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    EMM-3, new crystalline microporous material
    1.
    发明授权
    EMM-3, new crystalline microporous material 有权
    EMM-3，新型结晶微孔材料

    公开(公告)号：US07255849B2

    公开(公告)日：2007-08-14

    申请号：US10863125

    申请日：2004-06-08

    申请人： Karl G. Strohmaier ,  Arthur W. Chester ,  William R. Harrison ,  James C. Vartuli

    发明人： Karl G. Strohmaier ,  Arthur W. Chester ,  William R. Harrison ,  James C. Vartuli

    IPC分类号： C01B37/04 ,  C01B37/08

    CPC分类号： C01B37/065 ,  B01J29/70 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  C01B37/04 ,  C01B37/06 ,  C01B39/54 ,  Y10S423/30

    摘要： EMM-3 (ExxonMobil Material number 3) is a new crystalline microporous material with a framework of tetrahedral atoms connected by atoms capable of bridging the tetrahedral atoms, the tetrahedral atom framework being defined by the interconnections between the tetrahedrally coordinated atoms in its framework. EMM-3 can be prepared in aluminophosphate (AlPO) and metalloaluminophosphate (MeAPO) compositions with the hexamethonium template. It has a unique X-ray diffraction pattern, which identifies it as a new material. EMM-3 is stable to calcination in air, absorbs hydrocarbons, and is catalytically active for hydrocarbon conversion.

    摘要翻译： EMM-3（埃克森美孚材料3号）是一种新的结晶微孔材料，其四面体原子框架由能够桥接四面体原子的原子连接，四面体原子框架由其框架中的四面体配位原子之间的互连定义。 可以在具有六甲铵模板的磷酸铝（AlPO）和金属铝磷酸盐（MeAPO）组合物中制备EMM-3。 它具有独特的X射线衍射图，将其识别为新材料。 EMM-3在空气中煅烧稳定，吸收烃，对烃转化具有催化活性。

    Synthesis and use of MSE-framework type molecular sieves
    2.
    发明申请
    Synthesis and use of MSE-framework type molecular sieves 有权
    合成和使用MSE-框架型分子筛

    公开(公告)号：US20090318696A1

    公开(公告)日：2009-12-24

    申请号：US12214631

    申请日：2008-06-20

    申请人： Karl G. Strohmaier ,  Simon C. Weston ,  James C. Vartuli ,  J. Thomas Ippoliti

    发明人： Karl G. Strohmaier ,  Simon C. Weston ,  James C. Vartuli ,  J. Thomas Ippoliti

    IPC分类号： C07D241/04 ,  B01J29/06

    CPC分类号： C07D295/023 ,  C01B37/02 ,  C01B39/48

    摘要： A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium and germanium, a source of an alkali or alkaline earth metal, M, and a source of organic cations, Q, having the following general structure: in which R1 is hydrogen or an alkyl group, and R2 and R3 are alkyl groups.

    摘要翻译： 合成具有MSE骨架类型的结晶分子筛的方法包括将包含水源，四价元素的氧化物源Y的反应混合物结晶，Y选自硅，锡，钛，钒和 锗，碱金属或碱土金属的源，M和有机阳离子源Q，具有以下一般结构：其中R1是氢或烷基，R2和R3是烷基。

    Synthesis and use of MSE-framework type molecular sieves
    3.
    发明授权
    Synthesis and use of MSE-framework type molecular sieves 有权
    合成和使用MSE-框架型分子筛

    公开(公告)号：US08025863B2

    公开(公告)日：2011-09-27

    申请号：US12214631

    申请日：2008-06-20

    申请人： Karl G. Strohmaier ,  Simon C. Weston ,  James C. Vartuli ,  J. Thomas Ippoliti

    发明人： Karl G. Strohmaier ,  Simon C. Weston ,  James C. Vartuli ,  J. Thomas Ippoliti

    IPC分类号： C01B39/04 ,  C01B39/48

    CPC分类号： C07D295/023 ,  C01B37/02 ,  C01B39/48

    摘要： A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium and germanium, a source of an alkali or alkaline earth metal, M, and a source of organic cations, Q, having the following general structure: in which R1 is hydrogen or an alkyl group, and R2 and R3 are alkyl groups.

    摘要翻译： 合成具有MSE骨架类型的结晶分子筛的方法包括将包含水源，四价元素的氧化物源Y的反应混合物结晶，Y选自硅，锡，钛，钒和 锗，碱金属或碱土金属的源，M和有机阳离子源Q，具有以下一般结构：其中R1是氢或烷基，R2和R3是烷基。

    EMM-11, A Novel Synthetic Crystalline Microporous Material, Its Preparation and Use
    6.
    发明申请
    EMM-11, A Novel Synthetic Crystalline Microporous Material, Its Preparation and Use 失效
    EMM-11，一种新型合成结晶微孔材料，其制备与应用

    公开(公告)号：US20100078388A1

    公开(公告)日：2010-04-01

    申请号：US12542493

    申请日：2009-08-17

    申请人： Karl G. Strohmaier ,  Douglas L. Dorset ,  Gordon J. Kennedy

    发明人： Karl G. Strohmaier ,  Douglas L. Dorset ,  Gordon J. Kennedy

    IPC分类号： C07F7/30 ,  B01D59/26

    CPC分类号： C07F7/30 ,  B01J20/18 ,  B01J20/2808 ,  C01B37/005 ,  C01B39/06 ,  C01B39/48

    摘要： EMM-11 is a novel synthetic crystalline microporous material having a single crystalline phase with a unique 3-dimensional channel system comprising three sets of channels, namely a first set comprising 10-ring channels, and a second set and third set comprising 8-ring channels. EMM-11 has unique T-atom connectivity and X-ray diffraction pattern which identify it as a novel material. EMM-11 may be prepared with an organic structure directing agent, preferably, 3-isopropyl-1-methyl-1H-imidazol-3-ium. EMM-11 may be used in organic compounds conversion and absorptive processes.

