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1.发明申请公开(公告)号：US20100143608A1
公开(公告)日：2010-06-10
申请号：US12598530
申请日：2008-04-29
IPC分类号： C23C16/06 , C23C16/513
CPC分类号： C23C16/06 , C23C18/1216 , C23C18/1225 , C23C18/1245 , C23C18/1287 , C23C18/1295
摘要： Method for preparing a substrate comprising a solid support and a plurality of layers on the support; at least one layer consisting of a uniform, homogeneous, and continuous film of particles of one or more metal oxide(s), or of uniformly, homogeneously, dispersed particles of one or more metal oxide(s), on the support or on an underlying layer; at least one layer consisting of a continuous or discontinuous film of one or more metal(s) or of one or more metal alloy(s), or of dispersed nanoparticles of one or more metal(s) or of one or more metal alloy(s), on the support or on an underlying layer; the method comprising the following steps: a)—impregnating the heated solid support or an already deposited underlying layer with a solution of precursors of the metal oxide or oxides in a supercritical fluid, and depositing a uniform, homogeneous, and continuous film of particles of one or more metal oxide(s), or of uniformly, homogeneously, dispersed particles of one or more metal oxide(s), on the support or on the underlying layer; b)—depositing a continuous or discontinuous film of one or more metal(s) or of one or more metal alloy(s), or dispersed nanoparticles of one or more metal(s) or of one or more metal alloy(s), on the support or on an underlying layer, by chemical vapour deposition CVD, from one or more precursors; the steps a) and b) being carried out in the same chamber, same reactor.
摘要翻译： 在载体上制备包括固体支持物和多个层的基材的方法; 至少一层由均匀的，均匀的和连续的一层或多层金属氧化物的颗粒膜或一个或多个均匀分散的一种或多种金属氧化物颗粒组成的层，在载体上或在 下层 至少一层由一种或多种金属或一种或多种金属合金的连续或不连续膜组成，或由一种或多种金属或一种或多种金属合金的分散纳米颗粒（ s），在支撑上或在下层上; 该方法包括以下步骤：a）将加热的固体载体或已经沉积的下层与金属氧化物或氧化物的前体溶液浸渍在超临界流体中，并沉积均匀，均匀和连续的 一种或多种金属氧化物或均匀均匀分布的一种或多种金属氧化物的颗粒在载体上或下层上; b）沉积一种或多种金属或一种或多种金属合金或一种或多种金属或一种或多种金属合金的分散纳米颗粒的连续或不连续膜， 通过化学气相沉积CVD从一种或多种前体在载体上或在下层上; 步骤a）和b）在相同的室内进行，同一反应器。
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公开(公告)号：US20090186153A1
公开(公告)日：2009-07-23
申请号：US12300785
申请日：2007-05-14
申请人： Audrey Hertz , Bruno Fournel , Christian Guizard , Anne Julbe , Jean-Christophe Ruiz , Stephane Sarrade
发明人： Audrey Hertz , Bruno Fournel , Christian Guizard , Anne Julbe , Jean-Christophe Ruiz , Stephane Sarrade
IPC分类号： B05D7/00
CPC分类号： B01J13/02 , B01J3/008 , B01J13/14 , B01J19/26 , B01J2219/00006 , B01J2219/0004 , B01J2219/00768
摘要： A process for the “in situ” manufacture, in a pressurized CO2 medium, of coated particles. The manufacturing process is characterized in that the steps of synthesising the particles and of coating these particles are coupled in such a way that the synthesised particles remain dispersed in a pressurized CO2 medium at least until the coating. The device comprises a reactor for synthesising particles in a pressurized CO2 medium; a means of injecting the coating material or precursor thereof into said reactor; a means of supplying said reactor with a pressurized CO2 medium; in which the means of injecting the coating material or precursor thereof is coupled to the synthesis reactor in such a way that the injection of the coating material or precursor thereof into said reactor does not destroy the dispersion of the particles, in a pressurized CO2 medium, in said reactor.
