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21 条记录 (耗时 0.038 秒)

    Heterogeneous alkylation and regeneration of alkylation catalysts
    3.
    发明授权
    Heterogeneous alkylation and regeneration of alkylation catalysts 失效
    烷基化催化剂的非均相烷基化和再生

    公开(公告)号：US5365009A

    公开(公告)日：1994-11-15

    申请号：US48385

    申请日：1993-04-14

    申请人： Ashok Uppal ,  William J. Murphy ,  Joseph P. Boyle

    发明人： Ashok Uppal ,  William J. Murphy ,  Joseph P. Boyle

    IPC分类号： B01J38/04 ,  C07C2/58 ,  B01J29/38 ,  B01J38/14

    CPC分类号： C07C2/58 ,  B01J38/04 ,  C07C2529/00 ,  Y02P20/584

    摘要： An alkylation process which utilizes a solid alkylation catalyst is disclosed. The catalyst, which has carbonaceous material adsorbed thereto, is regenerated by reacting the adsorbed carbonaceous material. The reaction step is accomplished by heating the catalyst in the presence of ozone to form an ozonated hydrocarbon, wherein the ozonated hydrocarbon includes carbonyl carbons. The ozonated hydrocarbon is removed by desorbing the carbonyl carbons from the solid alkylation catalyst. The carbonaceous material is preferably reacted at a temperature ranging from about 20.degree. C. to 200.degree. C. The ozone is preferably in a gaseous stream at a concentration ranging from about 1 to 50 volume percent. The carbonyl components are preferably desorbed from the heated alkylation catalyst by sweeping the catalyst with a desorption fluid.

    摘要翻译： 公开了一种利用固体烷基化催化剂的烷基化方法。 吸附有碳质材料的催化剂通过使吸附的碳质材料反应而再生。 反应步骤通过在臭氧存在下加热催化剂以形成臭氧化烃，其中臭氧化烃包括羰基碳来实现。 通过从固体烷基化催化剂中解吸羰基碳来除去臭氧化烃。 碳质材料优选在约20℃至200℃的温度下反应。臭氧优选为浓度为约1至50体积％的气态物流。 羰基组分优选通过用解吸流体清洗催化剂而从加热的烷基化催化剂中脱附。

    Process for reforming at low severities with high-activity, high-yield, tin modified platinum-iridium catalysts
    4.
    发明授权
    Process for reforming at low severities with high-activity, high-yield, tin modified platinum-iridium catalysts 失效
    用高活性，高收率，锡改性的铂 - 铱催化剂在低严重度下重整的方法

    公开(公告)号：US5269907A

    公开(公告)日：1993-12-14

    申请号：US847541

    申请日：1992-03-06

    申请人： William C. Baird ,  Joseph P. Boyle ,  George A. Swan, III

    发明人： William C. Baird ,  Joseph P. Boyle ,  George A. Swan, III

    IPC分类号： B01J23/62 ,  C10G35/09 ,  C10G59/02 ,  C10G35/085

    CPC分类号： C10G35/09 ,  B01J23/626 ,  C10G59/02

    摘要： A process for reforming a naphtha feed at low severities with tin modified platinum-iridium catalysts. In particular, both high selectivity, and high activity are manifested by such catalysts in reforming a naphtha feed at low severities in the lead reactor, or reactors, of a series of reactors; i.e., within the dehydrogenation and ring isomerization zone, or zones, of a reforming unit. The lead reactors of the series are charged with a tin-containing platinum-iridium catalyst, and the naphtha feed reformed to produce a low RON clear C.sub.5 + liquid reformate. The low octane product of the lead reactors may be transferred to a mogas pool, into blending components, or all or some part of the product further reformed. Preferably, the product is further reformed in a tail reactor, and preferably the tail reactor is charged with a non-tin containing platinum, or platinum-iridium catalyst.

    摘要翻译： 用锡改性的铂 - 铱催化剂将石脑油进料低馏分重整的方法。 特别地，高选择性和高活性都表现在这样的催化剂中，在一系列反应器的引导反应器或反应器中以较低严重性重整石脑油进料; 即在重整单元的脱氢和环异构化区域或区域内。 该系列的引导反应器装有含锡的铂 - 铱催化剂，重新制备石脑油进料以产生低RON透明的C5 +液体重整产物。 引导反应器的低辛烷值产物可以转移到摩尔卡巴池中，混合成分，或进一步重整产物的全部或部分。 优选地，产物在尾反应器中进一步重整，并且优选地，尾反应器装有不含锡的铂或铂 - 铱催化剂。

