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1.发明授权公开(公告)号：US07923399B2
公开(公告)日：2011-04-12
申请号：US11547209
申请日：2005-03-31
申请人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
发明人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
IPC分类号： B01J29/42
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2 I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2 II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.
摘要翻译： 用于转化烃的催化剂包括基于催化剂的重量，1-60重量％的沸石，0.1-10重量％的助催化组分，5-98重量％的耐热无机氧化物，和 以氧化物换算0-70重量％的粘土。 沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物，其基于混合物的重量，包含所述MFI结构的75-100重量％ 含沸石的磷光体和过渡金属和0-25重量％的大孔沸石。 就氧化物的质量而言，含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式：（0-0.3）Na2O（0.3-5.5）Al2O3（1.0-10）P2O5。 （0.7-15）M1xOy（0.01-5）M2mOn（0-10）RE2O3（70-97）SiO2 I或（0-0.3）Na2O（0.3-5）Al2O3（1.0-10）P2O5（ 0.7-15）MpOq。（0-10）RE2O3。（70-98）SiO2 II助催化剂组分是选自碱金属，ⅣB族金属，Ⅷ族非贵金属的一种或多种 ，元素周期表中的稀土金属。 该催化剂具有较高的转化石油烃的能力和较高的丙烯，乙烯和轻质芳族化合物的产率。
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公开(公告)号：US20070293714A1
公开(公告)日：2007-12-20
申请号：US11547209
申请日：2005-03-31
申请人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
发明人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2 I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2 II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.
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3.发明授权公开(公告)号：US07485595B2
公开(公告)日：2009-02-03
申请号：US10855386
申请日：2004-05-28
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： B01J29/04 , B01J29/87 , B01J29/06 , B01J21/00 , B01J29/00 , B01J29/08 , B01J21/16 , B01J23/00 , B01J23/32 , B01J23/02 , B01J23/06 , B01J23/70
CPC分类号： B01J29/088 , B01J29/061 , B01J29/146 , B01J29/166 , B01J37/0045 , B01J37/16 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/05
摘要： A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.
摘要翻译： 一种分子筛催化剂，用于裂解烃，包括分子筛，耐火无机氧化物，粘土和金属组分，其中所述分子筛的量为1至90重量％，耐火无机氧化物为2至80重量％ ，粘土为2〜80重量％，金属成分为0.1〜30重量％，以所述金属的最高化合价的氧化物计，基于催化剂的总量计，其中， 所述金属组分基本上以还原状态存在，并且是选自IIIA族金属（铝以外）中的一种或多种金属，以及IVA，VA，IB，IIB，VB，VIB和VIIB族的金属，以及 周期表第Ⅷ族的非贵金属。 该催化剂具有较高的裂解活性和较高的硫还原活性。
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公开(公告)号：US07435332B2
公开(公告)日：2008-10-14
申请号：US10949298
申请日：2004-09-27
申请人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
摘要： This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.
摘要翻译： 本发明涉及一种裂解烃油的方法。 该方法包括使烃油与已经与含有还原气体的气氛接触的催化剂接触，分离裂化产物和催化剂，并再生催化剂。 催化剂是含有金属组分的裂化催化剂，或含有金属组分的裂化催化剂和不含金属组分的裂化催化剂的催化剂混合物。 催化剂与含有还原气体的气氛在100〜900℃的温度下接触1秒以上，含有还原气体的气氛量不低于0.03立方米/ 裂化催化剂在还原反应器中以0.1-0.5MPa的压力每分钟含有金属组分。 该工艺提高脱硫和重油的能力。
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公开(公告)号：US09163182B2
公开(公告)日：2015-10-20
申请号：US12027123
申请日：2008-02-06
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。
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公开(公告)号：US20080289997A1
公开(公告)日：2008-11-27
申请号：US12027123
申请日：2008-02-06
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。
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公开(公告)号：US07347930B2
公开(公告)日：2008-03-25
申请号：US10964644
申请日：2004-10-15
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。
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公开(公告)号：US20050279670A1
公开(公告)日：2005-12-22
申请号：US10949298
申请日：2004-09-27
申请人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
摘要： This invention relates to a process for cracking hydrocarbon oils. Said process comprises contacting a hydrocarbon oil with a catalyst that has contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, regenerating the catalyst, contacting the regenerated catalyst with said atmosphere containing a reducing gas, wherein said catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component, contacting said catalyst with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, wherein the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has higher ability of desulfurizing and cracking heavy oils.
