公开(公告)号：US10427140B2

公开(公告)日：2019-10-01

申请号：US15678636

申请日：2017-08-16

申请人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Manuel Hernandez Rodriguez ,  Jose Luis Jorda Moret

发明人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Manuel Hernandez Rodriguez ,  Jose Luis Jorda Moret

IPC分类号： B01J20/10 ,  B01J29/70 ,  C01B39/48 ,  B01D53/86 ,  C07C1/22 ,  B01J29/04 ,  B01J35/00 ,  B01D53/04 ,  B01J20/30 ,  C10G73/02 ,  C01B37/00 ,  C01B39/54 ,  B01D53/94

摘要： The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.

公开(公告)号：US08337594B2

公开(公告)日：2012-12-25

申请号：US13272586

申请日：2011-10-13

申请人： Avelino Corma Canos ,  Miguel Palomino Roca ,  Fernando Rey Garcia ,  Susana Valencia Valencia

发明人： Avelino Corma Canos ,  Miguel Palomino Roca ,  Fernando Rey Garcia ,  Susana Valencia Valencia

IPC分类号： B01D53/02

CPC分类号： C10L3/10 ,  B01D53/04 ,  B01D2253/108 ,  B01D2256/24 ,  B01D2257/102 ,  B01D2257/504 ,  B01J20/18 ,  C01B39/48 ,  C10L3/102 ,  C10L3/104 ,  Y02C10/08 ,  Y02P20/152

摘要： The present invention describes the use of isostructural zeolites with rho zeolitic structure in processes of adsorption and separation of the various components of natural gas.

摘要翻译： 本发明描述了在天然气各种成分的吸附和分离过程中使用具有rho沸石结构的异构沸石。

公开(公告)号：US08226925B2

公开(公告)日：2012-07-24

申请号：US12525506

申请日：2008-01-31

申请人： Avelino Corma Canos ,  Manuel Moliner Marin ,  Fernando Rey Garcia ,  Jorge Gonzalez Gonzalez

发明人： Avelino Corma Canos ,  Manuel Moliner Marin ,  Fernando Rey Garcia ,  Jorge Gonzalez Gonzalez

IPC分类号： C01B39/46 ,  C01B39/48

CPC分类号： B01J29/70 ,  B01J20/18 ,  C01B39/48

摘要： Described herein are zeolite microporous crystalline materials comprising, in the heated state and in the absence of defects in its crystalline framework manifested by the presence of silanols, the empirical formula: x(M1/nXO2):yYO2:SiO2, wherein M is selected from H+, an inorganic cation of charge +n, and mixtures thereof, X is at least one chemical element having an oxidation state of +3, Y is at least one second chemical element other than Si having an oxidation state +4, x has a value between 0 and about 0.3, y has a value between 0 and about 0.1, and wherein the synthesized material has an X-ray diffraction pattern having at least values of angle 2θ (degrees) and relative intensities (I/I0) described. Process of making the microporous crystalline materials are also disclosed.

摘要翻译： 本文描述的是沸石微孔结晶材料，其包括在加热状态下，在不存在由硅烷醇存在的结晶框架中缺陷的情况下，经验式：x（M1 / nXO2）：yYO2：SiO2，其中M选自 H +，电荷无机阳离子+ n及其混合物，X是氧化态为+3的至少一种化学元素，Y是具有氧化态+4以外的除了Si以外的至少一种第二化学元素，x具有 值在0和约0.3之间，y具有在0和约0.1之间的值，并且其中合成材料具有至少具有角度2的角度的X射线衍射图案; （度）和相对强度（I / I0）。 还公开了制备微孔结晶材料的方法。

公开(公告)号：US08187469B2

公开(公告)日：2012-05-29

申请号：US11989330

申请日：2006-07-24

申请人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia

发明人： Avelino Corma Canos ,  Fernando Rey Garcia ,  Susana Valencia Valencia

IPC分类号： B01D15/00 ,  B01D15/04 ,  B01D53/22 ,  B01D59/12 ,  B01D53/02 ,  B01D59/26 ,  B01D47/00 ,  B01D53/14 ,  B01J39/00 ,  B01J49/00 ,  C02F1/42 ,  C02F1/28 ,  C07C7/144 ,  C01B33/36 ,  C07C7/12 ,  C01B39/00 ,  C01B21/00 ,  C01F7/00

CPC分类号： C07C7/13 ,  B01D15/00 ,  B01D53/02 ,  B01D53/04 ,  B01D53/047 ,  B01D2253/108 ,  B01D2253/308 ,  B01D2256/10 ,  B01D2256/24 ,  B01D2257/702 ,  B01J20/18 ,  C01B39/48 ,  C10G25/03 ,  C10G53/08 ,  C10G2300/1081 ,  C10G2300/1092 ,  C10G2300/805 ,  C10G2400/20 ,  C10L3/10 ,  C10L3/102 ,  C10L3/12

