Modified Zeolite Beta
    5.
    发明申请
    Modified Zeolite Beta 有权
    改性沸石Beta

    公开(公告)号:US20080261803A1

    公开(公告)日:2008-10-23

    申请号:US11915765

    申请日:2006-05-31

    IPC分类号: B01J21/04

    摘要: A modified zeolite beta having an anhydrous chemical formula, by weight % of the oxides, of (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(70-97)SiO2, wherein M is one or more transition metal(s) selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn, x is the number of the atoms of said transition metal M, and y is a number that meets with the requirement of the oxidation state of said transition metal M, is disclosed. The modified zeolite beta can be used as an active component of a cracking catalyst or additive for catalytic cracking of petroleum hydrocarbons.

    摘要翻译: 具有无水化学式的改性沸石β,其重量百分比为(0-0.3)Na 2 O(0.5-10)Al 2 O 3, (1.3-10)P 5 (0.7-15)M< x< (70-97)SiO 2,其中M是一种或多种选自Fe,Co,Ni,Cu,Mn,Zn的过渡金属和 Sn,x是所述过渡金属M的原子数,y是满足所述过渡金属M的氧化态的要求的数。 改性沸石β可用作裂化催化剂或石油烃催化裂化添加剂的活性组分。

    Process for cracking hydrocarbon oils
    6.
    发明授权
    Process for cracking hydrocarbon oils 有权
    裂解烃油的工艺

    公开(公告)号:US07435332B2

    公开(公告)日:2008-10-14

    申请号:US10949298

    申请日:2004-09-27

    IPC分类号: C10G11/00 C10G9/00

    CPC分类号: C10G11/05 C10G11/04

    摘要: This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.

    摘要翻译: 本发明涉及一种裂解烃油的方法。 该方法包括使烃油与已经与含有还原气体的气氛接触的催化剂接触,分离裂化产物和催化剂,并再生催化剂。 催化剂是含有金属组分的裂化催化剂,或含有金属组分的裂化催化剂和不含金属组分的裂化催化剂的催化剂混合物。 催化剂与含有还原气体的气氛在100〜900℃的温度下接触1秒以上,含有还原气体的气氛量不低于0.03立方米/ 裂化催化剂在还原反应器中以0.1-0.5MPa的压力每分钟含有金属组分。 该工艺提高脱硫和重油的能力。

    Cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using the same
    7.
    发明授权
    Cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using the same 有权
    包含层状粘土的裂化催化剂和使用其的裂解烃油的方法

    公开(公告)号:US06908544B2

    公开(公告)日:2005-06-21

    申请号:US10327122

    申请日:2002-12-24

    IPC分类号: C10G11/05 B01J29/06

    CPC分类号: C10G11/05

    摘要: The present invention relates to a cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using said catalyst. Said catalyst is prepared by the process comprising the following steps: mixing and slurrying an expandable clay, a modifier component, pseudo-boehmite and water for 0.1-10 h to obtain a slurry, aging the slurry at 50-85° C. for 0.1-10 h, then drying and forming the slurry to obtain a formed material, water washing and aging the solid, and finally drying and calcining the solid, and said modifier being one or more selected from the group consisting of hydroxyl polymers of silicon, aluminum, zirconium or titanium, and substances comprising one or more of said hydroxyl polymers. Said process for cracking hydrocarbon oils comprises contacting a hydrocarbon oil with a catalyst under the cracking conditions, said catalyst being the aforesaid cracking catalyst comprising layered clays or a mixture of at least 1% by weight of said cracking catalyst comprising layered clays and a prior cracking catalyst. The catalyst according to the present invention has an improved ability to convert heavy oils. The process according to the present invention for cracking hydrocarbon oils has higher conversion of hydrocarbon oils and higher yield of light oils.

    摘要翻译: 本发明涉及包含层状粘土的裂化催化剂和使用所述催化剂裂化烃油的方法。 所述催化剂通过包括以下步骤的方法制备:将可膨胀粘土,改性剂组分,假勃姆石和水混合并制浆0.1-10小时以获得浆料,使浆料在50-85℃下老化0.1 -10小时,然后干燥并形成浆料以获得成型材料,水洗和老化固体,最后干燥和煅烧固体,所述改性剂是选自硅,铝的羟基聚合物中的一种或多种 ,锆或钛,以及包含一种或多种所述羟基聚合物的物质。 所述裂解烃油的方法包括在裂化条件下使烃油与催化剂接触,所述催化剂是上述包含层状粘土的裂化催化剂或至少1重量%的包含层状粘土的裂化催化剂和先前裂化的混合物 催化剂。 根据本发明的催化剂具有改进重油转化的能力。 根据本发明的用于裂解烃油的方法具有较高的烃油转化率和较高的轻油产率。

    Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst
    9.
    发明授权
    Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst 有权
    含沸石的烃转化催化剂,其制备方法以及用催化剂转化烃油的方法

    公开(公告)号:US07923399B2

    公开(公告)日:2011-04-12

    申请号:US11547209

    申请日:2005-03-31

    IPC分类号: B01J29/42

    摘要: A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2  I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2  II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

    摘要翻译: 用于转化烃的催化剂包括基于催化剂的重量,1-60重量%的沸石,0.1-10重量%的助催化组分,5-98重量%的耐热无机氧化物,和 以氧化物换算0-70重量%的粘土。 沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物,其基于混合物的重量,包含所述MFI结构的75-100重量% 含沸石的磷光体和过渡金属和0-25重量%的大孔沸石。 就氧化物的质量而言,含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式:(0-0.3)Na2O(0.3-5.5)Al2O3(1.0-10)P2O5。 (0.7-15)M1xOy(0.01-5)M2mOn(0-10)RE2O3(70-97)SiO2 I或(0-0.3)Na2O(0.3-5)Al2O3(1.0-10)P2O5( 0.7-15)MpOq。(0-10)RE2O3。(70-98)SiO2 II助催化剂组分是选自碱金属,ⅣB族金属,Ⅷ族非贵金属的一种或多种 ,元素周期表中的稀土金属。 该催化剂具有较高的转化石油烃的能力和较高的丙烯,乙烯和轻质芳族化合物的产率。