Abstract:
The present invention includes: a porous structure containing an oxygen ion conductive material; and a coating layer disposed on the porous structure and containing an electronically conductive material, in which a content of the oxygen ion conductive material is greater than that of the electronically conductive material, and the coating layer is uniformly formed to a thickness of 20 nm or less.
Abstract:
Provided is a method for manufacturing a sintered body for an electrolyte and an electrolyte for a fuel cell using the same. More particularly, the following disclosure relates to a method for preparing an electrolyte having a firm thin film layer by using a sintered body having controlled sintering characteristics, and application of the electrolyte to a solid oxide fuel cell. It is possible to control the sintering characteristics of a sintered body through a simple method, such as controlling the amounts of crude particles and nanoparticles. In addition, an electrode using the obtained sintered body having controlled sintering characteristics is effective for forming a firm thin film layer. Further, such an electrolyte having a firm thin film layer formed thereon inhibits combustion of fuel with oxygen when it is applied to a fuel cell, and thus shows significantly effective for improving the quality of a cell.
Abstract:
The present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell and a method for preparing the same. More particularly, the present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell obtained by forming a ceramic nanocatalyst including a noble metal dispersed therein in an atomic unit and contained in an ionic state having an oxidation number other than 0 through an in situ infiltration process in the internal pores of a porous electrode, and to application of the nanocatalyst to a solid oxide fuel cell having significantly higher electrochemical characteristics as compared to the solid oxide fuel cells including the conventional nickel-based anode and oxide anode, and particularly showing excellent characteristics at an intermediate or low temperature of 600° C. or less.
Abstract:
Provided is a solid oxide cell including a fuel electrode layer, electrolyte layer and an air electrode layer, wherein a diffusion barrier layer is provided between the air electrode layer and the electrolyte layer, the diffusion barrier layer includes: a first diffusion barrier layer formed on the electrolyte layer and including a sintered ceria-based metal oxide containing no sintering aid; and a second diffusion barrier layer formed on the first diffusion barrier layer and including a sintered product of a ceria-based metal oxide mixed with a sintering aid, the first diffusion barrier layer includes a sintered product of nanopowder and macropowder of a ceria-based metal oxide, and the first diffusion barrier layer and the second diffusion barrier layer are sintered at the same time. The diffusion barrier layer is densified, shows high interfacial binding force and prevents formation of a secondary phase derived from chemical reaction with the electrolyte.
Abstract:
A hybrid electrochemical cell using reversible operation of a solid oxide cell includes: i) solid oxide cell generating power; ii) first storage container storing hydrogen and carbon monoxide discharged from the solid oxide cell supplying the hydrogen and carbon monoxide to the solid oxide cell; iii) second storage container storing steam and carbon dioxide discharged from the solid oxide cell supplying the steam and carbon dioxide to the solid oxide cell; iv) first connection pipe connecting the first storage container, the second storage container, and the solid oxide cell; v) second connection pipe connecting the first storage container, the second storage container, and the solid oxide cell; vi) discharging terminal connected to the solid oxide cell; vii) charging terminal connected to the solid oxide cell spaced apart from the discharging terminal, having the solid oxide cell disposed in between; and viii) mode converter connected to the solid oxide cell.
Abstract:
Disclosed is a method of manufacturing a solid oxide fuel cell using a calendering process. The method includes preparing a stack including an anode support layer (ASL) and an anode functional layer (AFL), calendering the stack to obtain an anode, stacking an electrolyte layer on the anode to obtain an assembly, calendering the assembly to obtain an electrolyte substrate, sintering the electrolyte substrate, and forming a cathode on the electrolyte layer of the electrolyte substrate.
Abstract:
The present invention relates to a method for preparing a solid electrolyte using a sonochemical process, which includes a step of preparing a reaction vessel holding a solid electrolyte raw material in a solid or liquid form and a step of reacting the solid electrolyte raw material by applying energy into the reaction vessel by irradiating an ultrasound to the reaction vessel.
Abstract:
The present invention relates to a lithium-ion-conductive sulfide-based solid electrolyte which contains lithium (Li), sulfur (S), phosphorus (P), indium (In) and selenium (Se) and has a crystal structure of InSe and a method for preparing the same.
Abstract:
The present invention relates to a method for manufacturing a protonic ceramic fuel cell, more particularly to a method for manufacturing a protonic ceramic fuel cell, which includes an electrolyte layer with a dense structure and has very superior interfacial bonding between the electrolyte layer and a cathode layer.
Abstract:
Provided are a solid oxide fuel cell including: an anode support; a solid electrolyte layer formed on the anode support; and a composite cathode layer formed on the solid electrolyte layer, wherein the composite cathode layer is a porous sintered phase comprising an electrode material and an electrolyte material and a method for preparing same. The solid oxide fuel cell which includes a post-heat-treated nanocomposite cathode, which exhibits high interfacial strength and superior conductivity, exhibits superior power efficiency as well as superior durability.