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公开(公告)号:US20170248566A1
公开(公告)日:2017-08-31
申请号:US15445540
申请日:2017-02-28
Applicant: Kabushiki Kaisha Toshiba
Inventor: Ko YAMADA , Hirohisa MIYAMOTO , Reiko YOSHIMURA , Norikazu OSADA , Mitsuhiro OKI , Hiroko NAKAMURA
IPC: G01N33/00
CPC classification number: G01N33/0013 , G01N1/22 , G01N33/0027 , G01N33/0049
Abstract: A molecular detection apparatus according to an embodiment includes: a collection unit collecting a detection target gas containing a molecule to be detected; a substitution unit substituting a part of a molecular structure of at least a part of the molecule to generate a substitution product; a detector including a plurality of detection cells each having a sensor unit and an organic probe disposed at the sensor unit, the organic probe capturing the molecule or the substitution product; and a discriminator discriminating the molecule by a signal pattern based on an intensity difference of detection signals generated with the molecule or the substitution product being captured by the organic probes of the plurality of detection cells.
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公开(公告)号:US20240322222A1
公开(公告)日:2024-09-26
申请号:US18485357
申请日:2023-10-12
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Yuiko KOITABASHI , Tetsuya SASAKAWA , Hirofumi YASUMIISHI , Mitsuhiro OKI , Sayaka MORIMOTO
IPC: H01M10/0562 , B60L7/10 , H01M50/204 , H01M50/574
CPC classification number: H01M10/0562 , B60L7/10 , H01M50/204 , H01M50/574 , B60L50/64 , H01M2220/20 , H01M2300/0068
Abstract: In general, according to one embodiment, an electrode is provided. The electrode includes an active material and a titanium-containing solid electrolyte. The active material includes a transition metal oxide. In an X-ray absorption fine structure spectrum of Ti—K absorption edge for the electrode in a discharged state, a first X-ray absorption amount I at a first incident X-ray energy satisfies 0.2≤I≤0.6. In an X-ray absorption fine structure spectrum of Ti—K absorption edge for anatase titanium dioxide, a second X-ray absorption amount at a second incident X-ray energy is equal to the first X-ray absorption amount I. The first incident X-ray energy is higher than the second incident X-ray energy.
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公开(公告)号:US20250123251A1
公开(公告)日:2025-04-17
申请号:US18789830
申请日:2024-07-31
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Asato KONDO , Mitsuhiro OKI , Takashi KUBOKI
Abstract: A method of analyzing isopropylphenyl phosphate according to an embodiment includes desorbing a sample by hot extraction, analyzing the desorbed sample to obtain a mass chromatogram of one or more compounds in the sample by gas chromatography mass spectrometry and determining whether the mass chromatogram includes one or more peaks of one or more product ions and/or one or more molecular ions each having a predetermined mass-to-charge ratio (m/z).
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公开(公告)号:US20240097274A1
公开(公告)日:2024-03-21
申请号:US18176224
申请日:2023-02-28
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Yasunobu YAMASHITA , Kakuya UEDA , Mitsuhiro OKI , Yasuhiro HARADA , Norio TAKAMI
IPC: H01M50/431 , H01M4/48 , H01M10/42
CPC classification number: H01M50/431 , H01M4/483 , H01M10/425 , H01M2004/027
Abstract: In general, according to one embodiment, a nonaqueous electrolyte battery is provided. The nonaqueous electrolyte battery includes an electrode group, including a positive electrode, a negative electrode, and a separator. The separator includes at least one metal-element containing portion containing a metal element. The at least one metal-element containing portion is provided on a surface of the separator in contact with the negative electrode. The at least one metal-element containing portion contains at least one selected from a group consisting of a metal, a metallic oxide, and a metallic fluoride. An area of the at least one metal-element containing portion is in a range of 0.3 mm2 to 3.2 mm2.
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公开(公告)号:US20190293588A1
公开(公告)日:2019-09-26
申请号:US16131949
申请日:2018-09-14
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Hirohisa MIYAMOTO , Yasushi SHINJO , Ko YAMADA , Mitsuhiro OKI
Abstract: A molecular detection apparatus of an embodiment includes: a first detector which includes a first sensor containing a MOF having a fluorescence emitting property, a light source which irradiates the MOF with light, and a light receiver which receives fluorescence from the MOF; a second detector which includes a sensor layer electrodes electrically connected with the sensor layer; and a type discrimination and concentration calculation part which discriminates a type of the molecules to be detected based on a measurement result measured by the first detector, and calculates a concentration of the molecules a measurement result measured by the second detector based on a discrimination result of a type of the molecules.
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公开(公告)号:US20190086359A1
公开(公告)日:2019-03-21
申请号:US15912678
申请日:2018-03-06
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Ko YAMADA , Hirohisa MIYAMOTO , Reiko YOSHIMURA , Hiroko NAKAMURA , Mitsuhiro OKI , Yasushi SHINJO , Masaki ATSUTA
IPC: G01N27/414 , G01N27/68 , G01N33/00
CPC classification number: G01N27/4141 , G01N27/4146 , G01N27/68 , G01N33/0047
Abstract: A molecular detection apparatus according to an arrangement includes: a collection unit collecting a detection target gas containing a molecule to be detected; a detector including a detection cell that has an organic probe provided in a sensor unit, the organic probe capturing the collected molecule, and a discriminator discriminating the molecule by a detection signal generated by the molecule being captured by the organic probe of the detection cell. The detection cell has the organic probe including a dicyanovinyl structure or a coumarin structure.
