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    Monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers
    3.
    发明授权
    Monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers 有权
    包含硫烷基硅烷官能化的弹性体聚合物的单亚乙烯基芳族聚合物

    公开(公告)号：US08048960B2

    公开(公告)日：2011-11-01

    申请号：US12596162

    申请日：2008-03-27

    申请人： Amaia Montoya-Goni ,  Jose M. Rego ,  Evemarie Hamann ,  Sven K. H. Thiele

    发明人： Amaia Montoya-Goni ,  Jose M. Rego ,  Evemarie Hamann ,  Sven K. H. Thiele

    IPC分类号： C08F8/00 ,  C08L9/00 ,  C08L25/02 ,  C08K5/00

    CPC分类号： C08C19/44 ,  C08F8/42 ,  C08F279/02 ,  C08F279/04 ,  C08K5/548 ,  C08L15/00 ,  C08L19/006 ,  C08L25/06 ,  C08L51/003 ,  C08L51/006 ,  C08L51/04 ,  C08L53/025 ,  C08L55/02 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04

    摘要： The present invention is a rubber modified monovinylidene aromatic polymer composition where the rubber is a sulfanylsilane chain end modified elastomeric polymer. In the present invention the functionalized rubber provides sufficient grafting levels in standard graft polymerization process technologies to prepare desired rubber particle size distributions and morphologies. Across a range of rubber modified monovinylidene aromatic polymers, it has been found that the use of the modified elastomeric polymers according to the present invention can improve the combinations of resin properties, particularly clarity, surface and physical properties, including both rubber modified monovinylidene aromatic homopolymers (e.g., high impact polystyrene and copolymers (e.g., ABS). The functionalized rubbers have sulfanyl functional groups that provide an optimized reactive grafting site. This ensures that under graft polymerization conditions a monovinylidene aromatic polymer block is formed grafted to the butadiene polymer block. This is particularly desirable to enable the use of polybutadiene homopolymer rubbers which are more cost effectively used in rubber-modified monovinylidene aromatic polymers.

    摘要翻译： 本发明是一种橡胶改性单亚乙烯基芳族聚合物组合物，其中橡胶是硫基硅烷链端改性弹性体聚合物。 在本发明中，官能化橡胶在标准接枝聚合工艺技术中提供足够的接枝水平以制备所需的橡胶粒度分布和形态。 在一系列橡胶改性单亚乙烯基芳族聚合物中，已经发现使用根据本发明的改性弹性体聚合物可以改善树脂性能，特别是透明度，表面和物理性能的组合，包括橡胶改性的单亚乙烯基芳族均聚物 （例如，高抗冲聚苯乙烯和共聚物（例如ABS），功能化橡胶具有提供优化的反应性接枝位点的硫基官能团，这确保在接枝聚合条件下，形成接枝到丁二烯聚合物嵌段上的单亚乙烯基芳族聚合物嵌段。 特别希望使用在橡胶改性单亚乙烯基芳族聚合物中更经济有效地使用的聚丁二烯均聚物橡胶。

    Monovinylidene aromatic polymers with improved toughness and rigidity and a process for their preparation
    5.
    发明授权
    Monovinylidene aromatic polymers with improved toughness and rigidity and a process for their preparation 失效
    具有改善韧性和刚性的单亚乙烯基芳族聚合物及其制备方法

