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    Synthetic method for the synthesis of silicon polyether copolymers
    2.
    发明授权
    Synthetic method for the synthesis of silicon polyether copolymers 失效
    合成硅聚醚共聚物的合成方法

    公开(公告)号：US5247044A

    公开(公告)日：1993-09-21

    申请号：US904350

    申请日：1992-06-25

    Applicant: James V. Crivello ,  Mingxin Fan

    Inventor： James V. Crivello ,  Mingxin Fan

    IPC: C08G65/26 ,  C08G59/68 ,  C08G65/16 ,  C08G77/46 ,  C08G81/00 ,  C08K5/5419 ,  C08K5/549 ,  C08L83/05 ,  C08L83/06

    CPC classification number: C08G59/68 ,  C08G65/16 ,  C08G77/46 ,  C08K5/5419 ,  C08K5/549 ,  C08L83/06

    Abstract: The present invention is based on the discovery that various metal catalysts will catalyze the ring opening polymerization of epoxides to yield polyethers. The present invention therefore provides a method of making a polymeric product by ring-opening polymerization of heterocyclic epoxide monomer including the steps of preparing a mixture comprised of a catalyst; a Si--H containing compound; and at least one compound which is a heterocyclic epoxide containing monomer; and reacting the mixture at a temperature effective to promote ring-opening polymerization of the at least one compound to produce a polymeric product, preferably at room temperature.The present invention additionally provides for the silicone-polyether compositions created by this method.

    Abstract translation: 本发明基于以下发现：各种金属催化剂将催化环氧化物的开环聚合以产生聚醚。 因此，本发明提供了通过杂环环氧化物单体的开环聚合制备聚合物的方法，包括以下步骤：制备由催化剂组成的混合物; 含Si-H的化合物; 和至少一种含杂环氧化物的单体的化合物; 并在有效促进至少一种化合物的开环聚合的温度下使该混合物反应，以产生聚合产物，优选在室温下。 本发明另外提供了通过该方法制备的硅氧烷 - 聚醚组合物。

    Oligomeric and polymeric photosensitizers comprising a polynuclear aromatic group
    8.
    发明授权
    Oligomeric and polymeric photosensitizers comprising a polynuclear aromatic group 有权
    包含多核芳族基团的低聚和光敏剂

    公开(公告)号：US06593388B2

    公开(公告)日：2003-07-15

    申请号：US09826330

    申请日：2001-04-04

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F250

    CPC classification number: C08F2/50 ,  C07F7/0838 ,  C08G59/68

    Abstract: Enhancement of the rates of cationic polymerizations initiated by onium salts has been achieved through the use of oligomeric and polymeric electron-transfer photosensitizers derived from a polymerizable compound substituted with a polynuclear aromatic group, including epoxides, oxetanes, and ethylenically unsaturated compounds. The polymerizable compound is substituted with residues derived from anthracene, naphthalene, perylene, pyrene, fluorene, carbazole, indole, benzocarbazole, acridone, phenothiazine, and thianthrene, particularly carbazole.

    Abstract translation: 通过使用衍生自被多环芳族基团（包括环氧化物，氧杂环丁烷和烯键式不饱和化合物）取代的可聚合化合物的低聚和聚合电子转移光敏剂，已经实现了由鎓盐引发的阳离子聚合速率的提高。 可聚合化合物被衍生自蒽，萘，苝，芘，芴，咔唑，吲哚，苯并咔唑，吖啶酮，吩噻嗪和噻蒽，特别是咔唑的残基取代。

    Process for selective monoaddition to silanes containing two silicon-hydrogen bonds and products thereof
    9.
    发明授权
    Process for selective monoaddition to silanes containing two silicon-hydrogen bonds and products thereof 失效
    用于选择性加成含有两个硅氢键的硅烷及其产物的方法

    公开(公告)号：US5484950A

    公开(公告)日：1996-01-16

    申请号：US993689

    申请日：1992-12-21

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C07F7/08 ,  C08G77/38 ,  C07D303/02 ,  C07F7/10 ,  C07F7/18

    CPC classification number: C07F7/0896 ,  C07F7/0852 ,  C07F7/0879 ,  C08G77/38

    Abstract: A process for the selective monoadditon of an olefin or acetylene to a siloxane which contains two reactive Si--H bonds to produce a product in which only one of the two Si--H functions has added across the olefin or acetylene is disclosed. A process for making unsymmetrical siloxanes from symmetrical dihydrosiloxanes and products of both of these processes are also disclosed. Products are represented by the formula I in which R.sup.1 and R.sup.4 are different: ##STR1##

    Abstract translation: 公开了一种烯烃或乙炔对含有两个反应性Si-H键的硅氧烷的选择性单加成方法，以产生其中仅两种Si-H官能团中仅有一种加入到烯烃或乙炔中的产物。 还公开了从对称二氢硅氧烷制造不对称硅氧烷和这两种方法的产物的方法。 产品由式I表示，其中R1和R4不同：

    Cobalt catalyst for ring-opening polymerization of exopides and other heterocycles
    10.
    发明授权
    Cobalt catalyst for ring-opening polymerization of exopides and other heterocycles 失效
    钴催化剂用于外嵌剂和其它杂环的开环聚合

    公开(公告)号：US5412054A

    公开(公告)日：1995-05-02

    申请号：US159760

    申请日：1993-11-30

    Applicant: James V. Crivello ,  Ming-Xin Fan

    Inventor： James V. Crivello ,  Ming-Xin Fan

    IPC: C08G65/02 ,  B01J31/20 ,  C08G65/10 ,  C08G65/12

    CPC classification number: B01J31/1608 ,  B01J31/20 ,  C08G65/12 ,  B01J2231/14 ,  B01J2231/323 ,  B01J2531/0211 ,  B01J2531/845

    Abstract: A catalyst: mixture for ring-opening polymerization of heterocyclic monomers and polymers includes a catalyst composed of a cobalt carbonyl complex; and a cocatalyst composed of at least one Si-H-containing compound. A curable composition, which may be a two-part kit, is also disclosed and includes the catalyst; the cocatalyst; and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring. A method of producing a polymeric product by ring-opening polymerization of heterocyclic monomers and polymers is also disclosed which includes the steps of preparing a mixture including a catalyst composed of a cobalt carbonyl complex, a cocatalyst composed of at least one Si-H-containing compound, and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring; and reacting the mixture, preferably at about room temperature, to promote ring-opening polymerization of the at least one polymerizable compound to produce the polymeric product.

    Abstract translation: 催化剂：用于杂环单体和聚合物的开环聚合的混合物包括由羰基钴络合物组成的催化剂; 和由至少一种含Si-H的化合物组成的助催化剂。 还公开了可以是两部分试剂盒的可固化组合物，并且包括催化剂; 助催化剂; 以及作为含有杂环的单体或聚合物的至少一种聚合性化合物。 还公开了通过杂环单体和聚合物的开环聚合制备聚合物的方法，其包括以下步骤：制备包含由羰基钴配合物组成的催化剂的催化剂，由至少一种含Si-H 化合物和至少一种可聚合化合物，其是含有杂环的单体或聚合物; 并使混合物优选在约室温下反应，以促进至少一种可聚合化合物的开环聚合以产生聚合产物。

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