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172 条记录 (耗时 0.023 秒)

    Seeded emulsion polymerization of .alpha.-methylstyrene and acrylonitrile
    4.
    发明授权
    Seeded emulsion polymerization of .alpha.-methylstyrene and acrylonitrile 失效
    α-甲基苯乙烯和丙烯腈的接种乳液聚合

    公开(公告)号：US4920178A

    公开(公告)日：1990-04-24

    申请号：US312725

    申请日：1989-02-21

    申请人： Karl Zabrocki ,  Christian Lindner ,  Otto Koch ,  Hans-Eberhard Braese

    发明人： Karl Zabrocki ,  Christian Lindner ,  Otto Koch ,  Hans-Eberhard Braese

    IPC分类号： C08F212/10 ,  C08F2/26 ,  C08F20/42 ,  C08F212/00 ,  C08F220/44 ,  C08F257/02 ,  C08L27/06 ,  C08L51/00 ,  C08L55/02

    CPC分类号： C08F257/02 ,  C08L27/06 ,  C08L55/02 ,  C08L51/003

    摘要： An .alpha.-methylstyrene/acrylonitrile copolymer obtainable by emulsion polymerization which, in combination with other polymers, particularly PVC, enables alloys of outstanding thermal stability and color stability to be produced and, in addition, has a high heat distortion temperature and shows good fogging behavior and which is obtained by radically initiated inflow copolymerization of a mixture of 30 to 32 parts by weight acrylonitrile and 68 to 70 parts by weight .alpha.-methylstyrene in the presence of an emulsifier containing carboxyl groups. The polymerization is conducted in such a way that a seed latex of the same copolymer or of an analogous copolymer is introduced before addition of the monomers is commenced, the reaction temperature is kept between 75.degree. and 82.degree. C. and the molar ratio of emulsifier to initiator is between 4 and 6.

    摘要翻译： 可通过乳液聚合获得的α-甲基苯乙烯/丙烯腈共聚物，其与其它聚合物，特别是PVC组合使得能够产生出色的热稳定性和颜色稳定性的合金，并且另外具有高的热变形温度并且显示出良好的起雾行为 其通过在含有羧基的乳化剂存在下，通过30至32重量份丙烯腈和68至70重量份α-甲基苯乙烯的混合物的引发入流共聚而获得。 以这样的方式进行聚合，即在加入单体之前引入相同共聚物或类似共聚物的种子胶乳，反应温度保持在75-82℃，乳化剂的摩尔比 引发剂在4和6之间。

    Polymer mixtures of high ageing resistance
    5.
    发明授权
    Polymer mixtures of high ageing resistance 失效
    高耐老化聚合物混合物

    公开(公告)号：US5272205A

    公开(公告)日：1993-12-21

    申请号：US435056

    申请日：1989-11-13

    申请人： Herbert Eichenauer ,  Alfred Pischtschan ,  Christian Lindner

    发明人： Herbert Eichenauer ,  Alfred Pischtschan ,  Christian Lindner

    IPC分类号： C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L51/08

    CPC分类号： C08L51/04 ,  C08L51/085

    摘要： Molding compounds of(A) 5 to 95% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate silicone rubber with a mean particle diameter (d.sub.50) of from 0.10 to 0.50 .mu.m having a total rubber content of from 30 to 90% by weight and(B) 95 to 5% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate acrylate rubber with a mean particle diameter (d.sub.50) of from 0.05 to 1.00 .mu.m having a total rubber content of 30 to 80% by weight.

    摘要翻译： （A）5至95重量％的50至100重量份苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物和0至50重量份丙烯腈的混合物的接枝产物的成型化合物 平均粒径（d50）为0.10〜0.50μm，总橡胶含量为30〜90重量％的颗粒状硅橡胶，（B）95〜5重量％的 50至100重量份的苯乙烯，α-甲基苯乙烯，乙烯基甲苯，甲基丙烯酸甲酯或其混合物，以及0至50重量份的丙烯腈在平均粒径（d50）为0.05至1.00微米的丙烯酸甲酯橡胶上具有 总橡胶含量为30〜80重量％。

