公开(公告)号：US20170327645A1

公开(公告)日：2017-11-16

申请号：US15153079

申请日：2016-05-12

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: C08G75/04 ,  C08K3/38

CPC classification number: C08G75/04 ,  C08G73/02 ,  C08K3/38 ,  C08K2003/387

Abstract: Compounds include boronate ester polythioaminals with substituents that include hydrogen, fluorine or substituted or unsubstituted alkyls. The boronate ester polythioaminals have number average molecular weight or weight average molecular weight between about 2,000 to about 160,000.

公开(公告)号：US20170226290A1

公开(公告)日：2017-08-10

申请号：US15016610

申请日：2016-02-05

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Jason T. WERTZ ,  Rudy J. WOJTECKI

IPC: C08G73/06

CPC classification number: C08G73/0644 ,  C08G12/08 ,  C08G73/065 ,  G03F7/038 ,  G03F7/20 ,  G03F7/30

Abstract: This disclosure describes new compositions and methods related to photoresponsive poly(hexahydrotriazines) and related polymers.

公开(公告)号：US20170183451A1

公开(公告)日：2017-06-29

申请号：US15460785

申请日：2017-03-16

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Mareva B. FEVRE ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: C08G73/06 ,  C08L79/08 ,  C08L63/00 ,  C08L79/04

CPC classification number: C08G73/0644 ,  C07D207/452 ,  C08G73/065 ,  C08G73/1039 ,  C08G73/1064 ,  C08G73/1067 ,  C08L63/00 ,  C08L63/04 ,  C08L79/04 ,  C08L79/08

Abstract: In some embodiments, a product, such as a thermoset, has a polyhexahydrotriazine and a self-polymerized cross-linkable polymer. In some embodiments, a product is the reaction product of a diamine, an aldehyde, and a compound having an α,β-unsaturated electron withdrawing moiety.

公开(公告)号：US20170137572A1

公开(公告)日：2017-05-18

申请号：US15157224

申请日：2016-05-17

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Robert J. ONO ,  Rudy J. WOJTECKI

IPC: C08G75/02

CPC classification number: C08G75/02

Abstract: Thioaminal polymers are made from hexahydrotriazine precursors and dithiol precursors. The precursors are blended together and subjected to mild heating to make the polymers. An amine scavenger is used to remove amine byproducts from the reaction, thus promoting polymer growth to high molecular weight. The polymers have the general structure wherein each R1 is independently an organic or hetero-organic group, a plurality of R2 groups are substituents having molecular weight greater than about 120 Daltons, and n is an integer greater than or equal to 1. The polymers may be functionalized by adding a thiol-reactive group to either end or both ends.

公开(公告)号：US20170121461A1

公开(公告)日：2017-05-04

申请号：US15287419

申请日：2016-10-06

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: C08G75/02 ,  C08G75/0236

CPC classification number: C08G75/0272 ,  C08G75/0236 ,  C08G75/04

Abstract: Compounds include polythioaminals of the formula: Each instance of R may be hydrogen or an electron withdrawing group. ‘n’ may be an integer such that the number average molecular weight (Mn) or weight average molecular weight (Mw) is between about 2,000 to about 80,000. Compounds also include polythioaminals of the formula: Each instance of R may be independently selected from the group consisting of —H, —F, —CF3, and —NO2. Each instance of R′ may be independently selected from the group consisting of cycloalkyl, alkyl, alkylene glycol, acrylate, and siloxane. ‘n’ may be an integer such that the number average molecular weight (Mn) or weight average molecular weight (Mw) is between about 2,000 to about 80,000.

公开(公告)号：US20170121445A1

公开(公告)日：2017-05-04

申请号：US15353451

申请日：2016-11-16

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Robert J. ONO ,  Rudy J. WOJTECKI

IPC: C08G12/06 ,  C08G12/00 ,  C07C251/18 ,  C08G12/08 ,  C07C251/24 ,  C07C251/04

CPC classification number: C08G12/06 ,  C07C251/04 ,  C07C251/08 ,  C07C251/18 ,  C07C251/24 ,  C07C2101/14 ,  C07C2601/14 ,  C08G12/00 ,  C08G12/08

Abstract: Methods, compounds, and compositions described herein generally relate to polyalkylamines and syntheses thereof. In some embodiments, a chemical compound has the formula: Each instance of R is independently selected from the group consisting of aryl, alkyl, and polyether. Each instance of R′ is independently selected from the group consisting of hydrogen, alkyl, aryl, cycloalkyl, polyether, and alcohol. Each instance of Q and Z is independently a covalent bond or selected from the group consisting of alkyl and aralkyl.

公开(公告)号：US20170107328A1

公开(公告)日：2017-04-20

申请号：US15249218

申请日：2016-08-26

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: C08G75/02

CPC classification number: C08G75/02 ,  C08G75/04 ,  C08G75/10

Abstract: The disclosure describes new compositions and methods related to polyaminals and related polymers. The compositions are useful as therapeutic/drug conjugates, self-healing materials, reversible crosslinking materials, degradable hydrogels, protective coatings, and as metal scavenging agents. New atom efficient synthetic schemes are disclosed, which yield previously unobtainable high molecular weight polyaminals.

