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1.发明授权
公开(公告)号：US4628130A
公开(公告)日：1986-12-09
申请号：US763596
申请日：1985-08-08
IPC分类号： C07C29/136 , B01J23/00 , B01J23/825 , B01J23/835 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/02 , C07C67/00 , C07C37/055
CPC分类号： C07C29/149 , Y02P20/52
摘要： The invention has as an object the production of alcohols by hydrogenolysis of carboxylic acid esters, under hydrogen pressure, in the presence of a catalyst resulting from the incorporation of at least one compound of at least one metal from the group consisting of germanium, tin and lead to Raney nickel or to a nickel-containing carrier. The reaction is preferably conducted at a temperature from 180.degree. to 330.degree. C. and under a pressure from 1 to 10 MPa.
摘要翻译： 本发明的目的是通过在氢气压力下，在催化剂存在下，通过羧酸酯的氢解来生产醇，所述催化剂是由至少一种至少一种由锗，锡和 导致阮内镍或含镍载体。 反应优选在180至330℃的温度和1至10MPa的压力下进行。
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公开(公告)号：US5118884A
公开(公告)日：1992-06-02
申请号：US578113
申请日：1990-09-06
IPC分类号： B01J23/62 , C07B61/00 , C07C29/141 , C07C33/02
CPC分类号： C07C33/02 , C07C29/141
摘要： The invention concerns the production of a diolefinic unsaturated alcohol such as geraniol or nerol by the selective hydrogenation of citral. It is characterized by the use of a catalyst based on a metal from group VIII and based on a metal selected from the group made up of tin, germanium and lead, on preferably a silica carrier.
摘要翻译： 本发明涉及通过柠檬醛的选择性氢化生产二烯属不饱和醇如香叶醇或橙花醇。 其特征在于使用基于VIII族金属的催化剂，并且基于选自锡，锗和铅的金属，优选二氧化硅载体。
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公开(公告)号：US07393454B2
公开(公告)日：2008-07-01
申请号：US10471843
申请日：2002-03-12
IPC分类号： C02F1/28
CPC分类号： C02F1/705 , C02F1/02 , C02F1/281 , C02F2101/20 , C02F2101/22 , Y10S210/912
摘要： Method for the elimination of metal ions from aqueous media, such as zinc, lead, chrome, copper, iron, aluminium, manganese, cadmium, cerium or silver and mixtures of the metals present in a trace or ultratrace state in aqueous effluents, by adsorption on a solid charge containing a metal chosen from group VIII.
摘要翻译： 从含水介质如锌，铅，铬，铜，铁，铝，锰，镉，铈或银等水介质中除去金属离子的方法，以及痕量或超过两种状态的金属在含水废水中的混合物，通过吸附 在含有选自VIII族金属的固体电荷上。
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4.发明授权Process for preparing catalysts for use in organic compound transformation reactions 有权制备用于有机化合物转化反应的催化剂的方法公开(公告)号：US06281160B1
公开(公告)日：2001-08-28
申请号：US09182658
申请日：1998-10-30
申请人： Jean-Marie Basset , Jean-Pierre Candy , Blaise Didillon , Fabienne Le Peltier , Olivier Clause , Fatima Bentahar
发明人： Jean-Marie Basset , Jean-Pierre Candy , Blaise Didillon , Fabienne Le Peltier , Olivier Clause , Fatima Bentahar
IPC分类号： B01J2340
CPC分类号： B01J37/086 , B01J23/62 , B01J37/0203 , C07C5/3337 , C07C2523/08 , C07C2523/14 , C07C2523/36 , C07C2523/40 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C11/02
摘要： In a process for preparing a catalyst comprising at least one support, at least one metal from group VIII of the periodic table and at least one additional element M selected from the group formed by germanium, tin, lead, rhenium, gallium, indium and thallium, metal M is introduced in an aqueous solvent in the form of at least one organometalic compound comprising at least one carbon-M bond.
