Process for the production of 4-nitroso-diphenylamine
    1.
    发明授权
    Process for the production of 4-nitroso-diphenylamine 失效
    生产4-亚硝基二苯胺的方法

    公开(公告)号:US4034042A

    公开(公告)日:1977-07-05

    申请号:US338219

    申请日:1973-03-05

    CPC分类号: C07C209/68 Y02P20/582

    摘要: Object of the invention is a process for the production of 4-nitroso diphenylamine wherein N-nitroso diphenylamine is rearranged in the presence of an alcoholic hydrogen chloride solution by selecting the reaction conditions in such a way that the hydrochloride of 4-nitroso diphenylamine remains dissolved in the reaction medium. In this way spontaneous, uncontrollable decompositions do not occur.

    摘要翻译: 本发明的目的是生产4-亚硝基二苯胺的方法,其中通过选择反应条件以使4-亚硝基二苯胺的盐酸盐保持溶解的方式,在含有醇的氯化氢溶液存在下重新排列N-亚硝基二苯胺 在反应介质中。 这样就不会发生自发的,不可控制的分解。

    Preparation of 2,4-dichloro-3-alkyl-6-nitrophenols
    3.
    发明授权
    Preparation of 2,4-dichloro-3-alkyl-6-nitrophenols 失效
    2,4-二氯-3-烷基-6-硝基苯酚的制备

    公开(公告)号:US4670608A

    公开(公告)日:1987-06-02

    申请号:US826710

    申请日:1986-03-19

    摘要: 2,4-Dichloro-3-alkyl-6-nitrophenols are prepared by chlorinating, with chlorine in the presence of a catalyst, 1-alkyl-4-nitrobenzenes having a C.sub.2 -C.sub.8 -alkyl radical until the content of trichloroalkylnitrobenzenes is at least 60% by weight in the chlorination mixture, removing the catalyst from the chlorination mixture, then hydrolyzing the chlorination mixture, removing the precipitated reaction product, and treating it with an aqueous inorganic acid. The 2,4-dichloro-3-alkyl-6-nitrophenols are new.

    摘要翻译: 2,4-二氯-3-烷基-6-硝基苯酚的制备方法是在催化剂存在下用氯氯化具有C 2 -C 8烷基的1-烷基-4-硝基苯,直到三氯烷基硝基苯的含量至少为 在氯化混合物中为60重量%,从氯化混合物中除去催化剂,然后水解氯化混合物,除去沉淀的反应产物,并用无机酸水溶液处理。 2,4-二氯-3-烷基-6-硝基苯酚是新的。

    Phenoxymethane derivatives for regulating plant growth
    6.
    发明授权
    Phenoxymethane derivatives for regulating plant growth 失效
    苯氧甲烷衍生物用于调节植物生长

    公开(公告)号:US4588433A

    公开(公告)日:1986-05-13

    申请号:US582121

    申请日:1984-02-21

    摘要: Phenoxymethane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkoxy, halogenoalkyl, halogenoalkoxy, halogen, alkoxycarbonyl, cycloalkoxycarbonyl or nitro,R.sup.2 represents hydrogen, alkyl or halogen,R.sup.3 represents hydrogen, alkyl, alkenyl, alkinyl, phenyl which is optionally substituted by alkyl and/or halogen, phenylalkyl which is optionally substituted by alkyl and/or halogen, alkoxy, phenoxy, halogenoalkyl, halogenoalkoxy, alkylthio, halogenoalkylthio, alkylsulphonyl, phenylthio, phenylsulphonyl, nitro or halogen,R.sup.4 represents hydrogen, alkyl, halogen, cycloalkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, cycloalkylaminocarbonyl, di-cycloalkylaminocarbonyl, phenoxycarbonyl which is optionally substituted by halogen and/or alkyl, cyano or the radical of the formula --COOR,whereinR represents hydrogen, an alkali metal cation, one equivalent of an alkaline earth metal cation, alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or the radical of the formula --CH.sub.2 --O--(CH.sub.2 --CH.sub.2 --O).sub.q --AlkwhereinAlk represents alkyl andq represents 0, 1 or 2,m represents 1, 2 or 3,n represents 0, 1 or 2 andp represents 1, 2 or 3,are particularly suitable for regulating plant growth.

