摘要:
The invention relates to a process for the manufacture of noncellular polyurethane elastomers by reacting 4,4'-diisocyanato-1,2-diphenylethane or diisocyanato-1,2-diphenylethane isomer mixtures with a 4,4'-diisocyanato-1,2-diphenylethane content in excess of 95 percent by weight, higher molecular weight polyhydroxyl compounds and low molecular weight chain extenders optionally in the presence of auxiliaries and additives.The polyurethane elastomers produced in accordance with this invention excel by a greater hardness and improved mechanical properties compared with polyurethane elastomers based on 4,4'-diphenylmethane diisocyanate with otherwise comparable composition.
摘要:
The invention relates to a method for the preparation of cellular polyurethane elastomers with densities of approximately 250 to 800 grams per liter by reacting 4,4'-diisocyanato-1,2-diphenylethane or a diisocyanato-1,2-diphenylethane isomer mixture with a 4,4'-diisocyanato-1,2-diphenylethane content of more than 95 percent by weight with higher molecular weight polyhydroxyl compounds and water, as well as optionally chain extenders in the presence of auxiliaries and/or additives according to the one-shot or preferably the prepolymer method in closed molds.Compared with products based on 4,4'-diisocyanatodiphenylmethane, the polyurethane elastomer molded parts have improved physical and thermal properties.
摘要:
Polyurethane elastomers of improved heat stability are made by a process in which a polyisocyanate is reacted with a polyol of high molecular weight with an OH:NCO ratio of 1:0.66 to 1:0.85, and the resulting adduct is later reacted with an excess of symmetrical diisocyanate and a diol as chain extender.
摘要:
Polyurethane-urea elastomers with improved temperature characteristics, in particular improved low temperature properties, good mechanical properties over a large temperature range and excellent resistance to hydrolysis, are obtained by reacting(A) a prepolymer, possessing cycloaliphatic NCO groups, which has been prepared from essentially difunctional polyhydroxy compounds and organic diisocyanates possessing at least one NCO group bonded to a cycloaliphatic structure, these reactants being used so as to give a ratio of total hydroxyl: NCO groups of from 1:1.2 to 1:10, with(B) 3,3',5,5'-tetramethyl-4,4'-diamino-diphenylmethane, A and B being reacted in the molar ratio of from 1:0.8 to 1:1.2.
摘要:
A curable impact modified epoxy resin mixture suitable for producing high performance composites is composed ofA. an aromatic epoxy compound,B. an amine type curing agent,C. from 10 to 40% by weight of an aromatic thermoplastic oligomer which contains reactive groups, preferably a polyether sulfone, andD. from 0.1 to 10% by weight of a high molecular weight emulsifier, preferably a phenoxy resin, an epoxy resin or a thermoplastic copolymer, which is compatible not only with the epoxy compound A but also with oligomer C.
摘要:
Diisocyanates and isomeric mixtures of diisocyanates corresponding to the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, m and n are as defined herein are made by phosgenating diamines corresponding to the formula ##STR2## in which R.sub.1, R.sub.2, R.sub.3, m and n are as defined herein at a temperature of from -20.degree. to 250.degree. C. These diisocyanates are particularly useful as starting materials for the production of polyurethanes by the isocyanate polyaddition process.
摘要:
A process for the preparation of moldings, in particular resilient elements, which by virtue of a densified surface zone with substantially closed cells, have only a low water absorption, wherein a mixture comprising:(a) 100 parts by weight of an NCO-containing prepolymer, having an NCO content of from 3 to 6% by weight and based on organic diisocyanates and substantially linear polyester-polyols or polytetramethylene ether glycol,(b) from 0.5 to 1.6 parts by weight of water,(c) one or more catalysts, preferably a tertiary amine, in an amount of from 0.01 to 2.0 parts by weight and(d) assistants, with or without additives, is reacted in a closed mold, while undergoing densification, the surface temperature of the inner wall of the mold being from 50.degree. to 70.degree. C.
摘要:
Hard, rigid, non-elastomeric, non-cellular polyurethane compositions manufactured by reacting a liquid hydroxylic polyether having an OH equivalent weight of from 50 to 250, a monofunctional hydroxylic polyether having a molecular weight of from 150 to 10,000 and devoid of further functional groups which react with isocyanates, and an organic polyisocyanate, with or without catalysts, auxiliaries and additives.
摘要:
Fluid photo-crosslinkable composition consisting essentially of a photo-initiator and a mixture ofA. a polyurethane obtained by reacting a hydroxyl-containing saturated aliphatic polyester with a polyisocyanate and a monoacrylate or monomethacrylate of a diol, andB. an N-vinyl lactam optionally in admixture with other monomers.These compositions are suitable for the production of high-quality relief printing plates and have a short processing time.
摘要:
Isocyanates are produced by reaction of primary amines with phosgene in the gas phase. In this process, the reaction is terminated by guiding the reaction mixture from the reaction chamber through a cooling stretch into which liquids are injected. Direct cooling takes place in the cooling stretch in one stage in two or more cooling zones connected in series.