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公开(公告)号：US07361798B2
公开(公告)日：2008-04-22
申请号：US10946553
申请日：2004-09-21
CPC分类号： C07C6/126 , Y02P20/582 , C07C15/02
摘要： The invention relates to a process for producing a desired dialkylbenzene isomer having a formula R2C6H4, where R is an alkyl substituent, by contacting a polyalkylbenzene compound of formula RnC6H6-n, where n is an integer between 2 and 4, with a monoalkylbenzene compound of formula RC6H5 in the presence of a molecular sieve catalyst under reaction conditions sufficient to produce said dialkybenzene isomer. The preferred molecular sieve catalysts have pores or surface cavities greater than 5.6 Angstroms in diameter and/or an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07, and 3.42±0.07 Angstrom.
摘要翻译： 本发明涉及制备具有式R 2 C 6 H 4 H 4的所需二烷基苯异构体的方法，其中R是烷基取代基， 通过使式R n 6 C 6 H 6-n N的多烷基苯化合物（其中n是2和4之间的整数）与单烷基苯 在分子筛催化剂存在下，在足以产生所述二烷基苯异构体的反应条件下，式RC 6 H 5 H 5的化合物。 优选的分子筛催化剂具有直径大于5.6埃的孔或表面空腔和/或包括在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃处的d间距最大值的X射线衍射图。
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2.发明授权Using a catalyst having two different zeolites for transalkylation of a C9+ aromatic feed 失效使用具有两个不同沸石的催化剂用于C9 +芳烃进料的烷基转移公开(公告)号：US07485763B2
公开(公告)日：2009-02-03
申请号：US11592832
申请日：2006-11-03
申请人： John Scott Buchanan , Ronald J. Cimini , Robert A. Crane , Wenyih F. Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber
发明人： John Scott Buchanan , Ronald J. Cimini , Robert A. Crane , Wenyih F. Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber
IPC分类号： C07C6/12
CPC分类号： B01J29/80 , B01J29/40 , B01J29/44 , B01J29/48 , B01J29/70 , B01J29/74 , B01J29/78 , B01J35/002 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C10G45/64 , Y02P20/52
摘要： In a process for converting C9+ aromatic hydrocarbons to lighter aromatic products a feed comprising C9+ aromatic hydrocarbons is contacted under transalkylation reaction conditions with a catalyst composition comprising (i) a first molecular sieve selected from the group consisting of ZSM-12, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07; and (ii) a second molecular sieve having a constraint index ranging from 3 to 12. At least the first molecular sieve has a hydrogenation component associated therewith and the first and second molecular sieves are contained in the same catalyst bed. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene.
摘要翻译： 在将C9 +芳族烃转化为较轻芳香族产物的方法中，在烷基转移反应条件下，将C9 +芳香烃进料与含有（i）选自ZSM-12，丝光沸石和多孔 具有在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07的d间距最大值的X射线衍射图的结晶无机氧化物材料; 和（ii）约束指数为3至12的第二分子筛。至少第一分子筛具有与之相关的氢化组分，并且第一和第二分子筛包含在相同的催化剂床中。 C9 +芳烃在烷基转移反应条件下转化为含有二甲苯的反应产物。
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公开(公告)号：US07148391B1
公开(公告)日：2006-12-12
申请号：US10294428
申请日：2002-11-14
申请人： John Scott Buchanan , Ronald J. Cimini , Frank Wenyih Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber , Robert A. Crane
发明人： John Scott Buchanan , Ronald J. Cimini , Frank Wenyih Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber , Robert A. Crane
IPC分类号： C07C5/52
CPC分类号： B01J29/80 , B01J29/40 , B01J29/44 , B01J29/48 , B01J29/70 , B01J29/74 , B01J29/78 , B01J35/002 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C10G45/64 , Y02P20/52
摘要： In a process for converting C9+ aromatic hydrocarbons to lighter aromatic products a feed comprising C9+ aromatic hydrocarbons is contacted under transalkylation reaction conditions with a catalyst composition comprising (i) a first molecular sieve selected from the group consisting of ZSM-12, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07; and (ii) a second molecular sieve having a constraint index ranging from 3 to 12. At least the first molecular sieve has a hydrogenation component associated therewith and the first and second molecular sieves are contained in the same catalyst bed. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene.
