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公开(公告)号：US4859798A
公开(公告)日：1989-08-22
申请号：US211008
申请日：1988-06-24
IPC分类号： B01J27/188 , B01J27/199 , C07C29/50 , C07C45/33
CPC分类号： B01J23/002 , B01J27/188 , B01J27/199 , C07C29/50 , C07C45/33 , B01J2523/00
摘要： Alkanes are oxidized in the liquid phase at relatively low temperatures using heteropolyacids or polyoxoanions promoted with azide or certain metals. Such azide catalysts are also part of the invention.
摘要翻译： 在相对低的温度下，使用杂多酸或用叠氮化物或某些金属促进的聚氧阴离子，在液相中使烷烃氧化。 这种叠氮化物催化剂也是本发明的一部分。
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公开(公告)号：US4916101A
公开(公告)日：1990-04-10
申请号：US279903
申请日：1988-12-05
IPC分类号： B01J23/85 , B01J27/186 , B01J27/188 , B01J27/199 , B01J37/08 , C01B25/16 , C01B25/24 , C01B25/45 , C01B33/00 , C01B33/20 , C01B39/10 , C01G41/00 , C07C211/63
CPC分类号： B01J27/188 , B01J23/85 , B01J37/086 , C01B25/16 , C01B33/00 , C01G41/006 , C01P2006/60
摘要： Polyoxoanions are converted to the corresponding heteropolyacids by conversion to their tetrabutylammonium salt followed by pyrolysis.
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公开(公告)号：US4803187A
公开(公告)日：1989-02-07
申请号：US76570
申请日：1987-07-20
IPC分类号： C01B21/097 , B01J23/28 , B01J23/34 , B01J23/88 , B01J27/187 , B01J27/188 , B01J27/198 , B01J27/199 , B01J27/24 , B01J37/00 , C01B25/00 , C07B61/00 , C07C27/00 , C07C27/12 , C07C29/50 , C07C31/02 , C07C31/10 , C07C31/12 , C07C45/00 , C07C45/33 , C07C49/04 , C07C49/08 , C07C67/00 , B01J27/14
CPC分类号： B01J27/199 , B01J23/002 , B01J27/188 , C01G39/006 , C01G41/006 , C01G49/009 , C07C29/50 , C07C45/33 , B01J2523/00
摘要： Heteropolyacids or polyoxoanions promoted with azide, such as K.sub.6 PW.sub.11 VO.sub.40 N.sub.3, useful in the liquid phase oxidation of alkanes.
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4.发明授权Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes 失效由叠氮化物活化的金属配位络合物催化的烃氧化反应
公开(公告)号：US4895682A
公开(公告)日：1990-01-23
申请号：US246
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidixed with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
摘要翻译： 碳氢化合物，特别是较低分子量的烷烃和环烷烃可以容易地与空气或O 2一起氧化，以高产率选择性地形成醇，酮等产物，当用作催化剂高活性叠氮化物活化金属配位体 具有结构
的复合物，其中M是过渡金属; “”是配体; X为叠氮化物。 本发明还涉及某些新型叠氮化物活化金属配位络合物催化剂本身。 -
5.发明授权Hydrocarbon oxidations catalyzed by nitride-activated metal coordination complexes 失效由氮化物活化的金属配位络合物催化的烃氧化
公开(公告)号：US4895680A
公开(公告)日：1990-01-23
申请号：US000247
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C12C11/02 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbon, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like in high yields when there is employed as the catalyst a highly active nitride-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is a nitride. Certain dimeric forms of the above catalyst are also employed herein. It has also been discovered that Group IV through VIII transition metal nitrides are also highly effective oxidation catalysts for lower molecular weight hydrocarbons such as alkanes.
