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公开(公告)号：US5583194A
公开(公告)日：1996-12-10
申请号：US195792
申请日：1994-02-14
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/1876 , C08G77/38
Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a quaternary ammonium, phosphonium or arsonium hexahaloplatinate which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method.
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公开(公告)号：US5247044A
公开(公告)日：1993-09-21
申请号：US904350
申请日：1992-06-25
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: C08G65/26 , C08G59/68 , C08G65/16 , C08G77/46 , C08G81/00 , C08K5/5419 , C08K5/549 , C08L83/05 , C08L83/06
Abstract: The present invention is based on the discovery that various metal catalysts will catalyze the ring opening polymerization of epoxides to yield polyethers. The present invention therefore provides a method of making a polymeric product by ring-opening polymerization of heterocyclic epoxide monomer including the steps of preparing a mixture comprised of a catalyst; a Si--H containing compound; and at least one compound which is a heterocyclic epoxide containing monomer; and reacting the mixture at a temperature effective to promote ring-opening polymerization of the at least one compound to produce a polymeric product, preferably at room temperature.The present invention additionally provides for the silicone-polyether compositions created by this method.
Abstract translation: 本发明基于以下发现：各种金属催化剂将催化环氧化物的开环聚合以产生聚醚。 因此，本发明提供了通过杂环环氧化物单体的开环聚合制备聚合物的方法，包括以下步骤：制备由催化剂组成的混合物; 含Si-H的化合物; 和至少一种含杂环氧化物的单体的化合物; 并在有效促进至少一种化合物的开环聚合的温度下使该混合物反应，以产生聚合产物，优选在室温下。 本发明另外提供了通过该方法制备的硅氧烷 - 聚醚组合物。
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公开(公告)号：US5223344A
公开(公告)日：1993-06-29
申请号：US811188
申请日：1991-12-20
Applicant: Chris A. Sumpter , Larry N. Lewis , Judith Stein , James V. Crivello , Mingxin Fan
Inventor： Chris A. Sumpter , Larry N. Lewis , Judith Stein , James V. Crivello , Mingxin Fan
IPC: C08L83/05 , C08L83/04 , C08L83/07 , C09D183/04
CPC classification number: C08L83/04 , C09D183/04 , C08G77/12 , C08G77/20 , C08G77/80 , Y10T428/31663 , Y10T428/31667
Abstract: The present invention discloses the use of certain silicon hydrides having at least two hydrogen atoms attached to silicon in particular heat curable platinum catalyzed silicone coating formulations, which permits the use of a reduced level of inhibitor and improved cure performance.
Abstract translation: 本发明公开了使用具有至少两个与硅连接的氢原子的硅氢化物，特别是可热固化的铂催化的硅氧烷涂料配方，其允许使用降低的抑制剂水平和改进的固化性能。
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4.发明授权Rhodium containing catalysts for the synthesis of epoxysiloxane/epoxysilicone monomers and polymers 失效含铑催化剂用于合成环氧硅氧烷/环氧硅氧烷单体和聚合物
公开(公告)号：US5442026A
公开(公告)日：1995-08-15
申请号：US337593
申请日：1994-11-10
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: C08G59/20 , B01J31/02 , B01J31/18 , B01J31/30 , C07F7/08 , C07F7/18 , C08G59/30 , C08G59/68 , C08G65/16 , C08G77/14 , C08G77/22 , C08G77/38 , C08G77/46 , C08K5/5419 , C08K5/549 , C08L83/06 , C08L83/12 , C08G77/08
CPC classification number: C08G77/38 , B01J31/0239 , B01J31/0267 , B01J31/0268 , B01J31/30 , C07F7/0829 , C07F7/0847 , C07F7/0879 , C07F7/1876 , C08G59/68 , C08G65/16 , C08G77/46 , C08K5/5419 , C08K5/549 , C08L83/06 , C08L83/12 , B01J2231/323
Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a rhodium containing selective catalyst which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The rhodium containing selective catalyst has the general formula[R.sub.4 M].sup.+ [RhCl.sub.3 Br].sup.-wherein M is phosphorous or nitrogen and R is an organic radical comprising a C.sub.1-18 linear alkyl radical, aryl, alkaryl or aralkyl radical.
