公开(公告)号：US20070072056A1

公开(公告)日：2007-03-29

申请号：US11508158

申请日：2006-08-23

申请人： Jung-min Oh ,  Hae-kyoung Kim ,  Hyuk Chang

发明人： Jung-min Oh ,  Hae-kyoung Kim ,  Hyuk Chang

IPC分类号： H01M4/94 ,  H01M8/10 ,  H01M4/96

CPC分类号： H01M8/1004 ,  H01M8/0208 ,  H01M8/021 ,  H01M8/0232 ,  H01M8/0234 ,  H01M8/0236 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  H01M8/0247 ,  H01M8/0269

摘要： A membrane electrode assembly for a fuel cell, in which electrical resistance is minimized by including a current collector between a catalyst layer and a fuel diffusion layer inside electrodes to shorten the electron transfer distance, and in which corrosion of the current collector due to direct contact between the current collector and the catalyst in the catalyst layer is prevented by including an electrically conductive current collector-protecting layer between the current collector and the catalyst layer, and a fuel cell including the membrane electrode assembly which can stably exhibit constant performance for a prolonged period of time, and which has excellent efficiency due to low electrical resistance.

摘要翻译： 一种用于燃料电池的膜电极组件，其中通过在催化剂层和电极内部的燃料扩散层之间包括集电器来最小化电阻，以缩短电子传递距离，并且由于直接接触而导致集电体的腐蚀 通过在集电体和催化剂层之间设置导电集电体保护层，能够防止催化剂层中的集电体与催化剂之间的混合，以及具有能够长时间稳定地显示恒定性能的膜电极组件的燃料电池 一段时间，由于低电阻而具有优异的效率。

公开(公告)号：US08415072B2

公开(公告)日：2013-04-09

申请号：US11508148

申请日：2006-08-23

申请人： Jung-min Oh ,  Hae-kyoung Kim ,  Ji-rae Kim ,  Joon-hee Kim ,  Yoon-hoi Lee ,  Sang-hoon Joo

发明人： Jung-min Oh ,  Hae-kyoung Kim ,  Ji-rae Kim ,  Joon-hee Kim ,  Yoon-hoi Lee ,  Sang-hoon Joo

IPC分类号： H01M6/02

CPC分类号： H01M8/1004 ,  H01M8/0232 ,  H01M8/0234 ,  H01M8/0236 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  H01M8/0247 ,  H01M8/0269 ,  Y02P70/56

摘要： A membrane electrode assembly for a fuel cell provides a current collector adjacent to an electrode catalyst layer. Since electrons passing between the current collector and the electrode catalyst layer do not pass through a diffusion layer or a supporting layer, the diffusion layer or supporting layer may be non-conductive. Thus, various materials that are hydrophilic, hydrophobic, porous, hydrous, or the like can be used for the diffusion layer and the supporting layer, thereby improving the performance of the fuel cell. In addition, manufacturing costs of the membrane electrode assembly can be decreased since the membrane electrode assembly can be manufactured quickly with low energy.

摘要翻译： 用于燃料电池的膜电极组件提供与电极催化剂层相邻的集电体。 由于在集电体和电极催化剂层之间通过的电子不通过扩散层或支撑层，所以扩散层或支撑层可以是不导电的。 因此，可以将各种亲水，疏水，多孔，含水等的材料用于扩散层和支撑层，从而提高燃料电池的性能。 此外，膜电极组件的制造成本可以降低，因为可以以低能量快速制造膜电极组件。

公开(公告)号：US20070048594A1

公开(公告)日：2007-03-01

申请号：US11508148

申请日：2006-08-23

申请人： Jung-min Oh ,  Hae-kyoung Kim ,  Ji-rae Kim ,  Joon-hee Kim ,  Yoon-hoi Lee ,  Sang-hoon Joo

发明人： Jung-min Oh ,  Hae-kyoung Kim ,  Ji-rae Kim ,  Joon-hee Kim ,  Yoon-hoi Lee ,  Sang-hoon Joo

IPC分类号： H01M4/94 ,  H01M4/96

CPC分类号： H01M8/1004 ,  H01M8/0232 ,  H01M8/0234 ,  H01M8/0236 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  H01M8/0247 ,  H01M8/0269 ,  Y02P70/56

摘要： A membrane electrode assembly for a fuel cell provides a current collector adjacent to an electrode catalyst layer. Since electrons passing between the current collector and the electrode catalyst layer do not pass through a diffusion layer or a supporting layer, the diffusion layer or supporting layer may be non-conductive. Thus, various materials that are hydrophilic, hydrophobic, porous, hydrous, or the like can be used for the diffusion layer and the supporting layer, thereby improving the performance of the fuel cell. In addition, manufacturing costs of the membrane electrode assembly can be decreased since the membrane electrode assembly can be manufactured quickly with low energy.

