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公开(公告)号：US5336714A
公开(公告)日：1994-08-09
申请号：US175447
申请日：1993-12-30
申请人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
IPC分类号： C09K11/06 , C08G63/68 , C08G69/44 , C09B69/10 , C09D5/22 , C09D11/10 , C09D167/00 , C09D167/02 , C09D177/00 , C09D177/12 , C08K3/20
CPC分类号： C09D11/102 , C08G63/68 , C08G69/44 , C09B69/10 , Y10T428/29 , Y10T428/3179
摘要： Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.
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2.发明授权Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein 失效含有其中共聚的近红外荧光化合物的可水分散的聚酯和酰胺
公开(公告)号：US5292855A
公开(公告)日：1994-03-08
申请号：US19535
申请日：1993-02-18
申请人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
IPC分类号： C09K11/06 , C08G63/68 , C08G69/44 , C09B69/10 , C09D5/22 , C09D11/10 , C09D167/00 , C09D167/02 , C09D177/00 , C09D177/12 , C08G63/44
CPC分类号： C09D11/102 , C08G63/68 , C08G69/44 , C09B69/10 , Y10T428/29 , Y10T428/3179
摘要： Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.
摘要翻译： 提供了在其中共聚有热稳定性近红外光滑化合物的可水分散的含磺基聚酯和聚酯酰胺。 聚合物可用于涂料或油墨组合物，这些组合物又用于标记物品以用于鉴定/认证目的。 还提供了一种用于不可见地标记这种物品的方法，以及通过利用近红外荧光墨水或涂料组合物来检测和分选物品的方法。
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公开(公告)号：US5525516A
公开(公告)日：1996-06-11
申请号：US315386
申请日：1994-09-30
CPC分类号： C10L1/003 , C10L1/232 , C10L1/24 , C10L1/28 , C10L1/30 , C10L1/301 , C10M171/007 , G01N33/2882 , C10L1/233 , C10L1/2406 , C10L1/2412 , C10L1/2418 , C10L1/2431 , C10L1/2437 , C10L1/245 , C10L1/2456 , C10L1/305 , C10L1/308 , Y10T436/13
摘要： This invention provides a method for imparting invisible markings for identification purposes to petroleum hydrocarbons by incorporating one or more infrared fluorescing compounds therein. Certain infrared fluorophores from the classes of squaraines (derived from squaric acid), phthalocyanines and naphthalocyanines are useful in providing invisibly marked petroleum hydrocarbons such as crude oil, lubricating oils, waxes, gas oil (furnace oil), diesel oil, kerosene and in particular gasoline. The near infrared fluorophores are added to the hydrocarbons at extremely low levels and are detected by exposing the marked hydrocarbon compositions to near infrared radiation having a wavelength in the 670-850 nm range and then detecting the emitted fluorescent light via near infrared light detection means.
摘要翻译： 本发明提供了一种通过在其中掺入一种或多种红外荧光化合物来赋予石油烃识别目的的不可见标记的方法。 来自方酸类（衍生自方酸），酞菁和萘酞菁的某些红外荧光团可用于提供不可见的石油烃，例如原油，润滑油，蜡，瓦斯油（炉油），柴油，煤油，特别是 汽油。 将近红外荧光团以非常低的水平添加到烃中，并通过将标记的烃组合物暴露于具有670-850nm范围内的波长的近红外辐射，然后通过近红外光检测装置检测发射的荧光来检测。
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4.发明授权Method for detecting and separating thermoplastic containers with near infrared fluorosphores 失效用近红外荧光团检测和分离热塑性容器的方法
公开(公告)号：US5553714A
公开(公告)日：1996-09-10
申请号：US339318
申请日：1994-11-14
申请人： Michael R. Cushman , James J. Krutak , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
发明人： Michael R. Cushman , James J. Krutak , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
IPC分类号： C07D487/22 , B07C5/342 , C07D209/60 , C07F5/06 , C07F7/02 , C07F7/08 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3415 , C08L67/00 , C08L101/00 , C09B47/06 , C09B47/067 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/00 , C09B67/20 , C09K11/06 , B07C5/10
CPC分类号： C09B47/063 , B07C5/342 , B07C5/365 , C07D209/60 , C07F5/069 , C07F7/025 , C07F7/0858 , C08K5/0008 , C08K5/0041 , C08K5/34 , C09B47/0675 , C09B47/0676 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/007 , C09B67/0061 , B29B2017/0279 , Y02W30/622
摘要： Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions.
