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17 条记录 (耗时 0.022 秒)

    Hydrogenation of unsaturated cyclic compounds
    3.
    发明授权
    Hydrogenation of unsaturated cyclic compounds 失效
    不饱和环化合物的氢化

    公开(公告)号：US5773670A

    公开(公告)日：1998-06-30

    申请号：US398690

    申请日：1995-03-06

    申请人： Gary R. Gildert ,  Dennis Hearn ,  Hugh M. Putman

    发明人： Gary R. Gildert ,  Dennis Hearn ,  Hugh M. Putman

    IPC分类号： B01D3/00 ,  C07C5/10 ,  C07C209/72

    CPC分类号： C07C209/72 ,  B01D3/009 ,  C07C5/10 ,  C07C2101/14 ,  Y02P20/127 ,  Y10S203/06

    摘要： A process for the hydrogenation of unsaturated cyclic and polycyclic compounds to saturates is provided wherein the reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed. Although no separation is obtained all of the advantages of concurrent reaction with distillation are achieved.

    摘要翻译： 提供了将不饱和环和多环化合物氢化成饱和物的方法，其中反应器在压力下操作，其中反应混合物在0至350℃的约0.1psi至小于70psia的低氢分压下沸腾 psig 提供催化剂作为催化蒸馏结构，使得反应同时进行蒸馏。 塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。 虽然没有分离，但是实现了与蒸馏同时反应的所有优点。

    Selective hydrogenation of aromatics contained in hydrocarbon streams
    4.
    发明授权
    Selective hydrogenation of aromatics contained in hydrocarbon streams 失效
    碳氢化合物流中芳烃选择性加氢

    公开(公告)号：US5856602A

    公开(公告)日：1999-01-05

    申请号：US711101

    申请日：1996-09-09

    申请人： Gary R. Gildert ,  Hugh M. Putman ,  Dennis Hearn

    发明人： Gary R. Gildert ,  Hugh M. Putman ,  Dennis Hearn

    IPC分类号： C07C5/10 ,  C07B61/00 ,  C07C7/04 ,  C07C13/18 ,  C10G45/44

    CPC分类号： C10G45/44 ,  Y02P20/127 ,  Y10S203/06

    摘要： A process for the hydrogenation of a selected aromatic, such as benzene contained in a naphtha stream to cyclohexane wherein the distillation column reactor is operated such that the portion of the naphtha containing the benzene is maintained in the catalyst bed such that essentially only benzene is hydrogenated. The reactor is operated at a pressure wherein the reaction mixture is boiling under low hydrogen partial pressure in the range of about 0.1 psi to less than 70 psia at 0 to 350 psig. The catalyst is provided as a catalytic distillation structure such that the reaction is concurrently occurring with a distillation. A portion of the overheads is returned as reflux to provide cooling within the catalyst bed and concurrent condensation of some of the gaseous material within the bed.

    摘要翻译： 将选择的芳族化合物（例如包含在石脑油中的苯）氢化成环己烷的方法，其中操作蒸馏塔反应器，使得含有苯的部分石脑油保持在催化剂床中，使得基本上仅苯被氢化 。 反应器在压力下操作，其中反应混合物在0至350psig下在约0.1psi至小于70psia的低氢分压下沸腾。 提供催化剂作为催化蒸馏结构，使得反应同时进行蒸馏。 塔顶馏出物的一部分作为回流返回，以在催化剂床内提供冷却，同时使一些气态物质在床内冷凝。

    Process for removal of mercaptans from hydrocarbon streams
    5.
    发明授权
    Process for removal of mercaptans from hydrocarbon streams 有权
    从烃流中除去硫醇的方法

    公开(公告)号：US06440299B2

    公开(公告)日：2002-08-27

    申请号：US09908022

    申请日：2001-07-18

    申请人： Dennis Hearn ,  Gary R. Gildert ,  Hugh M. Putman

    发明人： Dennis Hearn ,  Gary R. Gildert ,  Hugh M. Putman

    IPC分类号： C10G2700

    CPC分类号： C10G49/002 ,  B01D3/009 ,  C10G2300/4087

    摘要： A process for treating a light cracked naphtha to be used as an etherification feed stock is disclosed in which mercaptans, H2S and diolefins are removed simultaneously in a distillation column reactor using a reduced nickel catalyst. The mercaptans and H2S are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification unit. The higher boiling sulfides are removed as bottoms along with any C6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process.