摘要翻译： 在制备包含至少一种载体的催化剂的方法中，至少一种来自元素周期表第Ⅷ族的金属和至少一种选自锗，锡，铅，铼，镓，铟和铊的另外的元素M 金属M以包含至少一个碳-M键的至少一种有机金属化合物的形式引入水性溶剂中。
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5.发明授权Process for preparing a Ni/Sn supported catalyst for the selective hydrogenation of polyunsaturated hydrocarbons 失效制备用于多不饱和烃选择性氢化的Ni / Sn负载催化剂的方法公开(公告)号：US08637425B2
公开(公告)日：2014-01-28
申请号：US12857029
申请日：2010-08-16
申请人： Lars Fischer , Anne-Claire Dubreuil , Cecile Thomazeau , Layane Deghedi , Jean-Pierre Candy , Jean-Marie Basset , Fabienne Le Peltier
发明人： Lars Fischer , Anne-Claire Dubreuil , Cecile Thomazeau , Layane Deghedi , Jean-Pierre Candy , Jean-Marie Basset , Fabienne Le Peltier
IPC分类号： B01J21/00
CPC分类号： C10G45/36 , B01J21/04 , B01J21/08 , B01J23/835 , B01J37/0238 , B01J37/18 , C07C5/05 , C07C2523/835 , C10G2300/1088 , C10G2300/1096 , C10G2300/4018 , C10G2300/703 , C07C15/073
摘要： A process is described for preparing a catalyst comprising at least one porous support and at least one metallic phase containing nickel and tin in a proportion such that the Sn/Ni molar ratio is in the range 0.01 to 0.2, said process comprising at least the following steps in succession: a) depositing nickel on at least said support in order to obtain a supported nickel-based monometallic catalyst; b) reducing said monometallic catalyst in the presence of at least one reducing gas; c) depositing, in the gas phase and in the presence of at least one reducing gas, at least one organometallic tin compound onto said reduced monometallic catalyst; and d) activating the solid derived from said step c) in the presence of at least one reducing gas.
摘要翻译： 描述了一种制备催化剂的方法，该催化剂包含至少一种多孔载体和至少一种含镍和锡的金属相，其比例使得Sn / Ni摩尔比在0.01至0.2的范围内，所述方法至少包括以下 连续步骤：a）在至少所述载体上沉积镍以获得负载的镍基单金属催化剂; b）在至少一种还原气体的存在下还原所述单金属催化剂; c）在气相和至少一种还原气体的存在下，将至少一种有机金属锡化合物沉积在所述还原的单金属催化剂上; 和d）在至少一种还原气体的存在下活化来自所述步骤c）的固体。
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公开(公告)号：US20060108290A1
公开(公告)日：2006-05-25
申请号：US10525252
申请日：2003-08-19
IPC分类号： C02F1/42
CPC分类号： C02F1/281 , B01J20/02 , C02F1/705 , C02F2101/103 , C02F2101/20
摘要： The invention relates to a method of reducing the ionic metal content of aqueous effluents. The inventive method consists in bringing an aqueous effluent loaded with metal ions into contact with at least one hydrogen-covered metal.
摘要翻译： 本发明涉及一种降低含水废水的离子金属含量的方法。 本发明的方法包括使负载有金属离子的含水流出物与至少一个氢覆盖的金属接触。
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7.发明授权Catalytic reduction of substituted or unsubstituted nitroaromatic compound to corresponding aminoaromatic compounds 失效取代或未经取代的硝基化合物的催化还原相应的氨基化合物
公开(公告)号：US5235106A
公开(公告)日：1993-08-10
申请号：US817559
申请日：1992-01-07
申请人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
发明人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
IPC分类号： B01J23/62 , C07B61/00 , C07C209/36 , C07C209/38 , C07C211/52 , C07C211/56 , C07C213/02 , C07C215/76 , C07C217/82 , C07C219/34
CPC分类号： B01J23/622 , C07C209/36 , C07C209/365
摘要： The invention concerns the production of a substituted or unsubstituted aniline by selective hydrogenation of the corresponding nitroaromatic compound. It is characterized by the use of a catalyst based on a metal selected from rhodium and ruthenium and based on a metal selected from the group comprising tin, germanium and lead.
