公开(公告)号：US07790794B2

公开(公告)日：2010-09-07

申请号：US12248129

申请日：2008-10-09

申请人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

发明人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

IPC分类号： C08K5/07

CPC分类号： C09D5/02 ,  C08F8/44 ,  C08F214/18 ,  C08G18/6279 ,  C08G18/706 ,  C09D127/12 ,  C09D175/04

摘要： A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.4 to 7 mol % of a structural unit of the following formula

摘要翻译： 一种水性涂料的组合物，其具有低有机溶剂含量，对环境的负担较小，并且储存稳定性优异。 一种水性涂料组合物，其包含含有含氟共聚物的合成树脂，所述氟化共聚物包含40至60mol％的氟代烯烃单元，3至50mol％的烷基乙烯基醚或烷基乙烯基酯单元，从4至 30摩尔％的含羟基的乙烯基醚单元和0.4〜7摩尔％的下式的结构单元

公开(公告)号：US20110184116A1

公开(公告)日：2011-07-28

申请号：US13081608

申请日：2011-04-07

申请人： Isao KIMURA ,  Naoko Sumi

发明人： Isao KIMURA ,  Naoko Sumi

IPC分类号： C09D127/12 ,  C09D153/00

CPC分类号： C09D5/028 ,  C08L53/00 ,  C09D127/12 ,  C09D153/00 ,  C08L2666/24 ,  C08L2666/04

摘要： To provide an aqueous coating composition which has a high storage stability and which is capable of forming a coating film excellent in gloss, adhesion and water resistance; a process for its production; and a process for forming a coating film by using the aqueous coating composition.An aqueous coating composition comprising a fluoro-olefin copolymer, a pigment, a copolymer (1) (an A-B type block copolymer which is a copolymer having no fluorine atoms or ionic groups and which comprises hydrophilic blocks (A) having repeating units (a) having a polyoxyethylene chain in the side chain, and hydrophobic blocks (B) having repeating units (b) having a hydrocarbon chain in the side chain) and an aqueous medium.

摘要翻译： 提供具有高储存稳定性并且能够形成光泽，粘附性和耐水性优异的涂膜的水性涂料组合物; 一个生产过程; 以及通过使用该水性涂料组合物形成涂膜的方法。 一种水性涂料组合物，其包含氟代烯烃共聚物，颜料，共聚物（1）（AB型嵌段共聚物，其是不含氟原子或离子基团的共聚物，并且包含具有重复单元（a）的亲水性嵌段（A） 在侧链中具有聚氧乙烯链，以及具有在侧链中具有烃链的重复单元（b））和水性介质的疏水性嵌段（B）。

公开(公告)号：US08013071B2

公开(公告)日：2011-09-06

申请号：US12689458

申请日：2010-01-19

申请人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

发明人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

IPC分类号： C08L27/12

CPC分类号： C09D5/02 ,  C08F8/44 ,  C08F214/18 ,  C08G18/6279 ,  C08G18/706 ,  C09D127/12 ,  C09D175/04

摘要： A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability. A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoroolefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.4 to 7 mol % of a structural unit of the following formula (a4):

摘要翻译： 一种水性涂料的组合物，其具有低有机溶剂含量，对环境的负担较小，并且储存稳定性优异。 一种水性涂料组合物，其包含含有含氟共聚物（A）的合成树脂，其包含40至60mol％的氟烯烃单元，3至50mol％的烷基乙烯基醚或烷基乙烯基酯单元，4 至30摩尔％的含羟基的乙烯基醚单元和0.4〜7摩尔％的下式（a4）的结构单元：

