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1.发明授权Acid or anhydride grafted chlorinated polyolefin reacted with monoalcohol and polyepoxide 失效酸或酸酐接枝的氯化聚烯烃与一元醇和聚环氧化物反应
公开(公告)号：US4997882A
公开(公告)日：1991-03-05
申请号：US376441
申请日：1989-07-07
CPC分类号： C08J7/047 , C08F8/14 , C08J2323/02 , C08J2451/00
摘要： Disclosed is an ungelled, modified chlorinated polyolefin resin suitable for providing a highly adherent, solvent resistant film on a thermoplastic polyolefin substrate. The modified chlorinated polyolefin resin is prepared by grafting an unsaturated polycarboxylic acid and/or an unsaturated acid anhydride onto a chlorinated polyolefin resin to form an acid- and/or anhydride-modified chlorinated polyolefin resin. The resulting acid- and/or anhydride-modified chlorinated polyolefin resin is reacted with an organic monohydric alcohol to form an esterified product containing acid functionality. The resulting esterified product is reacted with a polyepoxide to form the ungelled modified chlorinated polyolefin resin.Also disclosed is a method of preparing an ungelled modified chlorinated polyolefin resin of the invention, a coating composition containing a resin of the invention, and a method of forming a hardened film from the coating composition on a thermoplastic polyolefin substrate.
摘要翻译： 公开了一种未凝胶化的改性氯化聚烯烃树脂，其适于在热塑性聚烯烃基材上提供高粘附性，耐溶剂性的膜。 通过将不饱和多羧酸和/或不饱和酸酐接枝到氯化聚烯烃树脂上以形成酸和/或酸酐改性的氯化聚烯烃树脂来制备改性氯化聚烯烃树脂。 将所得酸和/或酸酐改性的氯化聚烯烃树脂与有机一元醇反应形成含有酸官能团的酯化产物。 所得酯化产物与聚环氧化物反应形成未凝胶化的改性氯化聚烯烃树脂。 还公开了制备本发明的未凝胶化改性氯化聚烯烃树脂的方法，含有本发明树脂的涂料组合物和在热塑性聚烯烃基材上由涂料组合物形成硬化膜的方法。
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2.发明授权
公开(公告)号：US5084506A
公开(公告)日：1992-01-28
申请号：US128315
申请日：1987-12-03
IPC分类号： C08G12/40 , C08J3/00 , C08J3/09 , C08L33/06 , C08L61/20 , C08L67/00 , C08L71/00 , C08L75/00 , C08L75/06 , C08L101/00
CPC分类号： C08J3/09 , C08G12/40 , C08J3/005 , C08L61/20 , C08J2361/20 , C08L33/06 , C08L67/00 , C08L75/06 , Y10S524/923
摘要： A stable, nonaqueous microparticle dispersion of the polymeric reaction product of reactants containing an aminoplast resin and a hydroxyl containing material is characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns, further characterized in that at a total solids content of 60 percent the Brookfield viscosity is less that 1000 centipoise measured at 50 RPM using a number 3 spindle at 25.degree. C., the polymeric reaction product being prepared from reactants which are substantially free of acrylic polymer in a nonaqueous medium which is inert to the reactants.Stable nonaqueous microparticle dispersions characterized as above can also be prepared by the self condensation of an aminoplast resin.
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3.发明授权
公开(公告)号：US4833177A
公开(公告)日：1989-05-23
申请号：US128316
申请日：1987-12-03
CPC分类号： C08G18/0871 , C08G12/40
摘要： A method for preparing polymer microparticles which are stably dispersed in a nonaqueous medium involves:(a) mixing into a nonaqueous medium a polymerizable component at least 20 percent of which is insoluble in the nonaqueous medium, said polymerizable component comprising at least one polymerizable species;(b) subjecting the mixture of (a) to stress sufficient to particulate the mixture;(c) polymerizing the polymerizable component within each particle under conditions sufficient to produce polymer microparticles stably dispersed in the nonaqueous medium, said polymer microparticles being insoluble in the nonaqueous medium and the nonaqueous medium being substantially free of dissolved polymer, said polymer microparticles further characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns.
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公开(公告)号：US4783502A
公开(公告)日：1988-11-08
申请号：US128353
申请日：1987-12-03
CPC分类号： C08G18/0871
摘要： A stable, nonaqueous polyurethane microparticle dispersion is characterized in that less than 20 percent of the polymer microparticles have a mean diameter greater than 5 microns, further characterized in that at a total solids content of 60 percent the Brookfield viscosity is less than 1000 centipoise measured at 50 RPM using a number 3 spindle at 25.degree. C., the polyurethane being prepared from reactants which are substantially free of acrylic polymer and the polyurethane being further characterized in that it is substantially free of unreacted polyisocyanate monomer.
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5.发明授权Non-yellowing coating composition based on a hydroxy component and an anhydride component and utilization in a process of coating 失效基于羟基组分和酸酐组分的非黄变涂料组合物和在涂布过程中的利用
公开(公告)号：US4798745A
公开(公告)日：1989-01-17
申请号：US88327
申请日：1987-08-24
IPC分类号： C08G63/12 , B05D7/00 , C08L35/00 , C09D133/06 , C09D135/06 , C09D157/04 , C09D157/10 , C09D167/00 , C09D201/08 , B05D1/36 , C08L33/14
CPC分类号： B05D7/53 , C09D133/066 , C09D135/06 , C09D157/04 , C08L35/00
摘要： Disclosed is a non-yellowing coating composition comprising: a hydroxy component having at least two free hydroxyl groups per molecule, and an anhydride component having at least two carboxylic acid anhydride groups per molecule. The anhydride component is derived from a mixture of monomers comprising greater than or equal to 11 percent by weight of an ethylenically unsaturated carboxylic acid anhydride, the balance of the mixture comprised of at least one vinyl comonomer. The molar ratio of the vinyl comonomer to the carboxylic acid anhydride in the mixture should be at least 1.0:1.0 and the ratio should be sufficient to provide a color standard number of less than 150. Typically, the coating composition is in the form of a two-package composition.Also disclosed is a method of coating comprising: (I) coating a substrate with one or more applications of a pigmented basecoating composition to form a basecoat, and (II) coating the basecoat with one or more applications of a transparent topcoating composition to form a transparent topcoat, in which the basecoating composition and/or the topcoating composition comprises the aforesaid non-yellowing coating composition.