摘要翻译： 在将C 9+芳烃转化成较轻芳香族产物的方法中，包含C 9+芳烃的进料在烷基转移反应条件下与催化剂组合物接触，所述催化剂组合物包含（i） 选自ZSM-12，丝光沸石和具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07的d间距最大值的X射线衍射图的多孔结晶无机氧化物材料的第一分子筛 ; 和（ii）约束指数为3至12的第二分子筛。至少第一分子筛具有与之相关的氢化组分，并且第一和第二分子筛包含在相同的催化剂床中。 在烷基转移反应条件下将C 9+芳烃转化成含有二甲苯的反应产物。
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公开(公告)号：US07910779B2
公开(公告)日：2011-03-22
申请号：US12904215
申请日：2010-10-14
IPC分类号： C07C45/27 , C07C27/08 , C07C2/68 , C07C15/067
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US5865986A
公开(公告)日：1999-02-02
申请号：US552769
申请日：1995-11-03
申请人： John Scott Buchanan , Jane C. Cheng , David G. Freyman , Werner Otto Haag , Mohsen N. Harandi , Dominick N. Mazzone , Roger A. Morrison , Norman J. Rouleau , Charles M. Sorensen , Hye Kyung C. Timken , Robert Adams Ware
发明人： John Scott Buchanan , Jane C. Cheng , David G. Freyman , Werner Otto Haag , Mohsen N. Harandi , Dominick N. Mazzone , Roger A. Morrison , Norman J. Rouleau , Charles M. Sorensen , Hye Kyung C. Timken , Robert Adams Ware
摘要： This is a process for upgrading a petroleum naphtha fraction. The naphtha is subjected to reforming and the reformate is cascaded to a benzene and toluene synthesis zone over a benzene and toluene synthesis catalyst comprising a molecular sieve of low acid activity. The preferred molecular sieve is steamed ZSM-5. The benzene and toluene synthesis zone is operated under conditions compatible with the conditions of the reformer such as pressures of above about 50 psig (446 kPa) and temperatures above about 800.degree. F. (427.degree. C). In one aspect of the invention, the benzene and toluene synthesis catalyst includes a metal hydrogenation component such as cobalt, nickel, platinum or palladium. In one mode of operation, the benzene and toluene synthesis catalyst replaces at least a portion of the catalyst of the reformer. The process produces a product containing an increased proportion of benzene and toluene, and a reduced proportion of C8 aromatics, particularly ethylbenzenes, as compared to the reformate.
摘要翻译： 这是一种升级石脑油馏分的方法。 将石脑油进行重整，重整产物通过苯和甲苯合成催化剂层叠到苯和甲苯合成区，该催化剂包含低酸活性的分子筛。 优选的分子筛蒸ZSM-5。 苯和甲苯合成区在与重整器的条件相适应的条件下操作，例如高于约50psig（446kPa）的压力和高于约800°F（427℃）的温度。 在本发明的一个方面，苯和甲苯合成催化剂包括金属氢化组分如钴，镍，铂或钯。 在一种操作模式中，苯和甲苯合成催化剂代替重整器的至少一部分催化剂。 与重整产物相比，该方法产生含有苯和甲苯的比例增加的产物，以及与芳族化合物（特别是乙基苯）相比减少的比例。
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公开(公告)号：US20110028762A1
公开(公告)日：2011-02-03
申请号：US12904215
申请日：2010-10-14
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US20100179351A1
公开(公告)日：2010-07-15
申请号：US12663303
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US07906685B2
公开(公告)日：2011-03-15
申请号：US12601572
申请日：2008-08-12
IPC分类号： C07C45/27 , C07C27/08 , C07C2/68 , C07C15/067
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The ratio of the total number of moles of hydrogen fed to said at least one reaction zone to the number of moles of benzene fed to said at least one reaction zone is between 0.4 and 0.9:1.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 供给到所述至少一个反应区的氢的总摩尔数与进料到所述至少一个反应区的苯的摩尔数之比为0.4-0.9:1。
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公开(公告)号：US07847128B2
公开(公告)日：2010-12-07
申请号：US12663303
申请日：2008-08-12
IPC分类号： C07C45/27 , C07C37/08 , C07C2/68 , C07C15/067
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US20100197971A1
公开(公告)日：2010-08-05
申请号：US12601572
申请日：2008-08-12
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The ratio of the total number of moles of hydrogen fed to said at least one reaction zone to the number of moles of benzene fed to said at least one reaction zone is between 0.4 and 0.9:1.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 供给到所述至少一个反应区的氢的总摩尔数与进料到所述至少一个反应区的苯的摩尔数之比为0.4-0.9:1。
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