摘要翻译： 本发明涉及通过相应的硝基芳族化合物的选择性氢化生产取代或未取代的苯胺。 其特征在于使用基于选自铑和钌的金属和基于选自锡，锗和铅的金属的催化剂。
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8.发明申请METHOD FOR PREPARING A STRUCTURED POROUS MATERIAL COMPRISING NANOPARTICLES OF METAL 0 IMBEDDED IN THE WALLS THEREOF 审中-公开制备包含在其中的金属0纳米颗粒的结构化多孔材料的方法公开(公告)号：US20110257006A1
公开(公告)日：2011-10-20
申请号：US13122420
申请日：2009-09-24
CPC分类号： B01J29/0308 , B01J23/42 , B01J23/462 , B01J29/041 , B01J35/0013 , B01J35/006 , B01J35/1023 , B01J35/1028 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/18 , B82Y30/00 , C01B33/02 , C01G23/00 , C01G23/002 , C01P2002/72 , C01P2004/64 , C01P2004/84 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , C07C5/03 , C07C2523/745 , C07C15/073
摘要： The present invention relates to a process for producing a structured porous material comprising a structured inorganic framework made up of metal-oxide based walls in which nanoparticles of metal 0 are incorporated, which comprises the following steps: a) formation of a suspension of hydrophilic nanoparticles of metal 0 stabilized by non-exchangeable ligands that give the nanoparticles their hydrophilic character; b) growth of the inorganic framework from an inorganic precursor around the nanoparticles of metal 0 stabilized by the non-exchangeable hydrophilic ligands, in the presence of a pore-forming agent; and c) elimination of the pore-forming agent and at least partially of the non-exchangeable ligands that give the nanoparticles their hydrophilic character.
摘要翻译： 本发明涉及一种生产结构化多孔材料的方法，其包括由金属氧化物基壁形成的结构化无机骨架，其中纳入金属O的纳米颗粒，其包括以下步骤：a）形成亲水性纳米颗粒的悬浮液 的非可交换配体稳定的金属0，使纳米颗粒具有亲水性; b）在成孔剂存在下，通过由不可交换的亲水性配体稳定的金属0的纳米颗粒周围的无机前体生长无机骨架; 和c）消除造孔剂和至少部分不可交换的配体，使纳米颗粒具有亲水性。
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公开(公告)号：US20110220579A1
公开(公告)日：2011-09-15
申请号：US13113350
申请日：2011-05-23
CPC分类号： C02F1/281 , B01J20/02 , C02F1/705 , C02F2101/103 , C02F2101/20
摘要： The invention relates to a method of reducing the ionic metal content of aqueous effluents. The inventive method consists in bringing an aqueous effluent loaded with metal ions into contact with at least one hydrogen-covered metal.
摘要翻译： 本发明涉及一种降低含水废水的离子金属含量的方法。 本发明的方法包括使负载有金属离子的含水流出物与至少一个氢覆盖的金属接触。
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10.发明授权Process for the selective hydrogenation of compounds comprising endo and exocyclic unsaturations 失效用于选择性氢化包含内环和外环不饱和化合物的方法
公开(公告)号：US5475174A
公开(公告)日：1995-12-12
申请号：US156777
申请日：1993-11-24
CPC分类号： C07C5/05 , B01J23/622 , C07C2101/14 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2523/755 , C07C2523/835
摘要： The invention concerns a process for the selective hydrogenation of polyunsaturated cyclic compounds comprising at least one endocyclic carbon-carbon double bond and at least one terminal exocyclic carbon-carbon double bond, said double bonds not being conjugated, to form a mixture essentially containing the saturated ring compound and comprising at least one terminal exocyclic double bond, the process being carried out in the presence of hydrogen under a pressure of from 1 to 10 MPa and at a temperature of from 0.degree. to 200.degree. C., and in the presence of a catalyst including a support and (a) from 0.1 to 5% by weight of at least one metal from group VIII (iridium, osmium, nickel, palladium, platinum and rhodium) and (b) from 0.01 to 15% by weight of at least one metal from group IVa (tin, germanium and lead), the molar ratio between metals of group VIII and group IVa being between 0.3 and 3. The process is used for the hydrogenation of 4-vinylcylcohexene to vinylcyclohexane.
摘要翻译： 本发明涉及包含至少一个内环碳 - 碳双键和至少一个末端环外碳 - 碳双键的多不饱和环状化合物的选择性氢化的方法，所述双键不是共轭的，以形成基本上含有饱和的 环化合物并且包含至少一个末端环外双键，该方法在氢气存在下，在1至10MPa的压力和0至200℃的温度下进行，并且在 包含载体的催化剂和（a）0.1至5重量％的至少一种第VIII族金属（铱，锇，镍，钯，铂和铑）和（b）0.01至15重量％ 来自IVa族（锡，锗和铅）的至少一种金属，VIII族和IVa族金属之间的摩尔比在0.3和3之间。该方法用于将4-乙烯基环己烯氢化成乙烯基环己烷。
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