摘要： The invention relates to a method of separating fluids from mixtures using a zeolite known as ITQ-32 consisting of a two-dimensional pore system comprising channels with openings formed by 8 tetrahedra which are interconnected by channels with openings formed by 12 tetrahedra. The inventive method comprises at least the following steps: a) the zeolite ITQ-32 material is brought into contact with the mixture of fluids, b) one or more of the components are adsorbed in the zeolite ITQ-32 material, c) the non-adsorbed components are extracted, and d) one or more of the components adsorbed in the zeolite ITQ-32 material are recovered.

摘要翻译： 本发明涉及一种使用称为ITQ-32的沸石从混合物中分离流体的方法，所述沸石由二维孔隙系统组成，该二维孔隙系统包括由8面四面体形成的开口的通道，该通道由通过由12面四面体形成的开口的通道相互连接。 本发明的方法至少包括以下步骤：a）使沸石ITQ-32材料与流体混合物接触，b）一种或多种组分被吸附在沸石ITQ-32材料中，c） - 吸附的组分被提取，并且d）吸收在沸石ITQ-32材料中的一种或多种组分被回收。

公开(公告)号：US07709408B2

公开(公告)日：2010-05-04

申请号：US11036783

申请日：2005-01-14

申请人： Avelino Corma Canos ,  Agustin Martinez Feliu ,  Fernando Rey García ,  María José Díaz Cabañas ,  Maria de los Desamparados Arribas Viana

发明人： Avelino Corma Canos ,  Agustin Martinez Feliu ,  Fernando Rey García ,  María José Díaz Cabañas ,  Maria de los Desamparados Arribas Viana

IPC分类号： B01J29/06

CPC分类号： B01J35/0006 ,  B01J23/40 ,  B01J29/04 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/54 ,  C10G45/64 ,  C10G2300/1055 ,  C10G2300/4018 ,  C10G2300/703 ,  C10G2400/04 ,  C10L1/08 ,  Y10S585/94

摘要： The invention relates to a catalyst consisting of at least: one matrix comprising at least one oxide which is selected from an amorphous oxide, an oxide with low crystallinity and a mixture of both; at least one solid microporous crystalline material which, in the calcined and anhydrous state, has the molar compositions X2O3:nYO2:mZO2, in which X is a trivalent element such as, for example, Al, B, Fe, In, Ga, Cr, Y is at least one trivalent element that is different from Ge and Z is Ge, the value (n+m) is at least equal to 5 and can be between 5 and ∞, and the value of n/m is at least equal to 1; and at least one hydrogenating compound, preferably Pt, Pd, It, Ru, Rh, and Re or a combination of same. The invention also relates to the use of said catalyst in a process in order to improve the quality of diesel fractions.

摘要翻译： 本发明涉及至少由以下组成的催化剂：包含至少一种选自无定形氧化物，低结晶度氧化物和二者的混合物的至少一种氧化物的基体; 至少一种在煅烧和无水状态下具有摩尔组成X 2 O 3 :nYO 2 :mZO 2的固体微孔结晶材料，其中X是三价元素，例如Al，B，Fe，In，Ga，Cr Y是与Ge不同的至少一种三价元素，Z是Ge，值（n + m）至少等于5并且可以在5和∞之间，并且n / m的值至少等于 至1; 和至少一种氢化化合物，优选Pt，Pd，It，Ru，Rh和Re或其组合。 本发明还涉及在一个方法中使用所述催化剂以改进柴油馏分的质量。

公开(公告)号：US07056489B2

公开(公告)日：2006-06-06

申请号：US10632535

申请日：2003-08-01

申请人： Avelino Corma Canós ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey García

发明人： Avelino Corma Canós ,  Teresa Navarro Villalba ,  Susana Valencia Valencia ,  Fernando Rey García

IPC分类号： C01B39/48

CPC分类号： C10G11/05 ,  B01J29/04 ,  C01B37/005 ,  C01B39/023 ,  C01B39/08 ,  C10G47/16 ,  Y10S423/27

摘要： The invention relates to a method for synthesizing a family of zeolite materials, grouped together under the name ITQ-16, in an OH− medium and in the absence of fluorides and to the catalytic applications thereof. The zeolite ITQ-16 family of materials is characterized by having different proportions of distinct polymorphs A, B and C described as possible intergrowths in the Beta zeolite and, therefore, the X-ray diffraction patterns of said family are different from that described for the Beta zeolite. In its calcinated form, zeolite ITQ-16 has the following empirical formula: x(MXO2):tTO2:gGeO2:(1−g)SiO2, wherein T is one or more elements having +4 oxidation status and different from Ge and Si; X is one or more elements having +3 oxidation status; and M can be H+ or one or more inorganic cations with a +n charge.