Abstract translation: 本发明提供了一种通过烯键式不饱和环氧化物和含SiH的硅氧烷之间的硅氢化反应制备可固化环氧硅氧烷组合物以制备环氧硅氧烷产物的方法，并且通过不促进环氧乙烷开环反应的含铑选择性催化剂催化 的烯键式不饱和环氧化物起始材料或环氧硅氧烷产物。 含铑选择性催化剂具有通式[R 4 M] + [RhCl 3 Br] - ，其中M为磷或氮，R为包含C 1-18直链烷基，芳基，烷芳基或芳烷基的有机基团。
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5.发明授权Rhodium containing selective catalysts for the synthesis of epoxysiloxane/epoxysilicone monomers and polymers 失效含铑选择性催化剂用于合成环氧硅氧烷/环氧硅氧烷单体和聚合物
公开(公告)号：US5387698A
公开(公告)日：1995-02-07
申请号：US896950
申请日：1992-06-11
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: C08G59/20 , B01J31/02 , B01J31/18 , B01J31/30 , C07F7/08 , C07F7/18 , C08G59/30 , C08G59/68 , C08G65/16 , C08G77/14 , C08G77/22 , C08G77/38 , C08G77/46 , C08K5/5419 , C08K5/549 , C08L83/06 , C08L83/12 , C07F7/02
CPC classification number: C08G77/38 , B01J31/0239 , B01J31/0267 , B01J31/0268 , B01J31/30 , C07F7/0829 , C07F7/0847 , C07F7/0879 , C07F7/1876 , C08G59/68 , C08G65/16 , C08G77/46 , C08K5/5419 , C08K5/549 , C08L83/06 , C08L83/12 , B01J2231/323
Abstract: The invention provides a method for making a curable epoxysilicone composition through the hydrosilation reaction between an ethylenically unsaturated epoxide and an SiH-containing silicone to produce an epoxysilicone product, and catalyzed by a rhodium containing selective catalyst which does not promote the oxirane ring-opening reaction of either the ethylenically unsaturated epoxide starting material or the epoxysilicone product. The invention also provides for a curable epoxysilicone composition made by the above method for the catalyst, and two methods of making the catalyst.
Abstract translation: 本发明提供了一种通过烯键式不饱和环氧化物和含SiH的硅氧烷之间的硅氢化反应制备可固化环氧硅氧烷组合物以制备环氧硅氧烷产物的方法，并且通过不促进环氧乙烷开环反应的含铑选择性催化剂催化 的烯键式不饱和环氧化物起始材料或环氧硅氧烷产物。 本发明还提供了通过上述催化剂方法制备的可固化环氧硅氧烷组合物和两种制备催化剂的方法。
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Patent Agency Ranking6.发明授权Platinum-based catalysts for the polymerization of vinyl ether monomers and polymers 失效用于聚合乙烯基醚单体和聚合物的铂基催化剂
公开(公告)号：US5272233A
公开(公告)日：1993-12-21
申请号：US916283
申请日：1992-07-17
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: C08F4/06 , C08F4/26 , C08F4/80 , C08F16/12 , C08F16/14 , C08F290/00 , C08F299/02 , C08F299/08 , C08L83/07 , C08F130/08 , C08F116/12
Abstract: The present invention relates to a curable polyvinyl ether composition created using a novel catalyst system for the synthesis of polyethers from vinyl ether monomers or polymers. This catalyst system comprises a platinum complex catalyst and silicon hydride cocatalyst. The invention also relates to a method of producing polyethers from vinyl ether monomers or polymers using the above-mentioned catalyst system.