公开(公告)号：US20090048391A1

公开(公告)日：2009-02-19

申请号：US12248129

申请日：2008-10-09

申请人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

发明人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

IPC分类号： C08L27/12

CPC分类号： C09D5/02 ,  C08F8/44 ,  C08F214/18 ,  C08G18/6279 ,  C08G18/706 ,  C09D127/12 ,  C09D175/04

摘要： A composition for aqueous coating material which has a low content of an organic solvent and presents little burden on the environment and which is excellent in storage stability.A composition for aqueous coating material, which comprises a synthetic resin containing a fluorinated copolymer (A) comprising from 40 to 60 mol % of a fluoro-olefin unit, from 3 to 50 mol % of an alkyl vinyl ether or alkyl vinyl ester unit, from 4 to 30 mol % of a hydroxyl group-containing vinyl ether unit and 0.4 to 7 mol % of a structural unit of the following formula (a4):

摘要翻译： 一种水性涂料的组合物，其具有低有机溶剂含量，对环境的负担较小，并且储存稳定性优异。 一种水性涂料组合物，其包含含有含氟共聚物（A）的合成树脂，其含有40至60mol％的氟烯烃单元，3至50mol％的烷基乙烯基醚或烷基乙烯基酯单元， 4〜30摩尔％的含羟基的乙烯基醚单元和0.4〜7摩尔％的下式（a4）的结构单元：

公开(公告)号：US08399555B2

公开(公告)日：2013-03-19

申请号：US13081608

申请日：2011-04-07

申请人： Isao Kimura ,  Naoko Sumi

发明人： Isao Kimura ,  Naoko Sumi

IPC分类号： C08L53/00 ,  C09J7/02

CPC分类号： C09D5/028 ,  C08L53/00 ,  C09D127/12 ,  C09D153/00 ,  C08L2666/24 ,  C08L2666/04

摘要： To provide an aqueous coating composition which has a high storage stability and which is capable of forming a coating film excellent in gloss, adhesion and water resistance; a process for its production; and a process for forming a coating film by using the aqueous coating composition.An aqueous coating composition comprising a fluoro-olefin copolymer, a pigment, a copolymer (1) (an A-B type block copolymer which is a copolymer having no fluorine atoms or ionic groups and which comprises hydrophilic blocks (A) having repeating units (a) having a polyoxyethylene chain in the side chain, and hydrophobic blocks (B) having repeating units (b) having a hydrocarbon chain in the side chain) and an aqueous medium.

摘要翻译： 提供具有高储存稳定性并且能够形成光泽，粘附性和耐水性优异的涂膜的水性涂料组合物; 一个生产过程; 以及使用该水性涂料组合物形成涂膜的方法。 一种水性涂料组合物，其包含氟代烯烃共聚物，颜料，共聚物（1）（AB型嵌段共聚物，其是不含氟原子或离子基团的共聚物，并且包含具有重复单元（a）的亲水性嵌段（A） 在侧链中具有聚氧乙烯链，以及具有在侧链中具有烃链的重复单元（b））和水性介质的疏水性嵌段（B）。

公开(公告)号：US07919557B2

公开(公告)日：2011-04-05

申请号：US12731208

申请日：2010-03-25

申请人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

发明人： Naoko Sumi ,  Takashi Morizumi ,  Isao Kimura

IPC分类号： C08L27/12

CPC分类号： C09D127/12

摘要： An aqueous coating composition which has a low content of an organic solvent, whereby a burden on an environment is small; in which an increase of the molecular weight, gelation, etc. are suppressed; which performs excellent storage stability and provides a coating film having good water permeability/water which composition is obtained by dispersing a fluorocopolymer (A) obtained by solution polymerization in an aqueous medium, and which comprises a repeating unit (1) of fluoroolefin, a repeating unit (2) of a vinyl or allyl monomer, a repeating unit (3) of a vinyl or allyl monomer having a hydroxyl group bonded thereto, and a unit (4) of a vinyl or allyl monomer having a carboxylate group bonded thereto, and which comprises a fluorocopolymer (A) wherein a proportion of the repeating unit (4) is from 0.4 mol % to less than 4 mol % based on the total repeating units, and an aqueous medium, wherein an amount of an organic solvent contained in the composition is from 0 to 1 mass %.

