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    Gem-diesters and epoxidized derivatives thereof
    2.
    发明授权
    Gem-diesters and epoxidized derivatives thereof 失效
    Gem-二酯及其环氧化衍生物

    公开(公告)号：US06740193B2

    公开(公告)日：2004-05-25

    申请号：US10032128

    申请日：2001-12-21

    申请人： John G. Woods ,  Jianzhao Wang ,  Jean M. J. Fréchet

    发明人： John G. Woods ,  Jianzhao Wang ,  Jean M. J. Fréchet

    IPC分类号： C09J16300

    CPC分类号： C07D303/12 ,  Y10T156/1111 ,  Y10T428/31511

    摘要： In accordance with the present invention, there are provided gem-diesters and epoxidized derivatives thereof. When cured, thermosets comprising invention gem-diesters and epoxidized derivatives thereof have thermally and/or chemically labile gem-diester groups interspersed throughout the crosslinked network. Thus, thermosets based on invention gem-diesters and epoxidized derivatives thereof can be easily reworked thermally or chemically by treatment with dilute acidic or basic solutions. Further provided by the present invention are adhesive compositions comprising invention gem-diesters and epoxidized derivatives thereof.

    摘要翻译： 根据本发明，提供了偕二酯及其环氧化衍生物。 当固化时，包含本发明偕二酯和环氧化衍生物的热固性材料具有散布在整个交联网络中的热和/或化学不稳定的偕二酯基团。 因此，基于本发明的偕二酯和其环氧化衍生物的热固性材料可以通过用稀酸或碱性溶液处理而易于热或化学地再加工。 本发明进一步提供的是含有本发明的偕二酯及其环氧化衍生物的粘合剂组合物。

    Process for producing polyester with metal phosphonic acid complex catalysts
    6.
    发明申请
    Process for producing polyester with metal phosphonic acid complex catalysts 审中-公开
    用金属膦酸配合物催化剂生产聚酯的方法

    公开(公告)号：US20080108779A1

    公开(公告)日：2008-05-08

    申请号：US11901478

    申请日：2007-09-17

    申请人： Stephen Andrews ,  Jianzhao Wang ,  Thomas Thompson ,  Paragkumar Thanki ,  Deepak Rane ,  Suhas Sahasrabudhe ,  Preetam Ghogale ,  Paul Odorisio ,  Si Wu

    发明人： Stephen Andrews ,  Jianzhao Wang ,  Thomas Thompson ,  Paragkumar Thanki ,  Deepak Rane ,  Suhas Sahasrabudhe ,  Preetam Ghogale ,  Paul Odorisio ,  Si Wu

    IPC分类号： C08G63/02

    CPC分类号： C08G63/84 ,  C08G63/183 ,  C08G63/189

    摘要： Disclosed is a method for the preparation of a polyester, which method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester, where a metal phosphonic acid complex compound of the formula is employed in the first step, in the second step or in both the first and second steps as a reaction catalyst; and wherein n is 0, 1, 2, 3, 4, 5 or 6; p is an integer from 1 to 30; M is a metal selected from the group consisting of Li, Na, K, Cs, Be, Ca, Mg, Sr, Ba, Al, Sb, Cd, Mn, Fe, Co, Ni, Cu and Zn; v is the valency of the metal M and is 1, 2 or 3; q is an integer from 1 to 20 where q=2p/v; and R1 is hydrogen, straight or branched chain alkyl of 1 to 36 carbon atoms, straight or branched chain alkenyl of 1 to 36 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or aryl of 6 to 10 carbon atoms; or is said alkyl, alkenyl, cycloalkyl or aryl substituted by one to four hydroxyl, halogen, straight or branched chain alkoxy of 1 to 8 carbon atoms, straight or branched chain alkyl of 1 to 8 carbon atoms or amino groups. The metal complex catalyst compound is in particular

    摘要翻译： 公开了一种制备聚酯的方法，该方法包括在第一步中，使二羧酸或C 1 -C 4 - 二羧酸二酯与二醇反应 合适的温度和压力以进行酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物在合适的温度和压力下进行缩聚以制备高分子量聚酯，其中式 在第一步，第二步或第一步和第二步都用作反应催化剂; 并且其中n为0,1,2,3,4,5或6; p是1至30的整数; M是选自Li，Na，K，Cs，Be，Ca，Mg，Sr，Ba，Al，Sb，Cd，Mn，Fe，Co，Ni，Cu和Zn中的金属; v是金属M的化合价，为1,2或3; q是1至20的整数，其中q = 2p / v; R 1是氢，1至36个碳原子的直链或支链烷基，1至36个碳原子的直链或支链烯基，5至8个碳原子的环烷基或6至10个芳基 碳原子 或被1至4个羟基，卤素，1至8个碳原子的直链或支链烷氧基，1至8个碳原子的直链或支链烷基或氨基取代的烷基，链烯基，环烷基或芳基取代。 特别是金属络合物催化剂化合物