摘要翻译： 当使用高活性氮化物活化的金属配位络合物作为催化剂时，烃，特别是低分子量烷烃和环烷烃可以容易地用空气或O 2氧化形成醇，酮等产物， 具有结构
，其中M是过渡金属; “”是配体; X是氮化物。 上述催化剂的某些二聚体形式也用于本文。 还发现，IV族至VIII族过渡金属氮化物也是用于低分子量烃如烷烃的高效氧化催化剂。 -
6.发明授权Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes 失效由叠氮化物活化的金属配位络合物催化的烃氧化反应
公开(公告)号：US5093491A
公开(公告)日：1992-03-03
申请号：US466163
申请日：1990-01-17
CPC分类号： C07C45/36 , B01J27/24 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , B01J2531/025 , B01J2531/62 , B01J2531/72 , C07C2101/14
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively on high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
摘要翻译： 碳氢化合物，特别是较低分子量的烷烃和环烷烃可以容易地用空气或O 2氧化，以高产率选择性地形成醇，酮等产物，当用作催化剂时，高活性的叠氮化物活化的金属配位体 具有结构
的复合物，其中M是过渡金属; “”是配体; X为叠氮化物。 本发明还涉及某些新型叠氮化物活化金属配位络合物催化剂本身。 -
7.发明授权Hydrocarbon oxidations catalyzed by iron coordination complexes containing a halogenated ligand 失效由含有卤化配体的铁配位络合物催化的烃氧化反应
公开(公告)号：US4900871A
公开(公告)日：1990-02-13
申请号：US66666
申请日：1987-06-26
IPC分类号： C07B61/00 , B01J27/24 , B01J31/18 , B01J31/22 , C07C27/00 , C07C27/12 , C07C29/50 , C07C31/02 , C07C31/10 , C07C31/12 , C07C45/00 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C49/08 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C67/00
CPC分类号： B01J31/183 , B01J27/24 , B01J31/1805 , B01J31/1815 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , B01J2531/025 , B01J2531/62 , B01J2531/72 , B01J2531/842
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively high yields when there is employed as the catalyst a coordination complex containing an iron center and a halogenated ligand having the structure ##STR1## where Fe is iron; " .circle. " is a ligand; X is a halogen substituent of the ligand; and A is an anion.
摘要翻译： 当使用含有铁中心和配位络合物的配位络合物作为催化剂时，烃，特别是低分子量烷烃和环烷烃可容易地被空气或O 2氧化以形成诸如醇，酮等的产物。 卤化配体具有结构
，其中Fe是铁; “＆cir＆”是配体; X是配体的卤素取代基; 而A是阴离子。 -
公开(公告)号：US5817881A
公开(公告)日：1998-10-06
申请号：US902931
申请日：1997-07-30
IPC分类号： B01J23/881 , B01J27/188 , C07C29/50 , C07C45/33
CPC分类号： C07C29/50 , B01J23/881 , B01J27/188 , C07C45/33
摘要： Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z �(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-eThe M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.
摘要翻译： 烷烃在空气或氧气中使用下式的铁取代的聚氧阴离子（POA）催化氧化：He-z [（n-C4H9）4N] z（XM11M'O39）-e M'（例如铁（III）/ 铁（II））还原电位受中心原子X和骨架金属M的选择以及四丁基铵基团的数量的影响。 已经发现Fe（III）/ Fe（II）还原电位的降低与增加的氧化活性相关。
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9.发明授权Process for making codimers of norbornadiene and phenylacetylenes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和苯乙炔的共聚物的方法
公开(公告)号：US4132742A
公开(公告)日：1979-01-02
申请号：US842813
申请日：1977-10-17
CPC分类号： C07C2/42 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substituents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
摘要翻译： 降冰片二烯和苯乙炔及其氢化衍生物（II）的新型共聚物（I）及其氢化衍生物（II），其具有以下结构：其中R是氢，苯基或具有烷基取代基的苯基，R 1是具有烷基取代基的苯基或苯基 并公开了制备两者的方法。 Codimer（II）可用作这种燃料的高能燃料或稀释剂。 制备编码（I）的方法包括使降冰片二烯和苯基乙炔或二苯基乙炔与钴或钴乙酰丙酮化合物的催化剂体系，1,2-双二苯基膦基乙烷和烷基氯化铝反应。
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公开(公告)号：US4100216A
公开(公告)日：1978-07-11
申请号：US819445
申请日：1977-07-27
CPC分类号： C07C2/42
摘要： Norbornadiene and isoprene are catalytically codimerized to an olefinic codimer. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. The codimer upon hydrogenation forms .beta.-methyltetramethylene nortricyclane having utility as a diluent for a high energy hydrocarbon missile fuel.
摘要翻译： 降冰片二烯和异戊二烯被催化同分异构化成烯属共聚体。 使用由钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝组成的三组分均相催化体系。 加氢时的同分子化形式可用作高能烃类导弹燃料的稀释剂的β-甲基四亚甲基核桃素。
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