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公开(公告)号：US07135241B2
公开(公告)日：2006-11-14
申请号：US10155390
申请日：2002-05-24
CPC分类号： C09K11/06 , C08G61/02 , Y10S428/917
摘要： Generally, and in one form, the present invention is a composition of light-emitting block copolymer. In another form, the present invention is a process producing a light-emitting block copolymers that intends polymerizing a first di(halo-methyl) aromatic monomer compound in the presence of an anionic initiator and a base to form a polymer and contacting a second di(halo-methyl) aromatic monomer compound with the polymer to form a homopolymer or block copolymer wherein the block copolymer is a diblock, triblock, or star polymer. In yet another form, the present invention is an electroluminescent device comprising a light-emitting block copolymer, wherein the electroluminescent device is to be used in the manufacturing of optical and electrical devices.
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公开(公告)号：US5527640A
公开(公告)日：1996-06-18
申请号：US306214
申请日：1994-09-14
IPC分类号： H01G9/02 , H01G9/022 , H01G9/04 , H01G9/042 , H01M4/60 , H01M10/05 , H01M10/0568 , H01M10/40
摘要： A new class of electrochemical capacitors provides in its charged state a positive electrode including an active material of a p-doped material and a negative electrode including an active material of an n-doped conducting polymer, where the p-doped and n-doped materials are separated by an electrolyte. In a preferred embodiment, the positive and negative electrode active materials are selected from conducting polymers consisting of polythiophene, polymers having an aryl group attached in the 3-position, polymers having aryl and alkyl groups independently attached in the 3- and 4-positions, and polymers synthesized from bridged dimers having polythiophene as the backbone. A preferred electrolyte is a tetraalykyl ammonium salt, such as tetramethylammonium trifluoromethane sulphonate (TMATFMS), that provides small ions that are mobile through the active material, is soluble in acetonitrile, and can be used in a variety of capacitor configurations.
摘要翻译： 一类新的电化学电容器在其带电状态下提供包括p掺杂材料的活性材料的正电极和包含n-掺杂导电聚合物的活性材料的负电极，其中p掺杂和n掺杂材料 被电解质分离。 在优选的实施方案中，正极活性材料和负极活性材料选自由聚噻吩组成的导电聚合物，具有连接在3-位上的芳基的聚合物，具有芳基的聚合物和独立地连接在3-和4-位的烷基， 由聚噻吩作为主链的桥连二聚体合成的聚合物。 优选的电解质是四烷基铵盐，例如四甲基三氟甲烷磺酸铵（TMATFMS），其提供可通过活性材料移动的小离子，可溶于乙腈，并且可用于各种电容器配置。
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公开(公告)号：US5510438A
公开(公告)日：1996-04-23
申请号：US211013
申请日：1994-03-11
CPC分类号： H01B1/127 , C07D495/04 , C08G61/126 , C09K9/02 , H01L51/0036 , H01L51/0074
摘要： The present invention involves monomeric compounds having the structure: ##STR1## Substituents W and Z are independently --CN, --NO.sub.2, -aryl, -aryl-V, --COX, SO.sub.2 R, --H, or -alkyl. Substituent X is --OR, or --NR,R where R and R.sup.1 are independently -alkyl or --H. Substituent V is -halide, --NO.sub.2, --CN, --SO.sub.2 R, or --COX. At least one of W and Z is --NO.sub.2, --SO.sub.2 R, --CN, --COX or -aryl-V. In one preferred embodiment substituents W and Z are both --CN. In another preferred embodiment, substituent X is --NO.sub.2 or --CN and substituent Z is --C.sub.6 H.sub.4 NO.sub.2. These monomers are polymerized to form low bandgap polymers.
摘要翻译： PCT No.PCT / US92 / 07604 Sec。 371日期：1994年3月11日 102（e）1994年3月11日PCT PCT 1992年9月9日PCT公布。 第WO93 / 05077号公报 本发明涉及具有以下结构的单体化合物：取代基W和Z独立地为-CN，-NO 2， - 芳基， - 芳基-V，-COX，SO 2 R，-H或 - 烷基。 取代基X是-OR或-NR，R，其中R和R 1独立地是烷基或-H。 取代基V是卤素，-NO 2，-CN，-SO 2 R或-COX。 W和Z中的至少一个是-NO 2，-SO 2 R，-CN，-COX或 - 芳基-V。 在一个优选实施方案中，取代基W和Z均为-CN。 在另一个优选的实施方案中，取代基X是-NO 2或-CN，取代基Z是-C 6 H 4 NO 2。 聚合这些单体以形成低带隙聚合物。
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公开(公告)号：US07794833B2
公开(公告)日：2010-09-14
申请号：US10601102
申请日：2003-06-20
IPC分类号： D02G3/02
CPC分类号： D01D5/003 , B82Y30/00 , C04B35/62231 , C04B35/6224 , C04B35/62259 , C04B35/624 , C04B35/632 , C04B2235/3208 , C04B2235/3222 , C04B2235/3239 , C04B2235/3251 , C04B2235/3293 , C04B2235/441 , C04B2235/444 , C04B2235/449 , C04B2235/5264 , D01F9/10 , Y10T428/2913 , Y10T428/2962
摘要： Electrospun fibers comprising mesoporous molecular sieve materials are described. In an aspect of the invention, fibers are electrospun from a conducting solution to which a high voltage electric current is applied. The apparatus includes in one aspect one or more conducting solution introduction devices for providing a quantity of conducting solution, said conducting solution introduction devices being electrically charged thereby establishing an electric field between said conducting solution introduction devices and a target, and means for controlling the flow characteristics of conducting solution from said one or more conducting solution introduction devices.