摘要翻译： 用于燃料电池的膜电极组件提供与电极催化剂层相邻的集电体。 由于在集电体和电极催化剂层之间通过的电子不通过扩散层或支撑层，所以扩散层或支撑层可以是不导电的。 因此，可以将各种亲水，疏水，多孔，含水等的材料用于扩散层和支撑层，从而提高燃料电池的性能。 此外，膜电极组件的制造成本可以降低，因为可以以低能量快速制造膜电极组件。

公开(公告)号：US08187764B2

公开(公告)日：2012-05-29

申请号：US11347275

申请日：2006-02-06

申请人： Ji-rae Kim ,  Hae-kyoung Kim ,  Seung-jae Lee ,  Hyuk Chang

发明人： Ji-rae Kim ,  Hae-kyoung Kim ,  Seung-jae Lee ,  Hyuk Chang

IPC分类号： H01M2/00 ,  H01M8/10

CPC分类号： H01M4/8605 ,  H01M4/881 ,  H01M4/8817 ,  H01M4/8896 ,  H01M8/023 ,  H01M8/04119 ,  H01M8/1004

摘要： A fuel cell includes a cathode, an anode, an electrolyte membrane interposed between the cathode and the anode, and a porous layer containing a moisture retentive material. The anode includes an anode catalyst layer adjacent to the electrolyte membrane and an anode diffusion layer adjacent to the anode catalyst layer, and the porous layer is disposed between the anode catalyst layer and the electrolyte membrane. The performance of the fuel cell can be stably maintained even when a fuel supply is temporarily interrupted due to a malfunction of a pump or clogging of a fuel channel.

摘要翻译： 燃料电池包括阴极，阳极，插在阴极和阳极之间的电解质膜，以及含有保湿材料的多孔层。 阳极包括与电解质膜相邻的阳极催化剂层和与阳极催化剂层相邻的阳极扩散层，并且多孔层设置在阳极催化剂层和电解质膜之间。 即使当由于泵的故障或燃料通道堵塞而暂时中断燃料供给时，也能够稳定地维持燃料电池的性能。

公开(公告)号：US08173712B2

公开(公告)日：2012-05-08

申请号：US11150366

申请日：2005-06-13

申请人： Hae-kyoung Kim ,  Jae-sung Lee ,  Hyun-chul Lee ,  Hyuk Chang ,  Chang-houn Rhee

发明人： Hae-kyoung Kim ,  Jae-sung Lee ,  Hyun-chul Lee ,  Hyuk Chang ,  Chang-houn Rhee

IPC分类号： C08J5/20 ,  C08J5/22 ,  H01M8/10

CPC分类号： C08J5/2275 ,  C08J2327/18 ,  H01M8/04197 ,  H01M8/1011 ,  H01M8/1016 ,  H01M2300/002 ,  H01M2300/0082 ,  H01M2300/0088 ,  Y02E60/523

摘要： The present invention relates to a modified inorganic material with excellent cation exchange capacity. In addition, the invention relates to a method of preparing the modified inorganic material, a composite electrolyte membrane comprising the modified inorganic material powder that has excellent methanol-repelling ability, and a fuel cell comprising the composite electrolyte membrane. The modified inorganic material includes an inorganic material, and a cation exchanger bonded to the inorganic material.

摘要翻译： 本发明涉及具有优异的阳离子交换能力的改性无机材料。 此外，本发明涉及一种制备改性无机材料的方法，包括具有优异的甲醇驱除能力的改性无机材料粉末的复合电解质膜和包含复合电解质膜的燃料电池。 改性无机材料包括无机材料和与无机材料结合的阳离子交换剂。

公开(公告)号：US07368198B2

公开(公告)日：2008-05-06

申请号：US10927194

申请日：2004-08-27

申请人： Hae-kyoung Kim ,  Jae-sung Lee ,  Chang-houn Rhee ,  Hyuk Chang

发明人： Hae-kyoung Kim ,  Jae-sung Lee ,  Chang-houn Rhee ,  Hyuk Chang

IPC分类号： H01M8/10 ,  C08J5/20

CPC分类号： B82Y30/00 ,  H01B1/122 ,  H01M8/1009 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1037 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1053 ,  H01M2300/0082

摘要： A hydrogen ionic conductive inorganic material having a layered structure, wherein a moiety containing a functional group with hydrogen ionic conductivity is introduced between layers of an inorganic material having a nano-sized interlayer distance. A polymer nanocomposite membrane including a reaction product of the hydrogen ionic conductive inorganic material and a conductive polymer, and a fuel cell using the same, are also provided. In the polymer nanocomposite membrane, a conductive polymer may be intercalated to a hydrogen ionic conductive inorganic material having a layered structure or products exfoliated from an inorganic material having a layered structure are dispersed in a conductive polymer.