摘要翻译： 本发明涉及一种裂解烃油的方法。 所述方法包括使烃油与与还原气体的气氛接触的催化剂，分离裂化产物和催化剂，再生催化剂，使再生催化剂与含有还原气体的气氛接触，其中所述催化剂是裂化 含有金属成分的催化剂或含有金属成分的裂化催化剂和不含金属成分的裂化催化剂的催化剂混合物，使催化剂与含有还原气体的气氛在100〜900℃的温度下接触至少 1秒钟，其中含有还原气体的气氛量在还原反应器中的压力为0.1-0.5MPa时，每分钟含有每分钟金属组分的裂化催化剂的还原气体不少于0.03立方米。 该工艺具有较高的脱硫脱硫重油能力。
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公开(公告)号：US20050133419A1
公开(公告)日：2005-06-23
申请号：US10964644
申请日：2004-10-15
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译： 一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。
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公开(公告)号：US09175230B2
公开(公告)日：2015-11-03
申请号：US11658831
申请日：2005-07-14
申请人： Jun Long , Zhonghong Qiu , Youbao Lu , Jiushun Zhang , Zhijian Da , Huiping Tian , Yuxia Zhu , Wanhong Zhang , Zhenbo Wang
发明人： Jun Long , Zhonghong Qiu , Youbao Lu , Jiushun Zhang , Zhijian Da , Huiping Tian , Yuxia Zhu , Wanhong Zhang , Zhenbo Wang
IPC分类号： B01J29/00 , B01J29/80 , C10G11/05 , B01J29/06 , B01J29/08 , B01J21/04 , B01J27/16 , B01J29/40 , B01J29/70 , B01J29/85 , B01J37/00
CPC分类号： C10G11/05 , B01J21/04 , B01J27/16 , B01J29/06 , B01J29/084 , B01J29/40 , B01J29/70 , B01J29/80 , B01J29/85 , B01J37/0045 , B01J2229/42 , C10G2400/02
摘要： A cracking catalyst, which contains alumina, phosphorus and molecular sieve, with or without clay, wherein said alumina is η-alumina or a mixture of η-alumina and χ-alumina and/or γ-alumina, and wherein the catalyst contains, on the basis of the total amount of the catalyst, 0.5-50 wt % of η-alumina, 0-50 wt % of χ-alumina and/or γ-alumina, 10-70 wt % of molecular sieve, 0-75 wt % of clay, and 0.1-8 wt % of phosphorus, measured as P2O5. The catalyst not only has higher cracking activity and higher cracking ability for cracking heavy oil, but also improves significantly quality and yield of gasoline, LCO and LPG in cracking products.
摘要翻译： 一种裂解催化剂，其含有氧化铝，磷和分子筛，具有或不具有粘土，其中所述氧化铝是氧化铝或氧化铝和氧化铝和χ-氧化铝和/或γ-氧化铝的混合物，并且其中所述催化剂含有 ，基于催化剂的总量，0.5-50重量％的氧化铝，0-50重量％的χ-氧化铝和/或γ-氧化铝，10-70重量％的分子筛，0- 75重量％的粘土和0.1-8重量％的磷，以P2O5测量。 该催化剂不仅具有较高的裂解活性和较高的裂解重质油裂化能力，而且可显着提高裂化产物中汽油，LCO和LPG的质量和产率。
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