    公开(公告)号：US06444752B1

    公开(公告)日：2002-09-03

    申请号：US09852198

    申请日：2001-05-09

    申请人： Mehmet Demirors ,  Dianne J. M. Maughon ,  Jose M. Rego ,  David Schrader

    发明人： Mehmet Demirors ,  Dianne J. M. Maughon ,  Jose M. Rego ,  David Schrader

    IPC分类号： C08F27902

    CPC分类号： C08F279/02 ,  C08F257/02 ,  C08L51/003 ,  C08L51/04 ,  C08F212/08 ,  C08L2666/02

    摘要： Disclosed are rubber-modified monovinylidene aromatic polymers with improved toughness and rigidity as well as a process for the preparation thereof. The polymer comprises: a) a monovinylidene aromatic polymer matrix, b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a diene rubber having I) from 20 to 80 percent, based on the total weight of said rubber particles, of a high solution viscosity component having a viscosity value ranging from 110 to 500 centipoise and II) from 80 to 20 percent, based on the total weight of said rubber particles, of a low solution viscosity component having a viscosity value ranging from 1 to 100 centipoise, further characterized in that the ratio of solution viscosity of high solution viscosity component to the solution viscosity of low solution viscosity ranges from 1.1 to 500, wherein both components I and II have a 1,4 cis content of greater than 30 percent, and III) the rubber is grafted with monovinylidene aromatic polymer to the extent that there is at least 30 percent monovinylidene aromatic polymer present as grafts on the rubber.

    摘要翻译： 公开了具有改进的韧性和刚性的橡胶改性的单亚乙烯基芳族聚合物以及其制备方法。 聚合物包括：a）单亚乙烯基芳族聚合物基体，b）分散在其中的橡胶颗粒，其特征在于，所述橡胶颗粒由二烯橡胶制成，所述二烯橡胶的I）为20-80重量％，基于所述橡胶颗粒的总重量， 具有粘度值为110-500厘泊的高溶液粘度组分和II。基于所述橡胶颗粒总重量的80％至20％的粘度值范围为1至100的低溶液粘度组分 其特征在于，高溶液粘度组分的溶液粘度与低溶液粘度的溶液粘度的比例为1.1至500，其中组分I和II均具有大于30％的1,4-顺式含量，以及 III）橡胶用单亚乙烯基芳族聚合物接枝至至少30％的单亚乙烯基芳族聚合物作为橡胶上的接枝物存在的程度。

    Compositions, Methods of Making the Same, and Articles Prepared from the Same
    7.
    发明申请
    Compositions, Methods of Making the Same, and Articles Prepared from the Same 审中-公开
    组合，制作方法及其制备方法

    公开(公告)号：US20130316111A1

    公开(公告)日：2013-11-28

    申请号：US13991545

    申请日：2011-12-29

    申请人： Xiaosong Wu ,  Jose M. Rego ,  Kim L. Walton ,  Brian W. Walther ,  Michael D. Read

    发明人： Xiaosong Wu ,  Jose M. Rego ,  Kim L. Walton ,  Brian W. Walther ,  Michael D. Read

    IPC分类号： C08L47/00

    CPC分类号： C08L47/00 ,  C08L23/10 ,  C08L23/16 ,  Y10T428/139

    摘要： A composition comprising at least the following components: (A) a first composition comprising the following: i) a first interpolymer comprising, in polymerized form, ethylene, an α-olefin, and a nonconjugated polyene; ii) a second interpolymer comprising, in polymerized form, ethylene, an α-olefin and a nonconjugated polyene; and wherein the first composition has an MWD less than, or equal to, 3.5, a Mooney Viscosity (ML (1+4 @125° C.)) greater than, or equal to, 80, and an [(ML(1+4 @125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g; (B) a thermoplastic polymer; and (C) a vulcanization agent is provided. A crosslinked composition made by heating one or more of the inventive compositions is also provided. Articles made from one or more of the inventive compositions are also provided.

    摘要翻译： 至少包含以下组分的组合物：（A）包含以下物质的第一组合物：i）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第一共聚体; ii）以聚合形式包含乙烯，α-烯烃和非共轭多烯的第二共聚体; 并且其中第一组合物的MWD小于或等于3.5，大于或等于80的门尼粘度（ML（1 + 4 @ 125℃））和[（ML（1+ 4 @ 125℃））/ Mw（conv）] * 1000大于0.429摩尔/ g; （B）热塑性聚合物; 和（C）硫化剂。 还提供了通过加热一种或多种本发明组合物制备的交联组合物。 还提供了由一种或多种本发明组合物制成的制品。