摘要翻译： 具有层状结构的氢离子导电无机材料，其中含有具有氢离子导电性的官能团的部分被引入具有纳米尺寸层间距离的无机材料的层之间。 还提供了包括氢离子导电无机材料和导电聚合物的反应产物的聚合物纳米复合膜以及使用其的燃料电池。 在聚合物纳米复合膜中，可以将导电性聚合物嵌入到具有层状结构的氢离子导电性无机材料或从具有层状结构的无机材料剥离的产物分散在导电性聚合物中。

公开(公告)号：US20070218336A1

公开(公告)日：2007-09-20

申请号：US11656375

申请日：2007-01-23

申请人： Hae-kyoung Kim ,  Won-mok Lee ,  Hyuk Chang ,  Jin Chul Jung ,  Sam Dae Park ,  Yun Ju Chang

发明人： Hae-kyoung Kim ,  Won-mok Lee ,  Hyuk Chang ,  Jin Chul Jung ,  Sam Dae Park ,  Yun Ju Chang

IPC分类号： H01M8/10 ,  C08G75/20 ,  C08J5/22

CPC分类号： H01M8/1081 ,  C08J5/2256 ,  C08J2381/06 ,  C08J2383/04 ,  C08J2383/10 ,  C08L81/06 ,  C08L83/04 ,  C08L2205/05 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2300/0082 ,  Y02P70/56 ,  C08L83/00

摘要： A multiblock copolymer includes a polysulfone repeating unit of formula (1) below; a sulfonated polysulfone repeating unit of formula (2) below; and a polydialkylsiloxane repeating unit of formula (3) below, a method of preparing the multiblock copolymer, a polymer electrolyte membrane prepared from the multiblock copolymer, a method of preparing the polymer electrolyte membrane, and a fuel cell including the polymer electrolyte membrane: where l, m, and n are integers of 1-200; each of R1 through R8 is independently hydrogen, fluorine, or a C1-C10 alkyl group that can be substituted by at least one fluorine atom; and X represents a tetraalkylamine cation that can be substituted by hydrogen ions or other cations by ion exchange. The multiblock copolymer has a high ionic conductivity, high hydrophobicity, and good mechanical properties, can minimize crossover of methanol, and can be manufactured at a low cost. In addition, the structure of the multiblock copolymer can be varied to increase selectivity to a solvent used in a polymer electrolyte membrane.

摘要翻译： 多嵌段共聚物包括以下式（1）的聚砜重复单元; 下面式（2）的磺化聚砜重复单元; 和下述式（3）的聚二烷基硅氧烷重复单元，制备多嵌段共聚物的方法，由多嵌段共聚物制备的聚合物电解质膜，制备聚合物电解质膜的方法和包含聚合物电解质膜的燃料电池：其中 l，m和n是1-200的整数; R 1至R 8中的每一个独立地为氢，氟或C 1 -C 10烷基 可以被至少一个氟原子取代; 并且X表示可以被氢离子或其它阳离子通过离子交换取代的四烷基胺阳离子。 该多嵌段共聚物具有高的离子导电性，高疏水性和良好的机械性能，可最小化甲醇的交换，并可以低成本制造。 此外，可以改变多嵌段共聚物的结构，以增加对在聚合物电解质膜中使用的溶剂的选择性。

公开(公告)号：US07759453B2

公开(公告)日：2010-07-20

申请号：US11443169

申请日：2006-05-31

申请人： Hae-kyoung Kim ,  Won-mok Lee ,  Jin-chul Jung ,  Hyuk Chang ,  Sam-dae Park ,  Yoon-ju Chang

发明人： Hae-kyoung Kim ,  Won-mok Lee ,  Jin-chul Jung ,  Hyuk Chang ,  Sam-dae Park ,  Yoon-ju Chang

IPC分类号： C08G75/20

CPC分类号： C08J5/2268 ,  C08G75/23 ,  C08J2381/06 ,  C08L81/06 ,  H01M8/1011 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1072 ,  H01M8/1081 ,  H01M2300/0082 ,  Y02E60/523 ,  Y02P70/56

摘要： A multiblock copolymer includes a polysulfone repeating unit, a sulfonated polysulfone repeating unit and an ethylenic unsaturated group at a terminal of the multiblock copolymer. Also provided are a method of preparing the multiblock copolymer, a polymer electrolyte membrane prepared from the multiblock copolymer, a method of preparing the polymer electrolyte membrane, and a fuel cell including the polymer electrolyte membrane. The polymer electrolyte membrane that has a high ionic conductivity and good mechanical properties and minimizes crossover of methanol can be manufactured at low cost. In addition, the structure of the multiblock copolymer can be varied to increase selectivity to a solvent used in a polymer electrolyte membrane.