    摘要翻译： EMM-11是具有单一结晶相的新型合成结晶微孔材料，其具有独特的3维通道系统，该三维通道系统包括三组通道，即包含10环通道的第一组，第二组和第三组包含8-环 频道 EMM-11具有独特的T原子连接性和X射线衍射图，将其识别为新型材料。 EMM-11可以用有机结构导向剂，优选3-异丙基-1-甲基-1H-咪唑-3-酮来制备。 EMM-11可用于有机化合物的转化和吸收过程。

    Light hydrocarbon separation using 8-member ring zeolites
    7.
    发明授权
    Light hydrocarbon separation using 8-member ring zeolites 有权
    使用8元环型沸石轻烃分离

    公开(公告)号：US07332640B2

    公开(公告)日：2008-02-19

    申请号：US10699258

    申请日：2003-10-31

    申请人： Sebastian C. Reyes ,  David H. Olson ,  Haiming Liu ,  Karl G. Strohmaier ,  Jose G. Santiesteban

    发明人： Sebastian C. Reyes ,  David H. Olson ,  Haiming Liu ,  Karl G. Strohmaier ,  Jose G. Santiesteban

    IPC分类号： C07C7/12

    CPC分类号： C07C7/13 ,  C07C11/06 ,  C07C9/08

    摘要： The present invention is related to a method for kinetically separating a light hydrocarbon mixture comprising at least two components by preferentially adsorbing a first component on a zeolite adsorbent comprising 8-member rings of tetrahedra as the pore opening controlling hydrocarbon diffusion and alkali metal cations balancing a framework charge, wherein a second component is not preferentially adsorbed. The novel process comprises contacting the light hydrocarbon mixture with a zeolite adsorbent having a SiO2/Al2O3 ratio greater than about 50 and less than 200 and further having a diffusion rate at least 50 times greater for the first component as compared to the second component, and then recovering at least one of the first component or the second component.

    摘要翻译： 本发明涉及一种用于动态分离含有至少两种组分的轻质烃混合物的方法，该轻质烃混合物优先吸附在包含八元环四面体的沸石吸附剂上的第一组分，作为开孔控制烃扩散和碱金属阳离子平衡 框架电荷，其中第二组分不被优先吸附。 该新方法包括使轻质烃混合物与沸石吸附剂接触，所述沸石吸附剂具有大于约50或更小的SiO 2 / Al 2 O 3 并且与第二组分相比，第一组分的扩散速率至少为50倍，然后回收第一组分或第二组分中的至少一种。

    Separation of 1-butene from C4 feed streams
    9.
    发明授权
    Separation of 1-butene from C4 feed streams 有权
    从C4进料流中分离1-丁烯

    公开(公告)号：US07148392B2

    公开(公告)日：2006-12-12

    申请号：US10464584

    申请日：2003-06-17

    申请人： Gary L. Casty ,  Richard B. Hall ,  Sebastian C. Reyes ,  Robert P. Reynolds, Jr. ,  Karl G. Strohmaier

    发明人： Gary L. Casty ,  Richard B. Hall ,  Sebastian C. Reyes ,  Robert P. Reynolds, Jr. ,  Karl G. Strohmaier

    IPC分类号： C07C7/12

    CPC分类号： C07C11/08 ,  C07C7/13

    摘要： In a process for selectively separating 1-butene from a C4 feed stream comprising at least 1-butene, cis-2-butene and trans-2-butene, the feed stream is passed through a first bed of an adsorbent comprising a crystalline microporous material to form a substantially trans-2-butene-free effluent stream. Then, the substantially trans-2-butene-free effluent stream is passed through a second bed of an adsorbent comprising a crystalline microporous material to form a substantially 1-butene-free effluent stream, whereby the 1-butene is separated from the feed stream. The adsorbed 1-butene is then typically desorbed from the second adsorbent bed either by lowering the pressure or raising the temperature of the bed.

    摘要翻译： 在从包含至少1-丁烯，顺式-2-丁烯和反式-2-丁烯的C 4 H 4进料流中选择性分离1-丁烯的方法中，使进料流通过第一床 的吸附剂，其包含结晶微孔材料以形成基本上反式-2-丁烯的流出物流。 然后，将基本上反式-2-丁烯的流出物流通过包含结晶微孔材料的吸附剂的第二床，以形成基本上不含1-丁烯的流出物流，由此从进料流中分离出1-丁烯 。 吸附的1-丁烯通常通过降低压力或升高床的温度而从第二吸附剂床解吸。