Abstract:
A thermoplastic elastomer composition comprising 100 parts by mass of a hydrogenated block copolymer (A) comprising a polymer block (a) consisting of a structural unit derived from an aromatic vinyl compound and a polymer block (b) comprising 1 to 100% by mass of a structural unit (b1) derived from farnesene and comprising 99 to 0% by mass of a structural unit (b2) derived from a conjugated diene other than farnesene, a mass ratio[(a)/(b)] of the polymer block (a) to the polymer block (b) being 1/99 to 70/30; and 5 to 300 parts by mass of a polar group-containing olefinic polymer (B), is excellent in flexibility and molding processability and capable of adhering to a ceramic, a metal, a synthetic resin, or the like even through a heat treatment at low temperatures (for example, 190° C. or lower) without requiring a primer treatment or the like.
Abstract:
The present invention relates to a laminate including an adhesive layer that hardly suffers from adhesive transfer and exhibits a good adhesive strength, and a substrate layer, a protective film including the laminate, and a process for producing the laminate. The laminate of the present invention includes an adhesive layer and a substrate layer, in which the adhesive layer includes a hydrogenated product of a copolymer containing a constitutional unit (a) derived from an aromatic vinyl compound and a constitutional unit (b) derived from a conjugated diene; a content of a constitutional unit (b1) derived from farnesene in a whole amount of the constitutional unit (b) derived from the conjugated diene is from 1 to 100% by mass, and a content of a constitutional unit (b2) derived from a conjugated diene other than farnesene in a whole amount of the constitutional unit (b) derived from the conjugated diene is from 0 to 99% by mass; and a hydrogenation rate of carbon-carbon double bonds in the constitutional unit (b) derived from the conjugated diene is 50 mol % or more.
Abstract:
A resin composition including a hydrogenated block copolymer (A) including a polymer block (a) consisting of a structural unit derived from an aromatic vinyl compound and a polymer block (b) containing 1 to 100% by mass of a structural unit (b1) derived from farnesene and containing 99 to 0% by mass of a structural unit (b2) derived from a conjugated diene other than farnesene, 50 mol % or more of a carbon-carbon double bond in the polymer block (b) being hydrogenated; and at least one resin (B) selected from the group consisting of a polyphenylene ether-based resin, a styrene-based resin, an acrylic resin, a polycarbonate-based resin, and a polyamide-based resin.
Abstract:
A film for a liquid packaging container, comprising at least one of a layer containing a resin composition (X) containing a polypropylene resin (a) and at least one of a hydrogenated block copolymer (b), the hydrogenated block copolymer (b) being a hydrogenated product of a block copolymer containing a polymer block (A) mainly containing an aromatic vinyl compound unit, and a polymer block (B) mainly containing an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units, in the resin composition (X), the hydrogenated block copolymer (b) having a phase separation structure having formed therein both (i) an island phase having a long axis of 1 μm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, and in the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) being from 61/100 to 95/100.
Abstract:
Provided is a liquid packaging container having satisfactory flexibility and transparency, high heat-seal strength, high bag-breaking strength at normal temperature and low temperatures, and low (inner layer)-(inner layer) adhesiveness, which are properties important for liquid packaging containers for medical use. Specifically, provided is a liquid packaging container formed from a laminate of at least three layers including an inner layer formed from a resin composition (Y) as described below, an intermediate layer, and an outer layer formed from a resin composition (Z) as described below, the intermediate layer being formed from a resin composition (X) as described below: resin composition (X): a resin composition including 100 parts by mass of a polypropylene-based resin (1), 5 parts by mass to 95 parts by mass of a particular thermoplastic elastomer (2), and 10 parts by mass to 95 parts by mass of a particular ethylene-α-olefin copolymer (3); resin composition (Y): a resin composition including 100 parts by mass of a polypropylene-based resin (1′), and 5 parts by mass to 250 parts by mass of a particular thermoplastic elastomer (2′) (provided that a particular ethylene-α-olefin copolymer is not included or, if included, the content of the copolymer is less than 10 parts by mass); and resin composition (Z): a resin composition including 100 parts by mass of a polypropylene-based resin (1″), and 0 parts by mass to 35 parts by mass of a particular thermoplastic elastomer (2″).
Abstract:
A film for a liquid packaging container, comprising at least one of a layer containing a resin composition (X) containing a polypropylene resin (a) and at least one of a hydrogenated block copolymer (b), the hydrogenated block copolymer (b) being a hydrogenated product of a block copolymer containing a polymer block (A) mainly containing an aromatic vinyl compound unit, and a polymer block (B) mainly containing an isoprene (Ip) unit, a butadiene (Bd) unit, or isoprene (Ip) and butadiene (Bd) units, in the resin composition (X), the hydrogenated block copolymer (b) having a phase separation structure having formed therein both (i) an island phase having a long axis of 1 μm or more, or a bicontinuous structure, and (ii) an island phase having a long axis of 300 nm or less, and in the resin composition (X), the mass ratio ((a)/((a)+(b))) of the polypropylene resin (a) and the hydrogenated block copolymer (b) being from 61/100 to 95/100.
Abstract:
A hydrogenated block copolymer having: a polymer block (A) having 90% by mass or more of a structural unit derived from an aromatic vinyl compound based on the total mass of the polymer block (A); and a polymer block (B) having 90% by mass or more of a structural unit derived from a conjugated diene compound based on the total mass of the polymer block (B), the hydrogenated block copolymer satisfying the following conditions: (1) a peak top molecular weight of the block copolymer is 50,000 to 300,000; (2) a content of the polymer block (A) in the hydrogenated block copolymer is 20.0 to 50.0% by mass; and (3) a gel composition containing a paraffin oil as a base oil and the hydrogenated block copolymer at a mass ratio of 9:1 satisfies specific conditions. A method for producing the same, a crumb of the same, and a gel composition.