公开(公告)号：US20170096532A1

公开(公告)日：2017-04-06

申请号：US15334156

申请日：2016-10-25

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: C08G75/04

CPC classification number: C08G75/02 ,  C08G75/04 ,  C08G75/10

Abstract: The disclosure describes new compositions and methods related to polyaminals and related polymers. The compositions are useful as therapeutic/drug conjugates, self-healing materials, reversible crosslinking materials, degradable hydrogels, protective coatings, and as metal scavenging agents. New atom efficient synthetic schemes are disclosed, which yield previously unobtainable high molecular weight polyaminals.

公开(公告)号：US20170065722A1

公开(公告)日：2017-03-09

申请号：US14844561

申请日：2015-09-03

Applicant: International Business Machines Corporation

Inventor： Dylan J. BODAY ,  Jeannette M. GARCIA ,  James L. HEDRICK ,  Rudy J. WOJTECKI

IPC: A61K47/48

CPC classification number: A61K47/59 ,  A61K47/20 ,  A61K47/56 ,  A61K47/6923 ,  A61K47/6929 ,  A61K49/0002 ,  A61K49/0017 ,  A61K49/0065 ,  C08G73/0253

Abstract: A functionalized nanomaterial, such as a nanoparticle, can include a polythioaminal functionalized surface. The polythioaminal linked to the surface of the nanomaterial can be bonded to a compound such as therapeutic and/or diagnostic materials. The thiol-based linkages can be used to bond the polythioaminal to both the nanomaterial and the therapeutic and/or diagnostic materials. Polythioaminals can be prepared via reactions of triazine and dithiols. Polythioaminals thus prepared can be further modified to provide linkages to the nanomaterial and other compounds such as medicinal compound, peptides, and dyes. Nanomaterials including such compounds linked thereto via the polythioaminal can be supplied for therapeutic and/or diagnostic purposes to biological target regions.

Abstract translation: 功能化纳米材料，例如纳米颗粒，可以包括聚硫代氨基官能化表面。 与纳米材料表面连接的聚硫代胺可以与化合物如治疗和/或诊断材料结合。 硫醇基键可以用于将聚硫代胺结合到纳米材料和治疗和/或诊断材料两者。 聚硫代胺可以通过三嗪和二硫醇的反应制备。 如此制备的聚硫代胺可进一步修饰以提供与纳米材料和其它化合物如药用化合物，肽和染料的连接。 包括通过聚硫代胺连接的这类化合物的纳米材料可以用于生物靶区域的治疗和/或诊断目的。

公开(公告)号：US20170045300A1

公开(公告)日：2017-02-16

申请号：US14824492

申请日：2015-08-12

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： Dylan J. BODAY ,  Levi A. CAMPBELL ,  Milnes P. DAVID ,  Dustin W. DEMETRIOU ,  Michael J. ELLSWORTH, JR. ,  Roger R. SCHMIDT ,  Robert E. SIMONS ,  Prabjit SINGH ,  Jason T. WERTZ

IPC: F28D7/00 ,  B23P15/26

CPC classification number: B23P15/26 ,  B23P2700/10 ,  F28F3/02 ,  F28F3/12 ,  H01L23/473 ,  H01L23/4735 ,  H05K7/20254 ,  H05K7/20772

Abstract: Liquid-cooled heat sink assemblies are provided which include: a heat transfer element including a heat transfer base with opposite first and second sides and a plurality of thermally conductive fins extending from the first side, and with the second side of the heat transfer base to couple to a component(s) to be cooled. The heat sink assembly further includes a coolant-carrying structure attached to the heat transfer element. The coolant-carrying structure includes a coolant-carrying base, and a coolant-carrying compartment through which liquid coolant flows. The coolant-carrying base includes a plurality of fin-receiving openings sized and positioned for the plurality of thermally conductive fins to extend therethrough. The plurality of thermally conductive fins extend into the coolant-carrying compartment through which the liquid coolant flows. In one or more embodiments, the heat transfer element is a metal structure and the coolant-carrying structure is a plastic structure.

Abstract translation: 提供了液冷式散热器组件，其包括：传热元件，其包括具有相对的第一和第二侧的传热基部和从第一侧延伸的多个导热翅片，以及传热基座的第二侧至 耦合到要冷却的部件。 散热器组件还包括附接到传热元件的冷却剂承载结构。 冷却剂承载结构包括冷却剂承载基座和液体冷却剂流过的冷却剂输送室。 冷却剂承载基座包括多个翅片接收开口，其大小和定位用于多个导热翅片延伸穿过其中。 多个导热翅片延伸到液体冷却剂流过的冷却剂供给室中。 在一个或多个实施例中，传热元件是金属结构，并且冷却剂承载结构是塑料结构。