摘要翻译： 在加压CO2介质中“涂覆颗粒”的“原位”制造方法。 制造方法的特征在于合成颗粒和涂覆这些颗粒的步骤以使得合成的颗粒保持分散在加压的CO 2介质中至少直到涂层的方式进行偶联。 该装置包括用于在加压的CO 2介质中合成颗粒的反应器; 将涂料或其前体注入所述反应器的方法; 向所述反应器供应加压的CO 2介质的装置; 其中将涂覆材料或其前体注入的方法以这样的方式耦合到合成反应器，使得将涂料或其前体注入所述反应器不会破坏颗粒在加压的CO 2介质中的分散， 在所述反应器中。
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公开(公告)号：US06475296B1
公开(公告)日：2002-11-05
申请号：US09744568
申请日：2001-01-25
IPC分类号： G21F900
CPC分类号： G21F9/002 , C11D1/72 , C11D11/0029 , C11D11/0041 , C11D17/003 , C23G1/14
摘要： The present invention relates to a degreasing composition, to a liquid, to a gel and to a degreasing foam which comprise said composition. The composition according to the invention comprises a base, a polyethoxylated fatty alcohol, saturated or unsaturated, a copolymer of ethylene oxide and propylene oxide, and water. The invention also relates to a degreasing and/or decontamination process of a surface using said composition, said liquid, said gel, and/or said degreasing foam.
摘要翻译： 本发明涉及包含所述组合物的脱脂组合物，液体，凝胶和脱脂泡沫。根据本发明的组合物包含碱，聚乙氧基化脂肪醇，饱和或不饱和的环氧乙烷共聚物 和环氧丙烷，和水。 本发明还涉及使用所述组合物，所述液体，所述凝胶和/或所述脱脂泡沫的表面的脱脂和/或去污处理。
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公开(公告)号：US07662754B2
公开(公告)日：2010-02-16
申请号：US10520438
申请日：2003-07-04
申请人： Sylvain Faure , Bruno Fournel , Paul Fuentes
发明人： Sylvain Faure , Bruno Fournel , Paul Fuentes
IPC分类号： G21F9/00
CPC分类号： G21F9/28 , C11D1/662 , C11D1/75 , C11D1/92 , C11D3/0094 , C11D3/042 , C11D3/044 , C11D3/222 , C11D11/0058 , C11D17/003
摘要： The invention relates to a composition which makes it possible to obtain a gelled aqueous foam capable of decontaminating, stripping or degreasing a surface. The composition of the present invention comprises one or more surfactants, one or more acidic or basic reactants and a gelling agent.The decontamination foam obtained from this composition exhibits long lifetimes, generally of between 1 and 10 hours, guaranteeing a prolonged time of action on the surface and a high decontamination effectiveness. These foams can be used to remove the radioactivity from an inaccessible plant, which is large in size and complex in design, by simple filling or by simple spraying over an accessible surface.
摘要翻译： 本发明涉及一种组合物，其可以获得能够净化，剥离或脱脂表面的凝胶状水性泡沫。 本发明的组合物包含一种或多种表面活性剂，一种或多种酸性或碱性反应物和胶凝剂。 由该组合物获得的去污泡沫体的寿命长，通常为1至10小时，保证了表面上延长的作用时间和高的去污效果。 这些泡沫可以用于通过简单的填充或通过在易于接近的表面上的简单喷涂来消除尺寸大且设计复杂的不可接近的植物的放射性。
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5.发明授权Method for generating and circulating a foam in an installation and system for application of this method 失效用于在安装中产生和循环泡沫的方法以及用于该方法的系统公开(公告)号：US06932330B2
公开(公告)日：2005-08-23
申请号：US10378882
申请日：2003-03-05
申请人： Bruno Fournel , Maria Faury , Jean-Marie Le Samedy
发明人： Bruno Fournel , Maria Faury , Jean-Marie Le Samedy
CPC分类号： B01F3/04446 , B01F5/0696
摘要： The invention relates to a method for generating a foam from a liquid phase and a gas phase, a method for placing a foam in circulation in an installation, and a method for cleaning an installation by placing a foam in circulation.Generation of the foam is made by aspiration of an appropriate liquid phase and an appropriate gas phase to generate a foam through a porous lining.The invention also relates to a system for generating a foam and to a system for generating and placing a foam in circulation in an installation.
