摘要:
Object of the invention is a process for the production of 4-nitroso diphenylamine wherein N-nitroso diphenylamine is rearranged in the presence of an alcoholic hydrogen chloride solution by selecting the reaction conditions in such a way that the hydrochloride of 4-nitroso diphenylamine remains dissolved in the reaction medium. In this way spontaneous, uncontrollable decompositions do not occur.
摘要:
In the preparation of 3,5-dichloro-.alpha.-methylstyrene by isopropylation of an m/p-dichlorobenzene mixture, isomerization of the resulting alkylation mixture, subsequent side chain bromination of the alkylation mixture and dehydrobromination of the resulting bromination mixture, the improvement which comprises reacting an excess of an m/p-dichlorobenzene mixture which contains at least 50% by weight of m-dichlorobenzene with isopropyl halide, isomerizing the resulting alkylation mixture under pressure in the presence of aluminum chloride until thermodynamic equilibrium has been attained, separating off the isomerized alkylation mixture from the unreacted m/p-dichlorobenzene mixture, and recycling the unreacted mixture for further reaction.
摘要:
2,4-Dichloro-3-alkyl-6-nitrophenols are prepared by chlorinating, with chlorine in the presence of a catalyst, 1-alkyl-4-nitrobenzenes having a C.sub.2 -C.sub.8 -alkyl radical until the content of trichloroalkylnitrobenzenes is at least 60% by weight in the chlorination mixture, removing the catalyst from the chlorination mixture, then hydrolyzing the chlorination mixture, removing the precipitated reaction product, and treating it with an aqueous inorganic acid. The 2,4-dichloro-3-alkyl-6-nitrophenols are new.
摘要:
3,5-Dichloro-.alpha.-methylstyrene is prepared from .alpha.-bromo-3,5-dichlorocumene by reaction with alkali metal hydroxide solutions in the presence of phase-transfer catalysts.
摘要:
Phenoxymethane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkoxy, halogenoalkyl, halogenoalkoxy, halogen, alkoxycarbonyl, cycloalkoxycarbonyl or nitro,R.sup.2 represents hydrogen, alkyl or halogen,R.sup.3 represents hydrogen, alkyl, alkenyl, alkinyl, phenyl which is optionally substituted by alkyl and/or halogen, phenylalkyl which is optionally substituted by alkyl and/or halogen, alkoxy, phenoxy, halogenoalkyl, halogenoalkoxy, alkylthio, halogenoalkylthio, alkylsulphonyl, phenylthio, phenylsulphonyl, nitro or halogen,R.sup.4 represents hydrogen, alkyl, halogen, cycloalkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, cycloalkylaminocarbonyl, di-cycloalkylaminocarbonyl, phenoxycarbonyl which is optionally substituted by halogen and/or alkyl, cyano or the radical of the formula --COOR,whereinR represents hydrogen, an alkali metal cation, one equivalent of an alkaline earth metal cation, alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or the radical of the formula --CH.sub.2 --O--(CH.sub.2 --CH.sub.2 --O).sub.q --AlkwhereinAlk represents alkyl andq represents 0, 1 or 2,m represents 1, 2 or 3,n represents 0, 1 or 2 andp represents 1, 2 or 3,are particularly suitable for regulating plant growth.
摘要:
The invention relates to a process for the preparation of 4-nitrodiphenylamines by the reaction of halogenonitrobenzenes with primary aromatic amines in the presence of copper or a copper compound, a neutralizing agent and a cyclic diaza compound.
摘要:
A dielectric composition comprising a mixture of monoisopropylated diphenyls and polyisopropylated diphenyls, especially a mixture of 30 to 60 parts by weight of monoisopropylated diphenyls and 70 to 40 parts by weight of polyisopropylated diphenyls, the polyisopropylated diphenyls preferably being made up in turn of 60 to 85 parts by weight of diisopropylated diphenyls, 10 to 35 parts by weight of triisopropylated diphenyls and 0.5 to 5 parts by weight of tetraisopropylated diphenyls, these latter amounts being based upon the total amount of the polyisopropylated diphenyls.
摘要:
In a process for the preparation of an aryloxyacetic acid by oxidation of aryloxyethanol of the formula ##STR1## wherein m represents 1 or 2,n represents the numeral which results from the difference (6-m) andR either individually or independently of one another represent hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, hydroxyl, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represent a benzene ring or cycloalkane ring fused to the phenyl ring,with oxygen or an oxygen-containing gas in an aqueous alkaline medium at a temperature from 0.degree. C. to the boiling point of the reaction mixture in the presence of platinum metals and/or palladium metals containing catalyst, the improvement which comprises carrying out the oxidation in the additional presence of an activator of lead and/or bismuth and/or a compound thereof and optionally in the additional presence of Cadmium and/or its compounds.
摘要:
3,3-Dimethylindan-5-yl N-alkyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is alkyl,R.sup.2 is hydrogen or alkyl, andR.sup.3 and R.sup.4 each independently is chlorine or alkyl, which possess fungicidal and arthropod development-inhibiting properties.