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    Process for hydroxyalkylating carboxylic acid-functionalized materials
    2.
    发明授权
    Process for hydroxyalkylating carboxylic acid-functionalized materials 失效
    羟基烷基化羧酸官能化材料的方法

    公开(公告)号：US07354977B1

    公开(公告)日：2008-04-08

    申请号：US09341287

    申请日：1998-01-16

    申请人： John G. Woods ,  Susanne D. Morrill ,  Anthony F. Jacobine

    发明人： John G. Woods ,  Susanne D. Morrill ,  Anthony F. Jacobine

    IPC分类号： C08F8/12

    CPC分类号： C08C19/36

    摘要： The present invention relates to a process for hydroxyalkylating terminal carboxylic acid groups. More specifically, this invention provides a process for preparing hydroxyl-functionalized materials, such as butadiene nitrile polymers, from carboxylic acid-functionalized materials, such as butadiene nitrile polymers, using a carbocyclic carbonate, such as ethylene carbonate, or a carbocyclic sulfite, such as ethylene sulfite.

    摘要翻译： 本发明涉及一种用于羟基烷基化末端羧酸基团的方法。 更具体地，本发明提供了使用碳酸亚碳酯如碳酸亚乙酯或碳环亚硫酸酯等羧酸官能化材料如丁二烯腈聚合物制备羟基官能化材料如丁二烯腈聚合物的方法，例如丁二烯腈聚合物 作为亚硫酸亚乙酯。

    Multi-functional alpha-alkoxyalkyl acrylate and methacrylate ester compositions and reworkable polymers formed therefrom
    4.
    发明授权
    Multi-functional alpha-alkoxyalkyl acrylate and methacrylate ester compositions and reworkable polymers formed therefrom 失效
    多官能α-烷氧基烷基丙烯酸酯和甲基丙烯酸酯组合物和由其形成的可再加工聚合物

    公开(公告)号：US07067601B2

    公开(公告)日：2006-06-27

    申请号：US10415904

    申请日：2001-11-15

    申请人： John G. Woods ,  Susanne D. Morrill

    发明人： John G. Woods ,  Susanne D. Morrill

    IPC分类号： C08F116/34

    CPC分类号： C08F20/28 ,  C08F265/06 ,  C08F290/061 ,  C08L2666/02 ,  C09D133/14 ,  C09J151/003

    摘要： Adhesive compositions are disclosed which include acrylates, their polymers, and free radical initiators. The compositions include a multi-functional alpha-alkoxyalkyl (meth)acrylate compound and a free radical initiator. The multi-functional alpha-alkoxyalkyl (meth)acrylate compound is the reaction product of: (a) a (meth)acrylic acid or a (meth)acrylate ester having a free carboxylic acid group; and (b) a compound including two or more 1-alkenyl ether groups and free of acetal and ketal groups, or a compound free of acetal and ketal groups and including one or more 1-alkenyl ether groups and a (meth)acrylate group. The compositions are easier and less expensive to prepare than conventional acrylate compositions and degrade when contacted with an acid medium or when heated. The compositions are useful in a wide range of applications and are compatible with conventional adhesive additives.

    摘要翻译： 公开了包括丙烯酸酯，它们的聚合物和自由基引发剂的粘合剂组合物。 组合物包括多官能α-烷氧基烷基（甲基）丙烯酸酯化合物和自由基引发剂。 多官能α-烷氧基烷基（甲基）丙烯酸酯化合物是：（a）（甲基）丙烯酸或具有游离羧酸基的（甲基）丙烯酸酯的反应产物; 和（b）包含两个或更多个1-链烯基醚基并且不含缩醛和缩酮基团的化合物或不含缩醛和缩酮基团的化合物并包括一个或多个1-烯基醚基团和（甲基）丙烯酸酯基团的化合物。 组合物比常规丙烯酸酯组合物更容易制备并且更便宜，并且当与酸性介质接触或加热时降解。 该组合物可用于广泛的应用，并且与常规粘合剂添加剂相容。

    Acetal and hemiacetal ester linked propylene carbonate functional (meth)acrylic esters and method of making same
    6.
    发明授权
    Acetal and hemiacetal ester linked propylene carbonate functional (meth)acrylic esters and method of making same 失效
    乙缩醛和半缩醛酯连接的丙烯碳酸酯官能（甲基）丙烯酸酯及其制备方法

    公开(公告)号：US06627762B1

    公开(公告)日：2003-09-30

    申请号：US10277988

    申请日：2002-10-23

    申请人： John G. Woods ,  Susanne D. Morrill

    发明人： John G. Woods ,  Susanne D. Morrill

    IPC分类号： C07D31736

    CPC分类号： C08F220/28 ,  C07D317/36 ,  C08F216/1416

    摘要： Compounds of the formula: wherein R1 is H or methyl, R2 is H or alkyl, R3 is C2-C4 alkylene, n is 0-4, n′ is 1-4, x is one or more, y is one or more, x+y=z, and A is a z-valent organic group linked to the group or groups on the left thereof through a carbon atom and is linked to the group or groups on the right thereof through an ether or ester oxygen atom, or, provided that x and y are both 1, a direct bond.