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7.发明授权Regiospecific catalyst for the synthesis of epoxysiloxane monomers and polymers 失效用于合成环氧硅氧烷单体和聚合物的区域特异性催化剂
公开(公告)号：US5260399A
公开(公告)日：1993-11-09
申请号：US895315
申请日：1992-06-08
Applicant: James V. Crivello , Mingxin Fan
Inventor： James V. Crivello , Mingxin Fan
IPC: B01J31/24 , B01J31/28 , C07B61/00 , C07F7/08 , C07F7/18 , C08G77/14 , C08G77/22 , C08G77/38 , C08G77/06
CPC classification number: C07F7/0829 , C07F7/0879 , C07F7/1876 , C08G77/38
Abstract: The invention provides a method for making an epoxysilicone compound through the hydrosilation addition reaction between an ethylenically unsaturated epoxide and an SiH-containing silicon to produce an epoxysilicone product, and catalyzed by a regiospecific hydrosilation catalyst which does not also promote an oxirane ring-opening polymerization reaction in either the ethylenically unsaturated epoxide starting compound or in the epoxysilicone hydrosilation reaction product. The invention also provides a hydrosilation catalyst with the above catalytic properties as well as an epoxysilicone composition made by the above method.
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8.发明申请公开(公告)号：US20050154121A1
公开(公告)日：2005-07-14
申请号：US11035357
申请日：2005-01-12
Applicant: Mingxin Fan , Jeffrey Allan Klang , Gary Ceska , James Horgan
Inventor： Mingxin Fan , Jeffrey Allan Klang , Gary Ceska , James Horgan
CPC classification number: C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
Abstract: A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
Abstract translation: 一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝剂，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层， 焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎 发动机支架，垫片，高尔夫球芯和橡胶辊。
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公开(公告)号：US06124483A
公开(公告)日：2000-09-26
申请号：US773524
申请日：1996-12-23
Applicant: Mingxin Fan , Gary W. Ceska , James Horgan
Inventor： Mingxin Fan , Gary W. Ceska , James Horgan
IPC: B01J31/24 , B01J31/34 , C07D301/12 , C07D303/16 , C07D303/24 , C07D303/40 , C08F20/32 , C08G59/24
CPC classification number: C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
Abstract: Process of making compounds of the formula ##STR1## wherein R.sub.1 =(C.sub.1 -C.sub.6) alkyl;X=O, S, NH;R.sub.2 =divalent saturated organic group;Y=O, S, NH, ester;R.sub.3 =cyclic moiety containing oxirane group;comprising reacting a compound of the formula ##STR2## wherein R.sub.4 is a cyclic moiety containing C.dbd.C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst;polymers of compounds of formula I; andcompounds of formula I except for compounds wherein R.sub.4 is a dicyclopentenyl epoxide, Y is O, R.sub.2 is --CH.sub.2 CH.sub.2 --, X is O, and R.sub.1 is H or methyl.
Abstract translation: 制备下式化合物的方法其中R1 =（C1-C6）烷基; X = O，S，NH; R2 =二价饱和有机基团; Y = O，S，NH，酯; R3 =含环氧乙烷基团的环状部分; 包括在（a）钨酸，（b）磷酸或其金属盐存在下使下式化合物其中R 4是含有C = C基团的环状部分与过氧化氢反应，和（c）至少一种相转移 催化剂; 式I化合物的聚合物; 和式I化合物，除了其中R 4是二环戊烯基环氧化物，Y是O，R 2是-CH 2 CH 2 - ，X是O，R 1是H或甲基的化合物。
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10.发明授权公开(公告)号：US07569641B2
公开(公告)日：2009-08-04
申请号：US11035357
申请日：2005-01-12
Applicant: Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
Inventor： Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
CPC classification number: C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
Abstract: A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
Abstract translation: 一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝料，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层， 焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎 发动机支架，垫片，高尔夫球芯和橡胶辊。
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