    Thermoplastic compositions of polyurethanes and partly crosslinked alkyl acrylate copolymers
    6.
    发明授权
    Thermoplastic compositions of polyurethanes and partly crosslinked alkyl acrylate copolymers 失效
    聚氨酯和部分交联丙烯酸酯共聚物的热塑性组合物

    公开(公告)号：US5237001A

    公开(公告)日：1993-08-17

    申请号：US713663

    申请日：1991-06-11

    申请人： Karl-Erwin Piejko ,  Ernst Orthmann ,  Christian Lindner ,  Hans-Eberhard Braese

    发明人： Karl-Erwin Piejko ,  Ernst Orthmann ,  Christian Lindner ,  Hans-Eberhard Braese

    IPC分类号： C08L25/14 ,  C08F265/04 ,  C08F279/04 ,  C08L33/04 ,  C08L33/06 ,  C08L73/00 ,  C08L75/00 ,  C08L75/04

    CPC分类号： C08F265/04 ,  C08F279/04 ,  C08L33/06 ,  C08L75/04

    摘要： The present invention is directed to a thermoplastic composition which is a blend of A) a thermoplastic polyurethane and B) an at least partly crosslinked alkyl acrylate copolymer of a C.sub.1-6 alkyl acrylate and a monomer selected from the group consisting of acrylonitrile, styrene, vinyl acetate, C.sub.1-6 alkyl methacrylates and mixtures thereof. The preferred compositions also contain copolymer selected from the group consisting ofC1) a thermoplastic graft product of a rubber component having a glass transition temperature below 0.degree. C., which serves as the graft base, and at least one graft monomer selected from the group consisting of styrene, .alpha.-methyl styrene, acrylonitrile an C.sub.1-6 alkyl methacrylate,C2) a rubber-free resin copolymer of styrene or .alpha.-methyl styrene with acrylonitrile,C3) mixtures thereof.

    摘要翻译： 本发明涉及一种热塑性组合物，其是A）热塑性聚氨酯和B）至少部分交联的丙烯酸C 1-6烷基酯与选自丙烯腈，苯乙烯， 乙酸乙烯酯，甲基丙烯酸C 1-6烷基酯及其混合物。 优选的组合物还包含共聚物，其选自C1）玻璃化转变温度低于0℃的橡胶组分的热塑性接枝产物，其用作接枝基质，和至少一种选自以下的接枝单体 由苯乙烯，α-甲基苯乙烯，丙烯腈和甲基丙烯酸C 1-6烷基酯组成，C2）苯乙烯或α-甲基苯乙烯与丙烯腈的无橡胶树脂共聚物，C3）其混合物。

    Mixtures of thermoplastic polymers in powder form
    8.
    发明授权
    Mixtures of thermoplastic polymers in powder form 失效
    粉末形式的热塑性聚合物的混合物

    公开(公告)号：US5112910A

    公开(公告)日：1992-05-12

    申请号：US743678

    申请日：1991-08-12

    申请人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    发明人： Karl-Erwin Piejko ,  Christian Lindner ,  Ralph Ostarek ,  Hans-Eberhard Braese ,  Karl-Heinz Ott

    IPC分类号： C08J3/00 ,  C08L21/00 ,  C08L25/12 ,  C08L33/06 ,  C08L33/12 ,  C08L51/04

    CPC分类号： C08L33/06 ,  C08J3/005 ,  C08L21/00 ,  C08L25/12 ,  C08L33/12 ,  C08L51/04

    摘要： Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.

    摘要翻译： 制备粉末形式的热塑性聚合物的混合物的方法，该方法由以下混合物的水性乳液制备：a）丙烯酸C 2 -C 8烷基酯和/或丁二烯与（基于共聚物）的至少40重量％的颗粒部分交联的橡胶状共聚物。 丙烯腈，苯乙烯或甲基丙烯酸C 1 -C 4烷基酯，b）热塑性树脂，如果合适，c）在二烯或烷基上的苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶，其橡胶含量为50〜95重量％ ％，其中a）和b）和如果合适的水性乳液c）具有15至50重量％的聚合物含量。 ％与凝固溶液同时混合，但在单独的流中，在20℃至100℃连续或半连续，聚合物a）和b），如果合适，c）凝结，将流合并，聚合物 混合物然后分离出来。