摘要翻译： 多嵌段共聚物在多嵌段共聚物的末端包括聚砜重复单元，磺化聚砜重复单元和烯属不饱和基团。 还提供了制备多嵌段共聚物的方法，由多嵌段共聚物制备的聚合物电解质膜，制备聚合物电解质膜的方法和包含聚合物电解质膜的燃料电池。 可以以低成本制造具有高离子导电性和良好机械性能并最小化甲醇交换的聚合物电解质膜。 此外，可以改变多嵌段共聚物的结构，以增加对在聚合物电解质膜中使用的溶剂的选择性。

公开(公告)号：US20070053826A1

公开(公告)日：2007-03-08

申请号：US11438229

申请日：2006-05-23

申请人： Hae-kyoung Kim ,  Jae-sung Lee ,  Young-kwon Kim ,  Hyuk Chang

发明人： Hae-kyoung Kim ,  Jae-sung Lee ,  Young-kwon Kim ,  Hyuk Chang

IPC分类号： C01B17/98 ,  H01M8/10 ,  C07C315/00 ,  C07C317/00

CPC分类号： C07C317/18 ,  B82Y30/00 ,  C01G23/003 ,  C01P2002/70 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/10 ,  C01P2004/20 ,  C01P2004/62 ,  C01P2004/64 ,  H01B1/122 ,  H01M8/04197 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1048 ,  H01M8/1067 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02E60/523 ,  Y02P70/56

摘要： A proton conducting titanate includes titanate and a sulfonic acid group-containing moiety having proton conductivity introduced into the surface of the titanate, in which the sulfonic acid group-containing moiety is directly bound to the titanate via an ether bond (—O). A polymer nano-composite membrane includes the proton conducting titanate, and a fuel cell includes the polymer nano-composite membrane. The proton conducting titanate is provided with a sulfonic acid functional group having proton conductivity, which increases the proton conductivity of the polymer nano-composite membrane. The polymer nano-composite membrane includes the proton conducting titanate, and thus can have a controllable degree of swelling in a methanol solution, and the transmittance of the polymer nano-composite membrane can be reduced. The polymer nano-composite membrane can be used as a proton conducting membrane in fuel cells to improve the thermal stability, energy density, and fuel efficiency of the fuel cells.

摘要翻译： 质子导电钛酸盐包括钛酸酯和具有引入钛酸盐表面的具有质子传导性的含磺酸基的部分，其中含磺酸基的部分通过醚键（-O）直接键合到钛酸酯上。 聚合物纳米复合膜包括质子导电钛酸盐，燃料电池包括聚合物纳米复合膜。 质子传导钛酸盐具有质子传导性的磺酸官能团，这增加了聚合物纳米复合膜的质子传导性。 聚合物纳米复合膜包括质子传导性钛酸盐，因此可以在甲醇溶液中具有可控度的溶胀度，并且可以降低聚合物纳米复合膜的透射率。 聚合物纳米复合膜可用作燃料电池中的质子传导膜，以提高燃料电池的热稳定性，能量密度和燃料效率。

公开(公告)号：US07883820B2

公开(公告)日：2011-02-08

申请号：US11415147

申请日：2006-05-02

申请人： Hyuk Chang ,  Hae-kyoung Kim ,  Hasuck Kim ,  Jin-Kyu Lee ,  Sangook Park ,  Shin Woo Ha

发明人： Hyuk Chang ,  Hae-kyoung Kim ,  Hasuck Kim ,  Jin-Kyu Lee ,  Sangook Park ,  Shin Woo Ha

IPC分类号： H01M8/10 ,  B01J20/28

CPC分类号： C08J5/22 ,  C08J2383/04 ,  H01M8/1048 ,  H01M8/106 ,  H01M8/1067 ,  H01M8/1069 ,  H01M2008/1095 ,  H01M2300/0068 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02P70/56

摘要： An ion-conductive composite membrane and a method of manufacturing the same, the membrane including phosphate platelets, a silicon compound, and a Keggin-type oxometalate and/or Keggin-type heteropoly acid, wherein the phosphate platelets are three-dimensionally connected to each other via the silicon compound. An electrolyte membrane having an ion-conductive inorganic membrane or an ion-conductive organic/inorganic composite membrane effectively prevents crossover of liquid fuel without the reduction of ion conductivity in a liquid fuel cell, thereby allowing for the production of fuel cells having excellent performance.

摘要翻译： 一种离子导电复合膜及其制造方法，所述膜包括磷酸盐片，硅化合物和Keggin型氧化金属酸盐和/或Keggin型杂多酸，其中磷酸盐血小板三维地连接到每个 其他通过硅化合物。 具有离子传导性无机膜或离子传导性有机/无机复合膜的电解质膜能够有效地防止液体燃料的交叉，而不会降低液体燃料电池中的离子传导性，从而能够生产具有优异性能的燃料电池。