    Solid state polymerization process for polyester with phosphinic acid compounds
    8.
    发明授权
    Solid state polymerization process for polyester with phosphinic acid compounds 失效
    具有次膦酸化合物的聚酯的固态聚合方法

    公开(公告)号：US08258253B2

    公开(公告)日：2012-09-04

    申请号：US13214751

    申请日：2011-08-22

    申请人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    发明人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    IPC分类号： C08G63/02 ,  C08G64/00

    CPC分类号： C08G63/80 ,  C08G63/85 ,  C08G63/87

    摘要： Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.

    摘要翻译： 公开了一种提高金属催化聚酯的固态聚合（SSP）速率的方法。 该方法包括在第一步骤中，在合适的温度和压力下使二羧酸或C 1 -C 4二羧酸二酯与二醇反应以实现酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物与 合适的温度和压力以制备高分子量聚酯，并且在第三步骤中，在合适的温度和压力的SSP条件下进一步提高聚酯的分子量和粘度，其中在第一步中加入金属催化剂或在 作为反应催化剂的第二步骤，其中在第一步骤，第二步骤或第三步骤之前加入某些次膦酸化合物。 聚酯产品在熔融加工步骤中表现出低醛形成以及优异的颜色。

    Solid State Polymerization Process for Polyester with Phosphinic Acid Compounds
    9.
    发明申请
    Solid State Polymerization Process for Polyester with Phosphinic Acid Compounds 失效
    聚酯与膦酸化合物的固态聚合方法

    公开(公告)号：US20110306710A1

    公开(公告)日：2011-12-15

    申请号：US13214751

    申请日：2011-08-22

    申请人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    发明人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    IPC分类号： C08K5/5313 ,  C08G63/86 ,  C08G63/85 ,  C08L67/02

    CPC分类号： C08G63/80 ,  C08G63/85 ,  C08G63/87

    摘要： Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.

    摘要翻译： 公开了一种提高金属催化聚酯的固态聚合（SSP）速率的方法。 该方法包括在第一步骤中，在合适的温度和压力下使二羧酸或C 1 -C 4二羧酸二酯与二醇反应以进行酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物与 合适的温度和压力以制备高分子量聚酯，并且在第三步骤中，在合适的温度和压力的SSP条件下进一步提高聚酯的分子量和粘度，其中在第一步中加入金属催化剂或在 作为反应催化剂的第二步骤，其中在第一步骤，第二步骤或第三步骤之前加入某些次膦酸化合物。 聚酯产品在熔融加工步骤中表现出低醛形成以及优异的颜色。

    Solid state polymerization process for polyester with phosphinic acid compounds
    10.
    发明授权
    Solid state polymerization process for polyester with phosphinic acid compounds 失效
    具有次膦酸化合物的聚酯的固态聚合方法

    公开(公告)号：US08030435B2

    公开(公告)日：2011-10-04

    申请号：US12384029

    申请日：2009-03-31

    申请人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    发明人： Paul Odorisio ,  Stephen M. Andrews ,  Thomas F. Thompson ,  Si Wu ,  Paragkumar Thanki ,  Deepak M. Rane ,  Delina Joseph ,  Jianzhao Wang

    IPC分类号： C08G63/68 ,  C08G79/02

    CPC分类号： C08G63/80 ,  C08G63/85 ,  C08G63/87

    摘要： Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.

    摘要翻译： 公开了一种提高金属催化聚酯的固态聚合（SSP）速率的方法。 该方法包括在第一步骤中，在合适的温度和压力下使二羧酸或C 1 -C 4二羧酸二酯与二醇反应以进行酯化或酯交换以制备预缩合物，并且在第二步中，使预缩合物与 合适的温度和压力以制备高分子量聚酯，并且在第三步骤中，在合适的温度和压力的SSP条件下进一步提高聚酯的分子量和粘度，其中在第一步中加入金属催化剂或在 作为反应催化剂的第二步骤，其中在第一步骤，第二步骤或第三步骤之前加入某些次膦酸化合物。 聚酯产品在熔融加工步骤中表现出低醛形成以及优异的颜色。