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公开(公告)号:US20180080911A1
公开(公告)日:2018-03-22
申请号:US15436092
申请日:2017-02-17
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Ko YAMADA , Hirohisa MIYAMOTO , Reiko YOSHIMURA , Norikazu OSADA , Hiroko NAKAMURA , Mitsuhiro OKI
IPC: G01N33/00 , G01N27/414 , H01L29/16
Abstract: A molecular detection apparatus 1 according to an embodiment includes: a collection unit collecting detection target gas containing molecules to be detected; a detector including a detection cell having an organic probe provided at a sensor unit, the organic probe capturing the collected molecule to be detected; and a discriminator discriminating the molecule to be detected by a detection signal generated by the molecule being captured by the organic probe. The detection cell has the organic probe containing a phosphonic acid structure or phosphoric acid structure.
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公开(公告)号:US20240309523A1
公开(公告)日:2024-09-19
申请号:US18419283
申请日:2024-01-22
Inventor: Norihiro YOSHINAGA , Mutsuki YAMAZAKI , Keisuke SHIINO , Taishi FUKAZAWA , Yoshihiko NAKANO , Koji MIZUGUCHI , Yoshitsune SUGANO , Masahiko YOSHIKI , Asato KONDO , Mitsuhiro OKI
IPC: C25B11/053 , C25B9/23 , C25B9/77 , C25B11/031 , C25B11/056 , C25B11/063 , C25B11/093
CPC classification number: C25B11/053 , C25B9/23 , C25B9/77 , C25B11/031 , C25B11/056 , C25B11/063 , C25B11/093
Abstract: An electrode of an embodiment includes a porous titanium support and a catalyst layer for electrolysis provided on the porous titanium support and stacked sheet layers and gap layers alternately. A first covering layer including titanium oxide is provided on the porous titanium support on the catalyst layer side. A second covering layer including titanium oxide is provided on the porous titanium support on an opposite side of the catalyst layer. An average thickness of the first covering layer is denoted as D1. An average thickness of the second covering layer is denoted as D2. D1 and D2 satisfies 1 [nm]≤D2−D1≤20 [nm].
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公开(公告)号:US20230296527A1
公开(公告)日:2023-09-21
申请号:US17887582
申请日:2022-08-15
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Mitsuhiro OKI , Sayaka MORIMOTO
IPC: G01N21/78
CPC classification number: G01N21/78
Abstract: A method of analyzing an antimony ion of an embodiment, the method includes using a first analysis solution or a second analysis solution, the first analysis solution containing trivalent antimony ions and pentavalent antimony ions, the second analysis solution being a solution obtained by mixing a first acid and the first analysis solution, and mixing the first analysis solution or the second analysis solution with a second acid to obtain a third analysis solution in which the pentavalent antimony ions are chlorinated and which contains [SbCl6]− ions, mixing the third analysis solution and a first organic solvent and phase-separating the mixture into a fourth analysis solution as an organic phase and an aqueous phase to obtain the fourth analysis solution, mixing the fourth analysis solution and a coloring liquid containing rhodamine B to obtain a fifth analysis solution, and evaluating a concentration of the pentavalent antimony ions in the first analysis solution from color of the fifth analysis solution. A total concentration of nitric acid, cerium (IV) nitrate, and cerium (IV) sulfate contained in the first analysis solution is 0.00 mol/L or more and 0.1 mol/L or less. The total concentration of nitric acid, cerium (IV) nitrate, and cerium (IV) sulfate contained in the first acid is 0.00 mol/L or more and 0.1 mol/L or less. The total concentration of nitric acid, cerium (IV) nitrate, and cerium (IV) sulfate contained in the second acid is 0.00 mol/L or more and 0.1 mol/L or less.
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公开(公告)号:US20170350854A1
公开(公告)日:2017-12-07
申请号:US15685117
申请日:2017-08-24
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Ko YAMADA , Hirohisa MIYAMOTO , Norikazu OSADA , Mitsuhiro OKI , Yasuko NORITOMI
IPC: G01N27/414 , G01N27/62
CPC classification number: G01N27/4141 , G01N27/62 , G01N27/622 , H01J49/025 , H01J49/40
Abstract: A molecular detection apparatus according to an embodiment includes: a distributor which ionizes a target containing substances to be detected, applies voltage to ionized substances, and extracts the substances to be detected according to a time-of-flight based on the speed; a detector which detects the substance to be detected dropped from the distributor; and a discriminator which discriminates the substance to be detected. The detector includes: a plurality of detection units including field effect transistors using graphene layers; and a plurality of organic probes which are provided on the graphene layers, and at least some of which have different bond strengths with the substances to be detected. The substance to be detected is discriminated depending on a signal pattern based on intensity differences of the detection signals generated by differences in the bond strengths between the organic probes and the substances to be detected.
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