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    Simultaneous upgrading and dedusting of liquid hydrocarbon feedstocks
    4.
    发明授权
    Simultaneous upgrading and dedusting of liquid hydrocarbon feedstocks 失效
    液化烃原料同时升级除尘

    公开(公告)号：US5009770A

    公开(公告)日：1991-04-23

    申请号：US238929

    申请日：1988-08-31

    申请人： Jeffrey T. Miller ,  Albert L. Hensley, Jr.

    发明人： Jeffrey T. Miller ,  Albert L. Hensley, Jr.

    IPC分类号： C10G1/00 ,  C10G45/02 ,  C10G67/08

    CPC分类号： C10G1/002 ,  B01J8/0214 ,  C10G45/02 ,  C10G67/08 ,  B01J2208/00814 ,  B01J2208/00876

    摘要： A process of concurrently dedusting and upgrading particulate laden raw, whole retort oil is provided which comprises the steps of: retorting solid hydrocarbon-containing material such as oil shale to liberate an effluent stream of dust laden hydrocarbons; injecting the dust-laden retort effluent product stream into a catalytic hydrotreater; agitating the product stream in the hydrotreater to constantly maintain the particulates in suspension within the oil; catalytically hydrotreating the agitated product stream in the presence of a hydroprocessing gas at a pressure of from 500 to 3000 psi, a temperature of from 650.degree. to 850.degree. F. and a space velocity of from 0.1 to 6.0 hr.sup.-1, whereby the suspended particulates are agglomerated to facilitate solid-liquid separation and substantial amounts of sulfur and nitrogen contaminants are simultaneously removed from the resulting ungraded oil; and mechanically separating the agglomerated particulates from the upgraded whole oil. The product oil may be further upgraded either by treatment with aqueous sulfuric acid or by hydrotreatment.

    摘要翻译： 提供了一种同时除尘和升级含颗粒的生的全蒸馏油的方法，其包括以下步骤：对含油页岩的固体含烃材料进行蒸馏以释放含灰尘的碳氢化合物的流出物流; 将含灰尘的蒸馏出口产物流注入催化加氢处理器中; 在加氢处理机中搅拌产物流，以将颗粒物质不断地保持悬浮在油中; 在加氢处理气体的存在下，在500-3000psi的压力，650至850°F的温度和0.1至6.0hr-1的空间速度下催化加氢处理搅拌的产物流，由此悬浮 颗粒团聚以促进固液分离，同时从所得未分级油中除去大量的硫和氮污染物; 并将附聚的颗粒与升级的全油机械分离。 产品油可以通过用硫酸水溶液或通过加氢处理进一步升级。

    Para-Xylene Selective Adsorbent Compositions and Methods
    9.
    发明申请
    Para-Xylene Selective Adsorbent Compositions and Methods 审中-公开
    对二甲苯选择性吸附剂组合物和方法

    公开(公告)号：US20080200742A1

    公开(公告)日：2008-08-21

    申请号：US11470346

    申请日：2006-09-06

    申请人： Ruth Ann Doyle ,  Bryce A. Williams ,  Jeffrey T. Miller

    发明人： Ruth Ann Doyle ,  Bryce A. Williams ,  Jeffrey T. Miller

    IPC分类号： C07C5/22 ,  B01D59/26

    CPC分类号： B01J20/183 ,  B01J20/0292 ,  B01J20/2803 ,  B01J20/28069 ,  B01J20/28083 ,  B01J20/28085 ,  B01J20/28092 ,  C07C7/13 ,  C07C15/067

    摘要： Adsorbent compositions for vapor-phase adsorption processes, which are selective for para-xylene. Such compositions can be used in gas-phase adsorption processes for the separation of para-xylene or the separation of para-xylene and ethylbenzene from mixed xylenes or a C8 aromatic mixture, respectively. The adsorbent compositions generally comprise materials of a molecular sieve material and a binder, wherein the adsorbent composition has a macropore volume of at least about 0.02 cc/g and a mesopore volume of less than about 0.20 cc/g.

    摘要翻译： 用于气相吸附方法的吸附剂组合物，其对对二甲苯是选择性的。 这种组合物可以用于分离对二甲苯的气相吸附方法或分别从混合二甲苯或C 8 C 8芳族混合物中分离对二甲苯和乙苯。 吸附剂组合物通常包括分子筛材料和粘合剂的材料，其中吸附剂组合物具有至少约0.02cc / g的大孔体积和小于约0.20cc / g的中孔体积。

    Fluid hydrocracking catalyst precursor and method
    10.
    发明授权
    Fluid hydrocracking catalyst precursor and method 失效
    流体加氢裂化催化剂前体及方法

    公开(公告)号：US5954945A

    公开(公告)日：1999-09-21

    申请号：US827191

    申请日：1997-03-27

    申请人： Roger H. Cayton ,  Ronald B. Fisher ,  Jeffrey T. Miller ,  John A. Waynick

    发明人： Roger H. Cayton ,  Ronald B. Fisher ,  Jeffrey T. Miller ,  John A. Waynick

    IPC分类号： C10G47/26 ,  C10G47/02

    CPC分类号： C10G47/26

    摘要： A method for converting a hydrocarbonaceous feedstock to a lower boiling temperature product is described which comprises suspending metal sulfide particles and oxide particles in a reaction zone including hydrogen and the hydrocarbonaceous feedstock at hydrocracking conditions. The metal sulfide particles and the oxide particles are introduced into the reaction zone through particle precursor fluids which precipitate upon heating to form the particles. The metal sulfide particles contain sulfidable transition metals. The oxide particles contain oxidisable elements such as magnesium, aluminum, silicon, phosphorous, calcium, scandium, titanium, gallium, germanium, zirconium, cerium, and mixtures thereof and are not hydrogenation catalysts under the reactor conditions. The oxide particles resist being chemically reduced by reducing agents in the reaction zone. Surprisingly, the presence of the oxide particles is associated with a significant reduction of coke production in the reaction zone. A hydrogenation catalyst precursor comprising a hydrocarbonaceous feedstock, a sulfide particle precursor fluid, and an oxide particle precursor fluid is also described.

    摘要翻译： 描述了将烃原料转化为低沸点产物的方法，其包括在加氢裂化条件下将包含氢和烃原料的金属硫化物颗粒和氧化物颗粒悬浮在反应区中。 金属硫化物颗粒和氧化物颗粒通过在加热时沉淀形成颗粒的颗粒前体流体引入反应区。 金属硫化物颗粒含有可硫化的过渡金属。 氧化物颗粒含有可氧化元素如镁，铝，硅，磷，钙，钪，钛，镓，锗，锆，铈及其混合物，并且在反应器条件下不是氢化催化剂。 氧化物颗粒抵抗由反应区中的还原剂化学还原。 令人惊奇的是，氧化物颗粒的存在与反应区中焦炭产生的显着降低有关。 还描述了包含烃原料，硫化物颗粒前体流体和氧化物颗粒前体流体的氢化催化剂前体。