smith, Jr. ,  Hugh M. Putman ,  Henry J. Semerak ,  Clifford S. Crossland

IPC: C07C4100

CPC classification number: B01D3/009 ,  B01D3/146 ,  C07C41/06 ,  C07C41/42 ,  Y02P20/127 ,  C07C43/046

Abstract: A process for the production of tertiary ethers from the reaction of isoolefins with lower alcohols, such as methanol, uses two distillation column reactors in series to maximize conversion, especially for isopentenes and isohexenes. The second distillation column reactor may be concurrently used as a C5 polishing reactor and a reactor for producing MTBE or ETBE from isobutene, for example.

Abstract translation: 从异烯烃与低级醇如甲醇的反应生产叔醚的方法使用两个串联的蒸馏塔反应器，以使转化率最大化，特别是对于异戊烯和异己烯。 第二蒸馏塔反应器可以同时用作C5抛光反应器和用于从异丁烯生产MTBE或ETBE的反应器。

公开(公告)号：US06338793B1

公开(公告)日：2002-01-15

申请号：US09692252

申请日：2000-10-19

Applicant: Hugh M. Putman

Inventor： Hugh M. Putman

IPC: C10G4502

CPC classification number: C10G49/002 ,  C08F110/06 ,  C10G2300/4087 ,  C10G2400/04 ,  C08F2500/12

Abstract: A process for the hydrodesulfurization of a diesel boiling range petroleum fraction wherein the hydrodesulfurization is carried out concurrently with a fractional distillation in a distillation column reactor containing a catalyst bed. The diesel is fed above the catalyst bed and hydrogen is fed below the bed. The heat for the distillation is provided by the heat of reaction of the hydrodesulfurization.

Abstract translation: 一种柴油沸程石油馏分的加氢脱硫方法，其中加氢脱硫在含有催化剂床的蒸馏塔反应器中与分馏同时进行。 柴油进料到催化剂床上方，氢气被送入床底。 蒸馏的热量由加氢脱硫反应的热量提供。