    Removal of sulfur from recycle gas streams in catalytic reforming
    5.
    发明授权
    Removal of sulfur from recycle gas streams in catalytic reforming 失效
    在催化重整中从循环气流中除去硫

    公开(公告)号：US5043057A

    公开(公告)日：1991-08-27

    申请号：US542499

    申请日：1990-06-25

    申请人： Joseph P. Boyle

    发明人： Joseph P. Boyle

    IPC分类号： C10G35/04 ,  C10G61/02

    CPC分类号： C10G35/04

    摘要： A catalytic reforming process in which sulfur moieties are removed from a gaseous product stream by use of a sulfur trap comprised of about 10 to about 70 wt. % nickel dispersed on a support. The sulfur which is removed is both sulfur which is inherent in the feed as well as sulfur which results from presulfiding the catalyst.

    Regeneration and reactivation of reforming catalysts avoiding iron scale carryover from the regenerator circuit to the reactors
    7.
    发明授权
    Regeneration and reactivation of reforming catalysts avoiding iron scale carryover from the regenerator circuit to the reactors 失效
    重整催化剂的再生和再活化，避免从再生器回路到反应器的铁垢残留

    公开(公告)号：US4769128A

    公开(公告)日：1988-09-06

    申请号：US61580

    申请日：1987-06-15

    申请人： Joseph P. Boyle

    发明人： Joseph P. Boyle

    IPC分类号： C10G35/06 ,  B01J23/96 ,  B01J38/12 ,  C10G35/085 ,  C10G35/09

    CPC分类号： B01J23/96 ,  C10G35/085 ,  Y10S502/516 ,  Y10S502/517

    摘要： Improvements in a reforming process for the regeneration and reactivation of a bed of a reforming catalyst, notably an iridium-containing catalyst, coked and catalytically deactivated during the on-oil portion of a reforming cycle. The reactor containing the catalyst is contained in a multi-reactor unit, the individual reactors of which are connected in series via suitable piping and valving. The reactor can be alternately manifolded with production facilities during the on-oil portion of the operating cycle during which period the catalyst of said reactor becomes coked, and can be manifolded alone or with other reactors with a ferrous metal regeneration circuit during the catalyst regeneration and reactivation portion of an operating cycle during which period the catalyst is regenerated and reactivated. In the regeneration and reactivation of the coked catalyst the sequence of process steps include (a) an oxidation step and subsequent reduction step, or (b) a reduction step and subsequent oxidation step, to remove coke and redisperse the iridium component of the catalyst of said reactor. Iron scale carryover from the regeneration circuit to the catalyst of said reactor is drastically reduced by by-passing said reactor during the periods of transition from the (a) oxidation step to the reduction step, or (b) from the reduction step to the oxidation step by closing off the manifold connection between the regeneration circuit and the said reactor. Loss of catalyst activity due to iron scale carryover to the catalyst of said reactor is thus suppressed.

    Integrated lubricant upgrading process
    8.
    发明授权
    Integrated lubricant upgrading process 有权
    综合润滑油升级过程

    公开(公告)号：US06569313B1

    公开(公告)日：2003-05-27

    申请号：US09711604

    申请日：2000-11-13

    申请人： Michael B. Carroll ,  Gary P. Schleicher ,  Joseph P. Boyle

    发明人： Michael B. Carroll ,  Gary P. Schleicher ,  Joseph P. Boyle

    IPC分类号： C10G7302

    CPC分类号： C10G65/12 ,  C10G2400/10

    摘要： A process for upgrading oil feedstock wherein the feedstock is hydrotreated, hydrocracked, and flashed and/or distilled. The bottoms are then vacuum distilled to adjust viscosity and volatility. The refined feed is then extracted, dewaxed, and cascaded to a hydrofinishing step, where it is contacted with a catalyst having a metal hydrogenation function in order to produce lubricant products.