    摘要翻译： 下式的化合物：其中R 1是H或甲基，R 2是H或烷基，R 3是C 2 -C 4亚烷基，n是0-4，n'是1-4，x是1或 更多的是，y是一个或多个，x + y = z，A是通过碳原子与其左侧的基团连接的z价有机基团，并且通过碳原子连接到其右侧的基团 醚或酯氧原子，或者如果x和y均为1，则直接键合。

    UV-curable fuel cell sealants and fuel cells formed therefrom
    8.
    发明授权
    UV-curable fuel cell sealants and fuel cells formed therefrom 有权
    可UV固化的燃料电池密封剂和由其形成的燃料电池

    公开(公告)号：US08197989B2

    公开(公告)日：2012-06-12

    申请号：US12161237

    申请日：2007-01-16

    申请人： Anthony F. Jacobine ,  John G. Woods ,  Steven T. Nakos ,  Matthew P. Burdzy ,  Brian R. Einsla ,  Kevin J. Welch

    发明人： Anthony F. Jacobine ,  John G. Woods ,  Steven T. Nakos ,  Matthew P. Burdzy ,  Brian R. Einsla ,  Kevin J. Welch

    IPC分类号： H01M8/02 ,  B29C45/14

    CPC分类号： H01M8/0284 ,  H01M8/0258 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/0297 ,  H01M8/2404 ,  H01M8/241 ,  H01M8/249

    摘要： A fuel cell, having improved sealing against leakage, includes a fuel cell component having a cured sealant, wherein the cured sealant includes a telechelic-functional polyisobutylene, an organhydrogenosilane crosslinker, a platinum catalyst and a photoinitiator. The fuel cell component may be a cathode flow field plate, an anode flow field plate, a resin frame, a gas diffusion layer, an anode catalyst layer, a cathode catalyst layer, a membrane electrolyte, a membrane-electrode-assembly frame, and combinations thereof. A method for forming such a fuel cell includes the steps of providing a fuel cell component including a substrate; providing a mold having a cavity; positioning the mold so that the cavity is in fluid communication with the substrate; applying a curable liquid sealant composition into the cavity, wherein the curable sealant composition includes a telechelic-functional polyisobutylene, an organhydrogenosilane crosslinker, a platinum catalyst and a photoinitiator; and curing the composition with actinic radiation.

    摘要翻译： 具有改进的泄漏密封性的燃料电池包括具有固化的密封剂的燃料电池部件，其中固化的密封剂包括遥爪功能聚异丁烯，有机氢硅烷交联剂，铂催化剂和光引发剂。 燃料电池部件可以是阴极流场板，阳极流场板，树脂框架，气体扩散层，阳极催化剂层，阴极催化剂层，膜电解质，膜 - 电极 - 组装框架，以及 其组合。 一种形成这种燃料电池的方法包括以下步骤：提供包括基板的燃料电池部件; 提供具有空腔的模具; 定位模具使空腔与衬底流体连通; 将可固化液体密封剂组合物施加到空腔中，其中可固化密封剂组合物包括遥爪功能性聚异丁烯，有机氢硅烷交联剂，铂催化剂和光引发剂; 并用光化辐射固化组合物。

    Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same
    9.
    发明授权
    Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same 有权
    感光性化合物，包含其的光聚合性组合物及其制备和使用方法

    公开(公告)号：US07705064B2

    公开(公告)日：2010-04-27

    申请号：US11781317

    申请日：2007-07-23

    申请人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    发明人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    IPC分类号： C08F2/50 ,  C08F222/10 ,  C07C69/587 ,  C08G16/00

    CPC分类号： C08F2/50 ,  C07C67/347 ,  C07C255/22 ,  C08G18/10 ,  C08G18/672 ,  C07C69/716 ,  C08G18/3206 ,  C08G18/3838 ,  C08G18/42

    摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.

    摘要翻译： 本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基， 和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

    Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same
    10.
    发明申请
    Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same 有权
    光敏化合物，包括其的可光聚合组合物及其制备和使用方法

    公开(公告)号：US20090030106A1

    公开(公告)日：2009-01-29

    申请号：US11781317

    申请日：2007-07-23

    申请人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    发明人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    IPC分类号： C08F2/48 ,  C07C45/00

    CPC分类号： C08F2/50 ,  C07C67/347 ,  C07C255/22 ,  C08G18/10 ,  C08G18/672 ,  C07C69/716 ,  C08G18/3206 ,  C08G18/3838 ,  C08G18/42

    摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.

    摘要翻译： 本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基， 和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。