摘要翻译： 具有低有机溶剂含量的水性涂料组合物，由此环境负担小; 其中抑制了分子​​量，凝胶化等的增加; 其具有优异的储存稳定性，并且提供了具有良好的透水性/水的涂膜，该组合物通过将通过溶液聚合获得的含氟共聚物（A）分散在水性介质中而获得，并且包含氟代烯烃的重复单元（1），重复 乙烯基或烯丙基单体的单元（2），与其结合的具有羟基的乙烯基或烯丙基单体的重复单元（3）和与其键合的羧酸酯基的乙烯基或烯丙基单体的单元（4），和 其包含含氟共聚物（A），其中所述重复单元（4）的比例相对于所述重复单元为0.4摩尔％至小于4摩尔％，以及水性介质，其中，所述含氟共聚物 组成为0〜1质量％。

公开(公告)号：US20060004129A1

公开(公告)日：2006-01-05

申请号：US11190855

申请日：2005-07-28

申请人： Nobuyuki Otozawa ,  Toyomichi Shimada ,  Takashige Maekawa ,  Naoko Sumi

发明人： Nobuyuki Otozawa ,  Toyomichi Shimada ,  Takashige Maekawa ,  Naoko Sumi

IPC分类号： C08F16/24

CPC分类号： C09D127/18 ,  C08G65/007 ,  C08K5/09 ,  C08K5/42 ,  C09D7/42 ,  G03F7/0046 ,  G03F7/091 ,  Y10T428/31786

摘要： To provide a coating composition useful to form an antireflection film having a refractive index lower than 1.4, excellent in water solubility and long-term stability in the form of a water solution. A coating composition containing a fluoropolymer having ionic functional groups (such as a fluoropolymer having polymer units of —CF2CF[O(CF2)3COOH]—), an acid and an aqueous medium.

摘要翻译： 为了提供可用于形成折射率低于1.4的抗反射膜的涂料组合物，水溶性和水溶液形式的长期稳定性优异。 含有具有离子性官能团的含氟聚合物的涂料组合物（例如具有-CF 2 O 2 CF 3 O 2 CF 3 O 3的聚合物单元的含氟聚合物 > COOH] - ），酸和水性介质。

公开(公告)号：US07205367B2

公开(公告)日：2007-04-17

申请号：US11023486

申请日：2004-12-29

申请人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi

发明人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi

IPC分类号： C08F214/24 ,  C08F214/26 ,  B29C47/20

CPC分类号： B32B27/08 ,  B32B1/08 ,  B32B27/28 ,  B32B27/322 ,  B32B27/34 ,  B32B2307/306 ,  B32B2307/712 ,  B32B2377/00 ,  B32B2597/00 ,  C08F214/18 ,  C08F214/26 ,  Y10T428/1321 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.

摘要翻译： 一种含氟共聚物，其包含（a）基于四氟乙烯和/或氯三氟乙烯的聚合单元，（b）基于氟化单体的聚合单元（不包括四氟乙烯和氯三氟乙烯）和（c）基于选自以下的至少一种的聚合单元： 的衣康酸，衣康酸酐，柠康酸和柠康酸酐，其中（a）为50〜99.8摩尔％，（b）为0.1〜49.99摩尔％，（c）为0.01〜5摩尔％，基于 （（a）+（b）+（c）），体积流量为0.1〜1000mm 3 / sec。

公开(公告)号：US06855787B2

公开(公告)日：2005-02-15

申请号：US10617663

申请日：2003-07-14

申请人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Koji Nakamura

发明人： Atsushi Funaki ,  Naoko Sumi ,  Eiichi Nishi ,  Noriyuki Isobe ,  Tomoharu Nishioka ,  Koji Nakamura

IPC分类号： B60K15/01 ,  B32B1/08 ,  B32B27/28 ,  B32B27/30 ,  B32B27/34 ,  C08F259/08 ,  C08L51/00 ,  F16L11/04 ,  F16L11/11 ,  F16L11/127 ,  F16L11/15 ,  C08F214/18 ,  B29D22/00