摘要翻译： 本发明涉及一种用于合成沸石材料族的一种方法，该材料族以名称ITQ-16，在OH - 介质中和在不存在氟化物的情况下分组在一起，以及其催化应用。 沸石ITQ-16系列材料的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长而被描述，因此，所述族的X射线衍射图不同于对于 β沸石。 在其煅烧形式中，沸石ITQ-16具有以下经验式：x（MXO 2 2）：tTO 2：gGeO 2：（1 -g）SiO 2，其中T是具有+4氧化状态并且不同于Ge和Si的一种或多种元素; X是具有+3氧化状态的一种或多种元素; 并且M可以是H + +或一种或多种具有+ n电荷的无机阳离子。

公开(公告)号：US20050238575A1

公开(公告)日：2005-10-27

申请号：US11045727

申请日：2005-01-28

申请人： Avelino Corma ,  Maria Diaz ,  Fernando Rey

发明人： Avelino Corma ,  Maria Diaz ,  Fernando Rey

IPC分类号： B01J20/18 ,  B01J29/035 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  C01B39/48 ,  C01F7/00 ,  C10G11/00 ,  C10G11/05 ,  C10G25/03

CPC分类号： B01J29/70 ,  B01J20/18 ,  B01J29/035 ,  B01J29/04 ,  B01J29/74 ,  B01J2229/42 ,  C01B39/48 ,  C10G25/03

摘要： ITQ-25 (INSTITUTO DE TECNOLOGÍA QUÍMICA number 25) is a new crystalline microporous material with a framework of tetrahedral atoms connected by atoms capable of bridging the tetrahedral atoms, the tetrahedral atom framework being defined by the interconnections between the tetrahedrally coordinated atoms in its framework. ITQ-25 can be prepared in silicate compositions with a organic structure directing agent. It has a unique X-ray diffraction pattern, which identifies it as a new material. ITQ-25 is stable to calcination in air, absorbs hydrocarbons, and is catalytically active for hydrocarbon conversion.

摘要翻译： ITQ-25（INSTITUTO DETECNOLOGÍAQUÍMICA编号25）是一种新的结晶微孔材料，其四面体原子框架由能够桥接四面体原子的原子连接，四面体原子框架由其框架中的四面体配位原子之间的互连 。 可以用具有有机结构导向剂的硅酸盐组合物制备ITQ-25。 它具有独特的X射线衍射图，将其识别为新材料。 ITQ-25在空气中煅烧稳定，吸收碳氢化合物，对烃转化具有催化活性。

公开(公告)号：US06916459B2

公开(公告)日：2005-07-12

申请号：US10412624

申请日：2003-04-11

申请人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

发明人： Avelino Corma Canós ,  Maria Teresa Navarro Villalba ,  Fernando Rey García ,  Susana Valencia Valencia

IPC分类号： B01D53/86 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/10 ,  C01B39/02 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07B61/00 ,  C07C2/66 ,  C07C45/29 ,  C07C45/33 ,  C07C45/46 ,  C10G11/02 ,  C10G11/05 ,  C10G29/20 ,  C10G45/64 ,  C10G47/16

CPC分类号： C10G47/16 ,  B01J29/04 ,  B01J29/70 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  C01B39/023 ,  C01B39/06 ,  C01B39/08 ,  C01B39/12 ,  C01B39/48 ,  C07C2/66 ,  C07C45/29 ,  C07C45/294 ,  C07C45/33 ,  C07C45/46 ,  C10G11/05 ,  C10G29/205 ,  C10G45/64 ,  Y02C20/30 ,  Y02P20/52 ,  C07C15/085

摘要： This invention refers to a new zeolitic material included under the ITQ-16 denomination, to the method for obtaining them and their use as catalysts.This material, ITQ-16 zeolite, is characterized by having different ratios of the different polymorphs A, B and C described as possible intergrowths in Beta zeolite and which, therefore, show different X-ray diffraction patterns to that described for Beta zeolite, showing the X-ray diffraction pattern for ITQ-16, as it is synthesised, diffraction peaks at 2θ angles of 6.9°, 7.4°, and 9.6°, simultaneously.ITQ-16 zeolite in its calcinated form has the following empiric formula: x(M1/nXO2):tTO2:gGeO2:(1−g)SiO2 where T is one or various elements with +4 oxidation status, different of Ge and Si; X is one or various elements with +3 oxidation status and M can be H+ or one or various inorganic cations with charge +n, t is comprised between 0 and 0.1, g is comprised between 0.001 and 0.33 and x is comprised between 0 and 0.2.