摘要翻译： 提供了使用近红外荧光化合物或易于检测的共聚残基来标记热塑性容器的方法。 还提供了一种用于识别热塑性容器的方法。 还提供了由近红外荧光化合物或由这些组合物组成的残余物和制品组成的热塑性聚合物组合物。
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5.发明授权
公开(公告)号：US5703229A
公开(公告)日：1997-12-30
申请号：US609011
申请日：1996-02-29
申请人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
IPC分类号： C07D487/22 , B07C5/342 , C07D209/60 , C07F5/06 , C07F7/02 , C07F7/08 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3415 , C08L67/00 , C08L101/00 , C09B47/06 , C09B47/067 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/00 , C09B67/20 , C09K11/06 , C07B47/24
CPC分类号： C09B47/063 , B07C5/342 , B07C5/365 , C07D209/60 , C07F5/069 , C07F7/025 , C07F7/0858 , C08K5/0008 , C08K5/0041 , C08K5/34 , C09B47/0675 , C09B47/0676 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/007 , C09B67/0061 , B29B2017/0279 , Y02W30/622
摘要： Provided are new compounds useful as near infrared fluorophoric markers. In the practice of this invention a method is also provided for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. The new compounds are phthalocyanine and naphthalocyanine derivatives which are covalently bonded to substituted silicon and aluminum compounds. The methods, compositions, and compounds described herein thus provide a total system useful for marking, for identification purposes, the various classes of thermoplastic wastes, so that they can be identified, sorted, and subsequently recycled.
摘要翻译： 提供用作近红外荧光标记的新化合物。 在本发明的实践中，还提供了使用近红外荧光化合物或易于检测的共聚残基来标记热塑性容器的方法。 新化合物是与取代的硅和铝化合物共价键合的酞菁和萘酞菁衍生物。 因此，本文所述的方法，组合物和化合物提供了用于标识目的的各种类型的热塑性废物的总体系统，以便可以鉴定，分类和随后再循环。
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6.发明授权Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein 失效含有其中共聚的近红外荧光化合物的可水分散的聚酯和酰胺
公开(公告)号：US5423432A
公开(公告)日：1995-06-13
申请号：US238300
申请日：1994-05-05
申请人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , William W. Parham , Clarence A. Coates , Max A. Weaver , Gabor Patonay
CPC分类号： G06K7/12 , C08G63/68 , C08G69/04 , G06K19/06009 , Y10T428/31786 , Y10T428/3179
摘要： Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.
摘要翻译： 提供了在其中共聚有热稳定性近红外光滑化合物的可水分散的含磺基聚酯和聚酯酰胺。 聚合物可用于涂料或油墨组合物，这些组合物又用于标记物品以用于鉴定/认证目的。 还提供了一种用于不可见地标记这种物品的方法，以及通过利用近红外荧光墨水或涂料组合物来检测和分选物品的方法。
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7.发明授权
公开(公告)号：US5461136A
公开(公告)日：1995-10-24
申请号：US265904
申请日：1994-06-27
申请人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
IPC分类号： C07D487/22 , B07C5/342 , C07D209/60 , C07F5/06 , C07F7/02 , C07F7/08 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3415 , C08L67/00 , C08L101/00 , C09B47/06 , C09B47/067 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/00 , C09B67/20 , C09K11/06 , C08G73/00
CPC分类号： C09B47/063 , B07C5/342 , B07C5/365 , C07D209/60 , C07F5/069 , C07F7/025 , C07F7/0858 , C08K5/0008 , C08K5/0041 , C08K5/34 , C09B47/0675 , C09B47/0676 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/007 , C09B67/0061 , B29B2017/0279 , Y02W30/622
摘要： Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions. Also provided are new compounds useful as near infrared fluorophoric markers in the practice of this invention. The methods, compositions, and compounds of the present invention thus provide a total system useful for marking, for identification purposes, the various classes of thermoplastic wastes, so that they can be identified, sorted, and subsequently recycled.