摘要翻译： 描述了包含介孔分子筛材料的电纺纤维。 在本发明的一个方面，纤维是从施加高压电流的导电溶液中电纺丝的。 该装置在一个方面包括用于提供一定数量的导电溶液的一个或多个导电溶液引入装置，所述导电溶液引入装置被充电，从而在所述导电溶液引入装置和靶之间建立电场，以及用于控制流动的装置 来自所述一个或多个导电溶液引入装置的导电溶液的特性。
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公开(公告)号：US06501587B1
公开(公告)日：2002-12-31
申请号：US09671549
申请日：2000-09-27
申请人： John P. Ferraris , Thuc H. Dam , David Meeker
发明人： John P. Ferraris , Thuc H. Dam , David Meeker
IPC分类号： G02F1153
摘要： The present invention comprises an apparatus for and method of creating electrically modifiable images using a computer printer. In one embodiment, one or more ink reservoirs of a printer cartridge are filled with an electrochromic ink. The printer thus prepared can be used to print electrochromic patterns on a surface using standard ink application methods. In certain embodiments, more than one ink reservoir is filled with electrochromic ink. In these embodiments, separate reservoirs are filled with separate ink formulations so that the characteristics of the electrochromic pattern can be varied.
摘要翻译： 本发明包括一种使用计算机打印机产生电可修改图像的装置和方法。 在一个实施例中，打印机墨盒的一个或多个墨水储存器填充有电致变色墨水。 如此制备的打印机可用于使用标准油墨施加方法在表面上印刷电致变色图案。 在某些实施例中，多个墨水储存器被电致变色墨水填充。 在这些实施例中，单独的储存器用独立的油墨配方填充，使得可以改变电致变色图案的特性。
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6.发明授权Methods for the synthesis and polymerization of &agr;,&agr;'-dihalo-p-xylenes 失效α，α'-二卤代对二甲苯的合成和聚合方法公开(公告)号：US06426399B1
公开(公告)日：2002-07-30
申请号：US09502953
申请日：2000-02-11
申请人： John P. Ferraris , Charles J. Neef
发明人： John P. Ferraris , Charles J. Neef
IPC分类号： C08F600
CPC分类号： C08G61/025 , C08G61/02 , C08G2261/3424
摘要： The present invention describes an improved method for the polymerization of &agr;,&agr;-dihalo-p-xylene's such as the &agr;,&agr;′-dihalo-2-methoxy-5-(2-ethylhexyloxy)-xylene's. The procedure for synthesis is based on the specific order of addition of reagents and the use of an anionic initiator that allows control of the molecular weight of the polymer. The molecular weight control allows processability of the polymer which is important for its utility in applications including in light-emitting-diodes, field effect transistors and photovoltaic devices.
摘要翻译： 本发明描述了α，α-二卤代对二甲苯如α，α'-二卤代-2-甲氧基-5-（2-乙基己氧基） - 二甲苯聚合的改进方法。 合成方法基于试剂的特定加入顺序以及允许控制聚合物分子量的阴离子引发剂的使用。 分子量控制允许聚合物的加工性，其对于其在包括发光二极管，场效应晶体管和光伏器件中的应用中的应用是重要的。
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7.发明授权公开(公告)号：US07938996B2
公开(公告)日：2011-05-10
申请号：US11576432
申请日：2005-09-30
IPC分类号： D01F9/12
CPC分类号： H01G9/058 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/174 , C01B2202/02 , C01B2202/26 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/13 , C01P2004/64 , C01P2006/40 , C09C1/44 , C09C1/48 , C09C1/56 , D01D5/06 , D01F9/12 , H01G11/36 , Y02E60/13 , Y10S977/842
摘要： Process, apparatus, compositions and application modes are provided that relate to nanofiber spinning without the use of superacids in the spinning solution. The methods employ either acids or bases for a flocculation solution. The advances disclosed therein enable the use of nanofibers, including carbon nanotubes, for a variety of applications including, but not limited to, electromechanical actuators, supercapacitors, electronic textiles, and in devices for electrical energy harvesting.