摘要翻译： 本发明涉及包含在ITQ-16面额内的新型沸石材料，其获得方法及其作为催化剂的用途。 该材料，ITQ-16沸石的特征在于具有不同比例的不同的多晶型物A，B和C作为β沸石中可能的共生生长，因此与β沸石所述的X射线衍射图不同，显示出 合成了ITQ-16的X射线衍射图，同时在2θ角为6.9°，7.4°和9.6°的衍射峰。 其煅烧形式的ITQ-16沸石具有以下经验公式：<？in-line-formula description =“In-line Formulas”end =“lead”？> x（M 1 / n XO 2→2→1：gGeO 2：（1-g）SiO 2-β-in-in-line-2 公式描述=“在线公式”end =“tail”？>其中T是具有+4氧化状态，Ge和Si不同的一种或多种元素; X是具有+3氧化状态的一种或各种元素，M可以是H + +或一种或多种带电荷+ n的无机阳离子，t在0和0.1之间，g在0.001和0.33之间 并且x在0和0.2之间。

公开(公告)号：US06797254B2

公开(公告)日：2004-09-28

申请号：US10412115

申请日：2003-04-11

申请人： Avelino Corma Canos ,  María José Diaz Cabañas ,  Fernando Rey García

发明人： Avelino Corma Canos ,  María José Diaz Cabañas ,  Fernando Rey García

IPC分类号： C01B3948

CPC分类号： C01B39/12 ,  B01J29/04 ,  B01J29/70 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48

摘要： A microporous crystalline material of a zeolitic nature that, in a calcinated and anhydrous state, has a chemical composition represented by the formula: x(M1/nXO2):yYO2:zGeO2:(1−z)TO2 wherein x has a value below 0.2, y has a value below 0.1, z has a value below 1, with at least one of x, z and y being above zero; M is H+ or at least an inorganic cation with a +n charge; X is at least one chemical element with a +3 oxidation status; Y is at least one chemical element with a + oxidation status; and T is at least one chemical element with a +4 oxidation status (Si, Ti, Sn, V), this material having a specific X-ray diffraction pattern. A method for preparation of the material and its use as a catalyst in organic compound separation and transformation processes is also described.

摘要翻译： 沸石性质的微孔结晶材料，其在煅烧和无水状态下具有由下式表示的化学组成：其中x具有低于0.2的值，y具有低于0.1的值，z具有低于1的值，其中在 x，z和y中的至少一个高于零; M是H +或至少一个具有+ n电荷的无机阳离子; X是至少一种具有+3氧化状态的化学元素; Y是具有+氧化状态的至少一种化学元素; 并且T是具有+4氧化状态（Si，Ti，Sn，V）的至少一种化学元素，该材料具有特定的X射线衍射图。 还描述了用于制备材料的方法及其在有机化合物分离和转化过程中作为催化剂的用途。

公开(公告)号：US06211388B1

公开(公告)日：2001-04-03

申请号：US09414555

申请日：1999-10-08

申请人： Junpei Tsuji ,  Jun Yamamoto ,  Avelino Corma Canos ,  Fernando Rey Garcia

发明人： Junpei Tsuji ,  Jun Yamamoto ,  Avelino Corma Canos ,  Fernando Rey Garcia

IPC分类号： C07D30112

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1076 ,  B01J35/108 ,  Y02P20/52

摘要： A method for producing propylene oxide by reacting propylene with ethylbenzene hydroperoxide, wherein the reaction is conducted in the presence of a catalyst comprising a titanium-containing silicon oxide and satisfying all of the following conditions (1) to (6): (1) there is at least one peak showing a interplanar spacing (d) larger than 18 Å in X-ray diffraction; (2) an average pore size is 10 Å or more; (3) a pore size of 90% or more of the total pore volume is 5 to 200 Å; (4) a specific pore volume is 0.2 cm3/g or more; (5) a quaternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by calcination operation: [NR1R2R3R4]+  (I) wherein R1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms; and (6) The catalyst has been subjected to silylation treatment.

摘要翻译： 一种通过丙烯与氢过氧化苯反应生产环氧丙烷的方法，其中反应在包含含钛氧化硅的催化剂存在下进行，并满足以下所有条件（1）至（6）：（1） 是在X射线衍射中显示出大于18的晶面间距（d）的至少一个峰;（2）平均孔径为10埃以上;（3）总孔径的90％以上的孔径 体积为5〜200;（4）比孔体积为0.2cm 3 / g以上;（5）以下述通式（I）表示的季铵离子作为模板，将所述模板用 煅烧操作：其中R1表示具有2至36个碳原子的直链或支链烃链，R 2至R 4表示具有1至6个碳原子的烷基; 和（6）催化剂已进行甲硅烷基化处理。