摘要翻译： 提供了使用近红外荧光化合物或易于检测的共聚残基来标记热塑性容器的方法。 还提供了一种用于识别热塑性容器的方法。 还提供了由近红外荧光化合物或由这些组合物组成的残余物和制品组成的热塑性聚合物组合物。 还提供了在本发明的实践中用作近红外荧光标记的新化合物。 因此，本发明的方法，组合物和化合物提供了用于标识目的的各种类型的热塑性废物的总体系统，以便可以鉴定，分类和随后再循环。
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公开(公告)号：US5397819A
公开(公告)日：1995-03-14
申请号：US156746
申请日：1993-11-24
申请人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
发明人： James J. Krutak , Michael R. Cushman , Clarence A. Coates , William W. Parham , Max A. Weaver , Gabor Patonay
IPC分类号： C07D487/22 , B07C5/342 , C07D209/60 , C07F5/06 , C07F7/02 , C07F7/08 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/3415 , C08L67/00 , C08L101/00 , C09B47/06 , C09B47/067 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/00 , C09B67/20 , C09K11/06
CPC分类号： C09B47/063 , B07C5/342 , B07C5/365 , C07D209/60 , C07F5/069 , C07F7/025 , C07F7/0858 , C08K5/0008 , C08K5/0041 , C08K5/34 , C09B47/0675 , C09B47/0676 , C09B47/073 , C09B47/08 , C09B47/18 , C09B57/007 , C09B67/0061 , B29B2017/0279 , Y02W30/622
摘要： Provided is a method for tagging thermoplastic containers using near infrared fluorescing compounds or copolymerized residues readily capable of detection. Also provided is a method for identifying a thermoplastic container. Also provided are thermoplastic polymer compositions comprised of the near infrared fluorescing compounds or residues and articles comprised of such compositions. Also provided are new compounds useful as near infrared fluorophoric markers in the practice of this invention. The methods, compositions, and compounds of the present invention thus provide a total system useful for marking, for identification purposes, the various classes of thermoplastic wastes, so that they can be identified, sorted, and subsequently recycled.
摘要翻译： 提供了使用近红外荧光化合物或易于检测的共聚残基来标记热塑性容器的方法。 还提供了一种用于识别热塑性容器的方法。 还提供了由近红外荧光化合物或由这些组合物组成的残余物和制品组成的热塑性聚合物组合物。 还提供了在本发明的实践中用作近红外荧光标记的新化合物。 因此，本发明的方法，组合物和化合物提供了用于识别目的的各种类型的热塑性废物的总体系统，以便可以鉴定，分类和随后再循环。
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9.发明授权Ultraviolet light-absorbing compounds and sunscreen formulations and polymeric materials containing such compounds or residues thereof 失效紫外光吸收化合物和防晒制剂以及含有这些化合物或其残基的聚合材料
公开(公告)号：US5374419A
公开(公告)日：1994-12-20
申请号：US994069
申请日：1992-12-18
申请人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
发明人： James J. Krutak , Max A. Weaver , Clarence A. Coates, Jr. , Samuel D. Hilbert , Terry A. Oldfield , William W. Parham , Wayne P. Pruett
IPC分类号： A61K8/00 , A61K8/04 , A61K8/40 , A61K8/46 , A61K8/85 , A61Q17/04 , C07C69/734 , C07C69/736 , C07C255/23 , C07C255/32 , C07C255/34 , C07C255/37 , C07C255/41 , C07C255/53 , C07C271/26 , C07C317/46 , C07C321/28 , C07C323/12 , C07C323/19 , C07C323/32 , C07C323/62 , C08G63/16 , C08G63/20 , C08G63/44 , C08G63/676 , C08G63/685 , C08G63/688 , C08G85/00 , C08J5/18 , C08K5/00 , C08L67/00 , C08L67/02 , C09K3/00 , A61K7/42 , A61K7/44 , C07C255/00
CPC分类号： A61Q17/04 , A61K8/40 , A61K8/46 , A61K8/85 , C07C255/41 , C08G63/676 , C08G63/6858 , C08G63/6888 , C08G85/00 , Y10S514/938 , Y10T428/13 , Y10T428/1352
摘要： Disclosed are sunscreen compositions containing certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.
摘要翻译： 公开了含有具有式“IMAGE”的某些多次甲基化合物的防晒组合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。
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公开(公告)号：US5194571A
公开(公告)日：1993-03-16
申请号：US746832
申请日：1991-08-19
申请人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
发明人： Max A. Weaver , Clarence A. Coates , William W. Parham , Samuel D. Hilbert , James J. Krutak , Wayne P. Pruett
IPC分类号： C08G63/685 , C08G63/688 , C08L101/00
CPC分类号： C08L101/00 , C08G63/6854 , C08G63/6884
摘要： Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
摘要翻译： 提供了在其中共聚有热稳定着色剂的聚酯组合物，所述着色剂由至少一个富含电子的芳族部分连接到负取代的2,5-二氧基吡咯啉-3-基部分上并含有至少一个，优选两个聚酯反应性 团体 还提供了聚酯颜色浓缩物和着色聚酯组合物与其它热塑性聚合物的混合物和由其组成的成形或成型制品。
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