摘要翻译： 提供了涉及在纺丝溶液中不使用超强酸的纳米纤维纺丝的方法，装置，组合物和应用模式。 该方法使用酸或碱作为絮凝溶液。 其中公开的进步使得能够使用纳米纤维，包括碳纳米管，用于各种应用，包括但不限于机电致动器，超级电容器，电子纺织品以及用于电能收集的装置。
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8.发明申请Carbon nanofiber with skin-core structure, method of producing the same, and products comprising the same 审中-公开具有皮芯结构的碳纳米纤维，其制造方法和包含该碳纳米纤维的产品公开(公告)号：US20100167177A1
公开(公告)日：2010-07-01
申请号：US12385439
申请日：2009-04-08
摘要： This invention relates to carbon nanofiber having a skin-core structure containing pitch and polyacrylonitrile, to a method of producing the carbon nanofiber, and to a product including the carbon nanofiber. The carbon nanofiber includes polyacrylonitrile and pitch having different properties respectively constituting a skin layer and/or a core layer, with a diameter of 1 μm or less, and thus functions of the carbon nanofiber vary depending on change in composition thereof.
摘要翻译： 本发明涉及具有含沥青和聚丙烯腈的皮芯结构的碳纳米纤维，碳纳米纤维的制造方法以及包含碳纳米纤维的产品。 碳纳米纤维包括具有分别构成直径为1μm以下的表皮层和/或芯层的不同性质的聚丙烯腈和沥青，因此碳纳米纤维的功能根据其组成的变化而变化。
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公开(公告)号：US06598966B2
公开(公告)日：2003-07-29
申请号：US10120854
申请日：2002-04-11
申请人： John P. Ferraris , Thuc H. Dam , David Meeker
发明人： John P. Ferraris , Thuc H. Dam , David Meeker
IPC分类号： B41J201
摘要： The present invention includes an apparatus for and method of creating electrically modifiable images using a computer printer. In one embodiment, one or more ink reservoirs of a printer cartridge are filled with an electrochromic ink. The printer thus prepared can be used to print electrochromic patterns on a surface using standard ink application methods. In certain embodiments, more than one ink reservoir is filled with electrochromic ink. In these embodiments, separate reservoirs are filled with separate ink formulations so that the characteristics of the electrochromic pattern can be varied.
摘要翻译： 本发明包括一种使用计算机打印机产生电可修改图像的装置和方法。 在一个实施例中，打印机墨盒的一个或多个墨水储存器填充有电致变色墨水。 如此制备的打印机可用于使用标准油墨施加方法在表面上印刷电致变色图案。 在某些实施例中，多个墨水储存器被电致变色墨水填充。 在这些实施例中，单独的储存器用独立的油墨配方填充，使得可以改变电致变色图案的特性。
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10.发明申请COMPOSITE CARBON FIBER ELECTRODES INCORPORATING POROUS HIGH SURFACE AREA CARBON 审中-公开配合多孔高表面积碳的复合碳纤维电极公开(公告)号：US20120189877A1
公开(公告)日：2012-07-26
申请号：US13357431
申请日：2012-01-24
申请人： John P. Ferraris , Qiang Wu , Marilou E. Dela Cruz
发明人： John P. Ferraris , Qiang Wu , Marilou E. Dela Cruz
CPC分类号： B29C67/20 , B82Y30/00 , B82Y40/00 , H01G11/36 , H01G11/40 , H01M4/133 , H01M4/364 , H01M4/583 , Y02E60/13
摘要： The claimed invention uses activated carbon fibers that incorporate porous carbon with a suitable pore size to maximize capacitance. The porous carbon material is prepared using a template, followed by incorporation into a matrix polymer and electrospinning of the mixture. Subsequent thermal treatments retain the fiber form, and a composite carbon fiber incorporating templated porous carbon is attained. The resulting electrode is binder free and 100% electrochemically active. Energy densities up to 41 Wh/kg in energy density 1.5 kW/kg in power density (electrode weight only) have been achieved.
摘要翻译： 所要求保护的发明使用活性碳纤维，其结合具有合适孔径的多孔碳以使电容最大化。 使用模板制备多孔碳材料，然后将其并入基质聚合物中并静电纺丝混合物。 随后的热处理保持纤维形式，并且获得并入模板多孔碳的复合碳纤维。 所得电极无粘合剂和100％电化学活性。 能量密度达到41 Wh / kg，功率密度为1.5 kW / kg（仅电极重量）。
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