    摘要翻译： 公开了一种用于处理用作醚化原料的轻质裂化石脑油的方法，其中在使用还原镍催化剂的蒸馏塔反应器中同时除去硫醇，H 2 S和二烯烃。 硫醇和H 2 S与二烯烃反应形成沸点高于用作醚化装置的进料的石脑油部分的硫化物。 较高沸点的硫化物作为底部以及任何C6和较重的材料被除去。 任何未转化成硫化物的二烯烃都被选择性氢化成单烯烃，用于醚化过程。

    Hydroconversion process
    7.
    发明授权
    Hydroconversion process 失效
    加氢转化过程

    公开(公告)号：US5961815A

    公开(公告)日：1999-10-05

    申请号：US717935

    申请日：1996-09-23

    申请人： Thomas P. Hickey ,  Dennis Hearn ,  Hugh M. Putman

    发明人： Thomas P. Hickey ,  Dennis Hearn ,  Hugh M. Putman

    IPC分类号： B01J23/85 ,  B01D3/00 ,  B01J8/02 ,  B01J23/88 ,  C10G45/00 ,  C10G47/00 ,  C10G47/02 ,  C10G11/02 ,  C10G29/04

    CPC分类号： B01D3/009 ,  C10G47/00

    摘要： The hydroconversion of heavy petroliferous stocks boiling mainly above 400.degree. F. is carried out in a distillation column reactor where concurrently a petroleum stream is fed into a feed zone; hydrogen is fed at a point below said feed zone; the petroleum stream is distilled and contacted in the presence of a cracking catalyst prepared in the form of a catalytic distillation structure at total pressure of less than about 300 psig and a hydrogen partial pressure in the range of 1.0 to less than 70 psia and a temperature in the range of 400 to 1000.degree. F. whereby a portion of the petroleum stream is cracked to lighter products boiling below the boiling point of the feed and products are distilled to remove a vaporous overhead stream comprising products mainly boiling below the boiling point of the feed and a liquid bottoms stream.

    摘要翻译： 主要在400°F以上沸腾的重质含油量的加氢转化在蒸馏塔反应器中进行，同时将石油流进料到进料区; 氢在所述进料区下方的一点进料; 在催化蒸馏结构形式的裂化催化剂存在下蒸馏并接触石油物流，其总压力小于约300psig，氢分压为1.0至小于70psia，温度为 在400至1000°F的范围内，由此一部分石油流裂化成低于进料沸点沸点的较轻的产物，并将产物蒸馏以除去蒸气塔顶物流，其包含主要沸点低于 饲料和液体底部物流。

    Ni hydrogenation catalysts, manufacture and use
    10.
    发明授权
    Ni hydrogenation catalysts, manufacture and use 有权
    镍氢化催化剂，制造和使用

    公开(公告)号：US07196035B2

    公开(公告)日：2007-03-27

    申请号：US11249867

    申请日：2005-10-13

    申请人： J. Yong Ryu ,  Hugh M. Putman

    发明人： J. Yong Ryu ,  Hugh M. Putman

    IPC分类号： B01J23/755

    CPC分类号： C07C5/05 ,  C07C5/09 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/84 ,  C07C2523/85 ,  C07C2523/885

    摘要： Improved Ni catalysts for hydrogenation reactions are disclosed. The catalysts are useful for hydrogenation such as selective hydrogenation of acetylenic impurities in crude olefin and diolefin streams. The catalysts are prepared by depositing nickel on a porous support which has the following specific physical properties; BET surface area of from 30 to about 100 m2/g, total nitrogen pore volume of from 0.4 to about 0.9 cc/g, and an average pore diameter of from about 110 to 450 Å with or without modifiers of one or more elements selected from the group consisting of Cu, Re, Pd, Zn, Mg, Mo, Ca and Bi.

    摘要翻译： 公开了用于氢化反应的改进的Ni催化剂。 该催化剂可用于氢化，例如在粗烯烃和二烯烃流中的炔属杂质的选择性氢化。 催化剂通过在具有以下具体物理性质的多孔载体上沉积镍来制备; BET表面积为30至约100m 2 / g，总氮孔体积为0.4至约0.9cc / g，平均孔径为约110至450有或没有 一种或多种选自Cu，Re，Pd，Zn，Mg，Mo，Ca和Bi的元素的改性剂。