CPC分类号： B32B1/08 ,  B32B27/08 ,  B32B27/28 ,  B32B27/34 ,  B32B2270/00 ,  B32B2323/043 ,  B32B2323/046 ,  B32B2367/00 ,  B32B2398/20 ,  B32B2597/00 ,  C08F259/08 ,  C08L51/003 ,  F16L11/127 ,  F16L11/15 ,  Y10T428/1317 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L2666/02

摘要： A multi-layer hose having a multi-layer structure comprising an inner layer (I) made of a fluorocopolymer and an outer layer (II) made of a polyamide resin, wherein the fluorocopolymer constituting the inner layer (I) is a fluorocopolymer which comprises polymerized units (a) based on tetrafluoroethylene, polymerized units (b) based on ethylene and polymerized units (c) based on itaconic anhydride and/or citraconic anhydride, wherein the molar ratio of (a)/(b) is from 20/80 to 80/20 and the molar ratio of (c)/((a)+(b)) is from 1/10,000 to 5/100 and which has a volume flow rate of from 1 to 1,000 mm3/sec., and the polyamide resin constituting the outer layer (II) is polyamide 11 and/or polyamide 12, which satisfies a condition of (terminal amino group concentration)/(terminal carboxyl group concentration)>1.

摘要翻译： 一种具有多层结构的多层软管，包括由含氟共聚物制成的内层（I）和由聚酰胺树脂制成的外层（II），其中构成内层（I）的含氟共聚物是含氟共聚物，其包含 基于四氟乙烯的聚合单元（a），基于乙烯的聚合单元（b）和基于衣康酸酐和/或柠康酸酐的聚合单元（c），其中（a）/（b）的摩尔比为20/80 至80/20，（c）/（（a）+（b））的摩尔比为1 / 10,000〜5/100，体积流量为1〜1000mm 3 / sec。 构成外层（II）的聚酰胺树脂是满足（末端氨基浓度）/（末端羧基浓度）> 1的条件的聚酰胺11和/或聚酰胺12。

公开(公告)号：US06528600B2

公开(公告)日：2003-03-04

申请号：US09910831

申请日：2001-07-24

申请人： Atsushi Funaki ,  Naoko Sumi

发明人： Atsushi Funaki ,  Naoko Sumi

IPC分类号： C08F242

CPC分类号： C08F214/262 ,  C08F14/26 ,  C08F2438/01 ,  C08F2/04 ,  C08F2/38

摘要： A method for producing a tetrafluoroethylene/perfluoro (alkyl vinyl ether) type copolymer (PFA), which comprises carrying out the polymerization in a polymerization medium (such as CHFClCF2CF2Cl) in the presence of a chain transfer agent of a C1 or 2 hydrofluorocarbon (such as CH3CF2H) by means of a polymerization initiator (such as (FCF2CF2CF2COO)2). PFA obtained by this method has a small amount of unstable terminal groups contained in its molecule and is excellent in thermal stability and cracking resistance against a liquid reagent. Further, the amount of elution of fluorine ions is little even when it is applied to a component of e.g. an equipment for the production of semiconductors.

摘要翻译： 一种四氟乙烯/全氟（烷基乙烯基醚）型共聚物（PFA）的制造方法，其包括在C1或2氢氟烃的链转移剂（例如CHFClCF 2 CF 2 Cl）的存在下在聚合介质（如CHFClCF 2 CF 2 Cl）中进行聚合 作为CH 3 CF 2 H）通过聚合引发剂（如（FCF 2 CF 2 CF 2 COO）2））。 通过该方法获得的PFA在其分子中含有少量不稳定的末端基团，并且对液体试剂的热稳定性和耐龟裂性优异。 另外，氟离子的洗脱量即使施加于例如乙烯的成分也很少。 半导体生产设备。