摘要翻译： 本发明涉及一种用于从液相和气相产生泡沫的方法，在安装中将泡沫放置在循环中的方法，以及通过将泡沫放置在循环中来清洁装置的方法。 通过抽吸合适的液相和合适的气相来制造泡沫以通过多孔衬里产生泡沫。 本发明还涉及一种用于产生泡沫的系统和用于在安装中产生和放置泡沫循环的系统。
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6.发明授权Process for decontaminating an organic solid substrate contaminated by solid radioactive particulate inorganic contaminants, using dense pressurized CO2 有权用固体放射性颗粒无机污染物污染有机固体底物的方法，使用致密的加压二氧化碳公开(公告)号：US08172955B2
公开(公告)日：2012-05-08
申请号：US12280205
申请日：2007-02-23
申请人： Bruno Fournel , Julien Galy , Frédéric Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jérôme Blancher
发明人： Bruno Fournel , Julien Galy , Frédéric Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jérôme Blancher
CPC分类号： B01D11/0203 , B08B3/02 , B08B3/045 , B08B3/102 , B08B3/104 , B08B3/12 , B08B7/0021 , B08B2203/0288 , G21F9/125
摘要： Process for decontaminating, cleaning a solid organic substrate contaminated by solid radioactive particulate inorganic contaminants, in which: the said solid substrate is brought into contact with an extraction medium, devoid of water, comprising: dense pressurized CO2; at least one nonhalogenated surface-active compound chosen from block copolymers of poly(ethylene oxide) PEO and poly(propylene oxide) PPO, such as (EO)x-(PO)y diblock copolymers, (EO)x-(PO)y-(EO)x triblock copolymers and (PO)x-(EO)y-(PO)x, triblock copolymers, where x and y are integers from 2 to 80 with x other than y; and polydi(1 to 6C)alkylsiloxanes, such as polydimethylsiloxane (PDMS); and at least one complexing agent chosen from tributyl phosphate (TBP), crown ethers, tributylphosphine oxide, triphenylphosphine oxide and tri(n-octyl)phosphine oxide; the solid substrate and/or the extraction medium is/are subjected, simultaneously with the contacting operation, to a mechanical action.
摘要翻译： 用于净化，清洁被固体放射性颗粒无机污染物污染的固体有机基质的方法，其中：使所述固体基质与无水的萃取介质接触，所述提取介质包含：加压的CO 2; 至少一种选自聚（环氧乙烷）PEO和聚（环氧丙烷）PPO的嵌段共聚物的非卤代表面活性化合物，例如（EO）x-（PO）y二嵌段共聚物，（EO）x-（PO）y - （EO）x三嵌段共聚物和（PO）x-（EO）y-（PO）x，三嵌段共聚物，其中x和y是2至80的整数，x不是y; 和聚二（1至6C）烷基硅氧烷，如聚二甲基硅氧烷（PDMS）; 和至少一种选自磷酸三丁酯（TBP），冠醚，三丁基氧化膦，三苯基氧化膦和三（正辛基）氧化膦的络合剂; 固体基质和/或提取介质在接触操作的同时受到机械作用。
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7.发明申请Process for Decontaminating an Organic Solid Substrate Contaminated by Solid Radioactive Particulate Inorganic Contaminants, Using Dense Pressurized CO2 有权用固体放射性微粒无机污染物污染有机固体基质去除污染的方法，使用密集加压的CO2公开(公告)号：US20090056742A1
公开(公告)日：2009-03-05
申请号：US12280205
申请日：2007-02-23
申请人： Bruno Fournel , Julien Galy , Frederic Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jerome Blancher
发明人： Bruno Fournel , Julien Galy , Frederic Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jerome Blancher
CPC分类号： B01D11/0203 , B08B3/02 , B08B3/045 , B08B3/102 , B08B3/104 , B08B3/12 , B08B7/0021 , B08B2203/0288 , G21F9/125
摘要： Process for decontaminating, cleaning a solid organic substrate contaminated by solid radioactive particulate inorganic contaminants, in which: the said solid substrate is brought into contact with an extraction medium, devoid of water, comprising: dense pressurized CO2; at least one nonhalogenated surface-active compound chosen from block copolymers of poly(ethylene oxide) PEO and poly(propylene oxide) PPO, such as (EO)x-(PO)y diblock copolymers, (EO)x-(PO)y-(EO)x triblock copolymers and (PO)x-(EO)y-(PO), triblock copolymers, where x and y are integers from 2 to 80 with x other than y; and polydi(1 to 6C)alkylsiloxanes, such as polydimethylsiloxane (PDMS); and at least one complexing agent chosen from tributyl phosphate (TBP), crown ethers, tributylphosphine oxide, triphenylphosphine oxide and tri(n-octyl)phosphine oxide; the solid substrate and/or the extraction medium is/are subjected, simultaneously with the contacting operation, to a mechanical action.