    摘要翻译： 一种用于升级油原料的方法，其中原料被加氢处理，加氢裂化，闪蒸和/或蒸馏。 然后将塔底物真空蒸馏以调节粘度和挥发性。 然后将精制的进料提取，脱蜡并级联到加氢精制步骤，在其中与具有金属氢化功能的催化剂接触以产生润滑剂产品。

    Process for solvent extraction of hydrocarbons providing an increased yield of raffinate
    9.
    发明授权
    Process for solvent extraction of hydrocarbons providing an increased yield of raffinate 有权
    提取萃取液产量提高的烃类溶剂萃取方法

    公开(公告)号：US06294082B1

    公开(公告)日：2001-09-25

    申请号：US09459029

    申请日：1999-12-10

    申请人： Keith K. Aldous ,  Joseph P. Boyle ,  Michael B. Davis

    发明人： Keith K. Aldous ,  Joseph P. Boyle ,  Michael B. Davis

    IPC分类号： C10G1701

    CPC分类号： C10G21/00

    摘要： A process for upgrading a hydrocarbon oil is provided which comprises introducing the oil and an aromatic extraction solvent containing 0.1 to 10 vol % water into an extraction zone for contact of the oil and solvent therein whereby an extract solution is formed; and injecting water into the extraction zone at a point below that at which the extraction solvent is introduced. The injected water is injected substantially countercurrent to the extraction solvent at a velocity of about 0.5 to 3 ft/sec in an amount ranging from about 0.1 to about 10 LV% based on the amount of extract solution being processed.

    摘要翻译： 提供一种烃油改质方法，包括将油和含有0.1〜10体积％水的芳香族萃取溶剂引入提取区，使油和溶剂接触，从而形成提取液; 并在低于提取溶剂引入的时间点将水注入萃取区。 基于处理的提取溶液的量，注入的水以约0.5至3ft / sec的速度基本上逆流地以约0.1至约10 LV％的量注入提取溶剂。

    Reactivation of iridium-containing catalysts
    10.
    发明授权
    Reactivation of iridium-containing catalysts 失效
    含铱催化剂的再活化

    公开(公告)号：US4514284A

    公开(公告)日：1985-04-30

    申请号：US643798

    申请日：1984-08-24

    申请人： Tom Wairegi ,  Joseph P. Boyle ,  John B. Gilbert

    发明人： Tom Wairegi ,  Joseph P. Boyle ,  John B. Gilbert

    IPC分类号： B01J23/96 ,  C10G35/085 ,  B01J23/90

    CPC分类号： B01J23/96 ,  C10G35/085

    摘要： A process wherein a coked, deactivated iridium-containing catalyst can be reactivated in a sequence of burn steps, inclusive of a low temperature primary burn step and a subsequent high temperature burn step. In (1) the low temperature primary burn step (i) the chloride level of the catalyst is raised and the catalyst passivated by contact with a hydrogen chloride containing gas, (ii) and coke is then burned from the catalyst by contact with a gas which contains hydrogen chloride at level sufficient to suppress iridium agglomeration at a level of oxygen providing burn temperatures which do not exceed about 425.degree. C., this being sufficient to remove a preponderance of the coke without agglomeration of the iridium component. (2) In a high temperature secondary burn step the catalyst is subjected to (iii) a chlorination step wherein the catalyst is contacted with a hydrogen chloride containing gas sufficient to raise the chloride level of the catalyst to a yet higher level for suppression of iridium agglomeration at higher temperature than 425.degree. C., (iv) residual coke is then burned from said catalyst by contact with a gas which contains hydrogen chloride at level sufficient to suppress iridium agglomeration at a level of oxygen sufficient to provide temperatures greater than 425.degree. C., sufficient to burn residual coke from the catalyst without agglomeration of the iridium. The high chloride catalyst can then be (3) stripped with steam, or steam and hydrogen chloride to reduce the level of chloride.

    摘要翻译： 一种其中可以以烧焦步骤（包括低温初级燃烧步骤和随后的高温烧制步骤）的顺序重新活化焦化，停用的含铱催化剂的方法。 在（1）中，低温初级烧成步骤（i）提高了催化剂的氯化物含量，并且通过与含氯化氢的气体（ii）和焦炭接触钝化的催化剂然后通过与气体接触而从催化剂中燃烧 其含有氯化氢，其水平足以在氧气水平下抑制铱团聚，提供不超过约425℃的燃烧温度，这足以除去焦炭的优势而不会使铱组分凝聚。 （2）在高温二次燃烧步骤中，催化剂经受（iii）氯化步骤，其中催化剂与含氯化氢的气体接触，足以使催化剂的氯化物水平提高到更高的水平以抑制铱 在高于425℃的温度下附聚，（iv）然后通过与含有氯化氢的气体接触来从所述催化剂中燃烧残余焦炭，其含量足以在足以提供高于425℃的氧气的氧气水平上抑制铱团聚 C.足以从催化剂中燃烧残余焦炭而没有铱的聚集。 然后，高氯催化剂可以（3）用蒸汽或蒸汽和氯化氢汽提，以降低氯化物的含量。