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公开(公告)号：US20080255307A1
公开(公告)日：2008-10-16
申请号：US12132928
申请日：2008-06-04
申请人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
发明人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
IPC分类号： C08G63/00
CPC分类号： C08F220/10
摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.
摘要翻译： 本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。 共聚物的多分散指数小于2.5。 本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。 该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。
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7.发明授权公开(公告)号：US07125931B2
公开(公告)日：2006-10-24
申请号：US10887733
申请日：2004-07-09
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
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公开(公告)号：US06992137B2
公开(公告)日：2006-01-31
申请号：US10697413
申请日：2003-10-30
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： C09D201/02 , C08F8/00 , C08F10/00 , C08F20/00
摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.
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9.发明授权Compositions containing copolymers of post-polymerization reacted (meth) acrylate monomers 失效含有后聚合反应的（甲基）丙烯酸酯单体的共聚物的组合物公开(公告)号：US06900279B2
公开(公告)日：2005-05-31
申请号：US10348367
申请日：2003-01-21
申请人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
发明人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
IPC分类号： B05D7/24 , B05D1/00 , B05D3/02 , B05D3/06 , B05D7/00 , B32B27/30 , C08F8/00 , C08F210/00 , C08F210/10 , C08F210/14 , C08F220/10 , C08F290/04 , C08G18/62 , C08G18/79 , C08G18/80 , C08K5/092 , C08L23/20 , C08L23/22 , C08L33/06 , C08L33/14 , C08L63/00 , C08L101/00 , C09D7/12 , C09D109/00 , C09D109/02 , C09D123/22 , C09D133/00 , C09D133/02 , C09D133/06 , C09D133/08 , C09D133/14 , C09D133/24 , C09D157/04 , C09D163/00 , C09D167/00 , C09D175/04 , C09D201/00 , C08F120/54 , C08F120/10
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A composition that includes a non-gelled copolymer that includes one or more residues of a first polymerizable ethylenically unsaturated monomer containing a pendant amide, ester or carboxylic acid group. The nearest neighboring monomer residues of the majority of the first monomer residues along the copolymer molecule do not contain pendant carbonyl functional groups. The amide, ester or carboxylic acid group of the residues of the first monomer are the post polymerization transesterification, transamidification or hydrolysis reaction product of a C1-C4 alkyl ester group in the unreacted first monomer with a compound selected from amine functional compounds and hydroxy functional compounds. The reacted copolymer is substantially free of cyclical structures resulting from the transesterification, transamidification or hydrolysis reaction. The compositions may be thermosetting compositions useful in multi-layer composite coatings.
摘要翻译： 包含非凝胶共聚物的组合物，其包含含有侧酰胺，酯或羧酸基团的第一可聚合烯属不饱和单体的一个或多个残基。 沿着共聚物分子的大部分第一单体残基的最邻近的单体残基不含有羰基官能团。 第一单体的残基的酰胺，酯或羧酸基是C 1 -C 4烷基酯基的后聚合酯交换，转酰胺化或水解反应产物 在未反应的第一单体中与选自胺官能化合物和羟基官能化合物的化合物反应。 反应的共聚物基本上不含由酯交换，酰胺化或水解反应产生的循环结构。 组合物可以是可用于多层复合涂层的热固性组合物。
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公开(公告)号：US06677422B2
公开(公告)日：2004-01-13
申请号：US10077559
申请日：2002-02-15
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F1000
CPC分类号： C08F220/12
摘要： A method of making a copolymer composition containing a copolymer, which includes the steps of (a) providing a donor monomer composition that includes an isobutylene type monomer; (b) mixing the donor monomer composition with an ethylenically unsaturated monomer composition that includes one or more ethylenically unsaturated acceptor monomers, and is substantially free of maleate type monomers and fumarate type monomers, and (c) polymerizing the mixture resulting from step (b) in the presence of a free radical polymerization initiator. The polymerization is carried out in the substantial absence of Lewis acids and/or transition metals. The isobutylene type monomer is present at a molar excess of at least 10 mol % based on the molar concentration of monomers in the ethylenically unsaturated monomer composition. The ethylenically unsaturated acceptor monomers are present in an amount of at least 15 mol % of the total monomer composition.
摘要翻译： 一种制备含有共聚物的共聚物组合物的方法，其包括以下步骤：（a）提供包含异丁烯型单体的供体单体组合物; （b）将供体单体组合物与包含一种或多种烯键式不饱和受体单体的烯属不饱和单体组合物混合，并且基本上不含马来酸盐型单体和富马酸盐型单体，和（c）将由步骤（b）得到的混合物聚合， 在自由基聚合引发剂存在下进行。 基本上不存在路易斯酸和/或过渡金属进行聚合。 基于烯属不饱和单体组合物中单体的摩尔浓度，异丁烯型单体的摩尔过量为至少10摩尔％。 烯属不饱和受体单体的存在量为总单体组合物的至少15摩尔％。
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