摘要翻译： 用于净化，清洁被固体放射性颗粒无机污染物污染的固体有机基质的方法，其中：使所述固体基质与无水的萃取介质接触，所述提取介质包含：加压的CO 2; 至少一种选自聚（环氧乙烷）PEO和聚（环氧丙烷）PPO的嵌段共聚物的非卤代表面活性化合物，例如（EO）x-（PO）y二嵌段共聚物，（EO）x-（PO）y - （EO）x三嵌段共聚物和（PO）x-（EO）y-（PO），三嵌段共聚物，其中x和y是2至80的整数，x不是y; 和聚二（1至6C）烷基硅氧烷，如聚二甲基硅氧烷（PDMS）; 和至少一种选自磷酸三丁酯（TBP），冠醚，三丁基氧化膦，三苯基氧化膦和三（正辛基）氧化膦的络合剂; 固体基质和/或提取介质在接触操作的同时受到机械作用。
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公开(公告)号：US06905610B2
公开(公告)日：2005-06-14
申请号：US10432997
申请日：2001-11-28
IPC分类号： B01D53/18 , B01F3/04 , B01F3/08 , B01F5/02 , B01F5/10 , B01J4/00 , B01J10/00 , B01J19/26 , C02F1/72 , C02F1/78
CPC分类号： B01J19/26 , B01F3/04099 , B01F3/0876 , B01F5/0218 , B01F5/0268 , B01F5/10 , B01F2003/04879 , B01F2003/04886 , B01J4/001 , B01J10/002 , Y10S261/75
摘要： A method, a module, and a device for gas-liquid contacting. The liquid is sent, in the presence of the gas, in jet form in a first direction onto a wall inclined at an angle of 35-55 degrees with respect to the first direction, the wall dispersing the liquid jet into the gas. The module includes a structure (23, 25) for sending a liquid jet in a first direction, a structure (21) for creating a gas flow, and a wall (11) inclined at an angle of 35-55 degrees.
摘要翻译： 一种用于气液接触的方法，模块和装置。 液体在气体存在下以第一方向以喷射形式被送到相对于第一方向以35-55度的角度倾斜的壁上，壁将液体射流分散到气体中。 模块包括用于沿第一方向发送液体射流的结构（23,25），用于产生气流的结构（21）和以35-55度的角度倾斜的壁（11）。
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9.发明授权Method for generating and circulating a foam in an installation and system for application of this method 有权用于在安装中产生和循环泡沫的方法以及用于该方法的系统公开(公告)号：US06561200B1
公开(公告)日：2003-05-13
申请号：US09582529
申请日：2000-07-13
申请人： Bruno Fournel , Maria Faury , Jean-Marie Le Samedy
发明人： Bruno Fournel , Maria Faury , Jean-Marie Le Samedy
IPC分类号： B08B9027
CPC分类号： B01F3/04446 , B01F5/0696
摘要： The invention relates to a method for generating a foam from a liquid phase and a gas phase, a method for placing a foam in circulation in an installation, and a method for cleaning an installation by placing a foam in circulation. Generation of the foam is made by aspiration of an appropriate liquid phase and an appropriate gas phase to generate a foam through a porous lining. The invention also relates to a system for generating a foam and to a system for generating and placing a foam in circulation in an installation.
摘要翻译： 本发明涉及一种用于从液相和气相产生泡沫的方法，在安装中将泡沫放置在循环中的方法，以及通过将泡沫放置在循环中来清洁装置的方法。泡沫的生成是 通过适当的液相和适当的气相的抽吸制成，以通过多孔衬里产生泡沫。本发明还涉及一种用于产生泡沫的系统和用于在安装中循环产生和放置泡沫的系统。
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公开(公告)号：US07718010B2
公开(公告)日：2010-05-18
申请号：US11200700
申请日：2005-08-09
申请人： Sylvain Faure , Bruno Fournel , Paul Fuentes , Yvan Lallot
发明人： Sylvain Faure , Bruno Fournel , Paul Fuentes , Yvan Lallot
IPC分类号： B08B7/00
摘要： The present invention related to a method for treating a surface with a gel, as well as to a treatment gel.The treatment may be a decontamination, etching or surface degreasing treatment, for example.The method comprises in this order, the following steps: applying the treatment gel on the surface to be treated, maintaining the treatment gel on the surface to be treated at a temperature and relative humidity such that the gel dries by breaking up and that it has the time to treat the surface before forming a dry and solid residue, and removing the dry and solid residue from the treated surface by suction or brushing.The gel comprises a viscosing agent, a treatment agent and optional an oxidizing agent.
摘要翻译： 本发明涉及用凝胶处理表面的方法以及处理凝胶。 处理可以是例如去污，蚀刻或表面脱脂处理。 该方法包括以下步骤：将处理凝胶涂覆在待处理的表面上，在温度和相对湿度下将处理凝胶保持在待处理的表面上，使得凝胶通过分解而干燥，并且其具有 在形成干燥和固体残余物之前处理表面的时间，以及通过抽吸或刷涂从处理过的表面除去干燥和固体残余物。 凝胶包括粘胶剂，处理剂和任选的氧化剂。
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