    摘要翻译: 式(I)的苯氧基甲烷衍生物,其中R 1表示氢,烷基,烷氧基,卤代烷基,卤代烷氧基,卤素,烷氧基羰基,环烷氧基羰基或硝基,R 2表示氢,烷基或卤素,R 3表示氢,烷基,链烯基,炔基 烷氧基,苯氧基,卤代烷基,卤代烷氧基,烷硫基,卤代烷硫基,烷基磺酰基,苯硫基,苯基磺酰基,硝基或卤素,R4代表氢,烷基和/或卤素取代的苯基, 烷基,卤素,环烷氧基羰基,氨基羰基,烷基氨基羰基,二烷基氨基羰基,环烷基氨基羰基,二环烷基氨基羰基,任选被卤素和/或烷基,氰基或式-COOR基团取代的苯氧基羰基,其中R表示氢,碱金属阳离子 ,一当量的碱土金属阳离子,烷基,烯基,烷氧基烷基,烷硫基烷基或辐射 (CH 2 -CH 2 -O)q-Alk其中Alk表示烷基,q表示0,1或2,m表示1,2或3,n表示0,1或2,p表示 1,2或3,特别适用于调节植物生长。

    Impregnating agent and its use
    8.
    发明授权
    Impregnating agent and its use 失效
    浸渍剂及其用途

    公开(公告)号:US4294715A

    公开(公告)日:1981-10-13

    申请号:US83876

    申请日:1979-10-11

    CPC分类号: H01G4/221 H01B3/20 H01B3/22

    摘要: A dielectric composition comprising a mixture of monoisopropylated diphenyls and polyisopropylated diphenyls, especially a mixture of 30 to 60 parts by weight of monoisopropylated diphenyls and 70 to 40 parts by weight of polyisopropylated diphenyls, the polyisopropylated diphenyls preferably being made up in turn of 60 to 85 parts by weight of diisopropylated diphenyls, 10 to 35 parts by weight of triisopropylated diphenyls and 0.5 to 5 parts by weight of tetraisopropylated diphenyls, these latter amounts being based upon the total amount of the polyisopropylated diphenyls.

    摘要翻译: 一种包含单异丙基化二苯基醚和聚异丙基化二苯基醚的混合物的电介质组合物,特别是30至60重量份单异丙基化二苯基醚和70至40重量份聚异丙基化二苯基酯的混合物,该聚异丙基化二苯基优选依次为60至85 二异丙基化二苯基酯重量份,10〜35重量份三异丙基化二苯基醚和0.5〜5重量份四异丙基化二苯基醚,后者为聚异丙基化二苯基的总量。

    Process for the preparation of aryloxyacetic acid
    9.
    发明授权
    Process for the preparation of aryloxyacetic acid 失效
    制备芳氧基乙酸的方法

    公开(公告)号:US4238625A

    公开(公告)日:1980-12-09

    申请号:US092783

    申请日:1979-11-08

    CPC分类号: C07C51/255 C07C51/235

    摘要: In a process for the preparation of an aryloxyacetic acid by oxidation of aryloxyethanol of the formula ##STR1## wherein m represents 1 or 2,n represents the numeral which results from the difference (6-m) andR either individually or independently of one another represent hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, hydroxyl, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represent a benzene ring or cycloalkane ring fused to the phenyl ring,with oxygen or an oxygen-containing gas in an aqueous alkaline medium at a temperature from 0.degree. C. to the boiling point of the reaction mixture in the presence of platinum metals and/or palladium metals containing catalyst, the improvement which comprises carrying out the oxidation in the additional presence of an activator of lead and/or bismuth and/or a compound thereof and optionally in the additional presence of Cadmium and/or its compounds.

    摘要翻译: 在通过氧化式(I)的芳氧基乙醇制备芳氧基乙酸的方法中,其中m表示1或2,n表示由差异(6-m)和R单独或独立地产生的数字 代表氢,烷基,环烷基,芳基,芳烷基,烷氧基,环烷氧基,芳氧基,羟基,卤素,烷基羰基,芳基羰基,羧基或硝基,或代表与苯环稠合的苯环或环烷烃环, 含氧气体在含水碱性介质中,在铂金属和/或含钯金属的催化剂存在下,在0℃至该反应混合物的沸点的温度下,其改进包括在额外的 铅和/或铋和/或其化合物的活化剂的存在,并且任选地在镉和/或其化合物的另外存在下。