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    Fluorine-containing resin for preparing paint
    1.
    发明授权
    Fluorine-containing resin for preparing paint 失效
    用于制备涂料的含氟树脂

    公开(公告)号：US6166141A

    公开(公告)日：2000-12-26

    申请号：US873231

    申请日：1997-06-11

    申请人： Kazuhiko Maeda ,  Yukio Ikeda ,  Kentaro Tsutsumi ,  Seiji Hasegawa

    发明人： Kazuhiko Maeda ,  Yukio Ikeda ,  Kentaro Tsutsumi ,  Seiji Hasegawa

    IPC分类号： C08F259/08 ,  C08L51/00 ,  C09D127/16 ,  C09D151/00 ,  C08L27/12 ,  C08F214/18

    CPC分类号： C09D151/003 ,  C08F259/08 ,  C08L51/003 ,  C09D127/16 ,  C08L2666/24

    摘要： The invention relates to a fluorine-containing resin (graft copolymer) used for preparing a paint. This resin is prepared by a graft copolymerization of a fluorine-containing copolymer with a first monomer composition. The fluorine-containing copolymer comprises a first constitutional unit derived from a fluoroolefin and at least one of second and third constitutional units. The second constitutional unit is derived from a particular carboxylic acid vinyl ester represented by a general formula of R--C(.dbd.O)OCH.dbd.CH.sub.2 where R is a special group. The third constitutional unit is derived from a first monomer which is at least one compound selected from vinyl ethers and allyl ethers. The first monomer is represented by a general formula of R--O--(CH.sub.2)n--CH.dbd.CH.sub.2. The first monomer composition for preparing the resin contains a second monomer which is at least one compound selected from methacrylic acid esters and acrylic esters. The second monomer is represented by a general formula of CH.sub.2 .dbd.C(--R')C(.dbd.O)O--R where R' is hydrogen atom or methyl group. A composition prepared by mixing the resin with vinylidene fluoride resin or with a combination of vinylidene fluoride resin and acrylic resin is capable of providing a coated film having high gloss, high weather resistance, and good results in bending test for a long time. Another composition prepared by mixing the resin with a hardener is capable of providing a coated film having high hardness, good adhesion to various other coated films, high weather resistance, and high stain resistance.

    摘要翻译： 本发明涉及用于制备涂料的含氟树脂（接枝共聚物）。 该树脂通过含氟共聚物与第一单体组合物的接枝共聚而制备。 含氟共聚物包含衍生自氟代烯烃的第一结构单元和第二和第三结构单元中的至少一个。 第二结构单元衍生自由通式R-C（= O）OCH = CH 2表示的特定羧酸乙烯基酯，其中R是特殊基团。 第三结构单元衍生自作为至少一种选自乙烯基醚和烯丙基醚的化合物的第一单体。 第一单体由通式R-O-（CH 2）n -CH = CH 2表示。 用于制备树脂的第一单体组合物含有作为至少一种选自甲基丙烯酸酯和丙烯酸酯的化合物的第二单体。 第二单体由通式CH 2 = C（-R'）C（= O）O-R表示，其中R'是氢原子或甲基。 通过将树脂与偏氟乙烯树脂或偏二氟乙烯树脂和丙烯酸树脂的组合混合而制备的组合物能够提供长时间具有高光泽，高耐候性和良好的弯曲试验结果的涂膜。 通过将树脂与硬化剂混​​合而制备的另一组合物能够提供具有高硬度，对各种其它涂膜的良好粘附性，高耐候性和高耐污性的涂膜。

    Water-based fluorine-containing emulsion
    2.
    发明授权
    Water-based fluorine-containing emulsion 失效
    水性含氟乳液

    公开(公告)号：US5859123A

    公开(公告)日：1999-01-12

    申请号：US749698

    申请日：1996-11-15

    申请人： Satoru Kobayashi ,  Kazuhiko Maeda ,  Yoshi Hirashima ,  Seiji Hasegawa ,  Kentaro Tsutsumi

    发明人： Satoru Kobayashi ,  Kazuhiko Maeda ,  Yoshi Hirashima ,  Seiji Hasegawa ,  Kentaro Tsutsumi

    IPC分类号： C08F214/18 ,  C08F214/24 ,  C08F214/26 ,  C09D143/04 ,  C08L27/12

    CPC分类号： C08F214/18 ,  C08F214/245 ,  C08F214/265 ,  C09D143/04 ,  C08L2201/52

    摘要： The present invention relates to a water-based fluorine-containing emulsion. This emulsion contains a fluorine-containing copolymer in a disperse phase thereof This copolymer is prepared by copolymerizing: (A) a fluoroolefin, (B) an organosilicon compound containing an olefinic unsaturated bond and an alkoxysilyl group, (C) an unsaturated carboxylic acid represented by a general formula of CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --COOH where n is an integer of from 3 to 15, and (D) at least one other copolymerizable monomer. A paint prepared from the emulsion is superior in storage stability and mechanical stability, although this paint belongs to a one-package paint. A coated film formed by applying the paint is superior in water resistance in its early stages, stain resistance, and weather resistance.

    摘要翻译： 本发明涉及水性含氟乳液。 该乳液在分散相中含有含氟共聚物。该共聚物通过共聚以下物质制备：（A）氟烯烃，（B）含有烯属不饱和键的有机硅化合物和烷氧基甲硅烷基，（C）不饱和羧酸 通式为CH 2 = CH-（CH 2）n -COOH，其中n为3至15的整数，和（D）至少一种其它可共聚单体。 由乳液制备的油漆在储存稳定性和机械稳定性方面是优异的，尽管这种油漆属于单组分涂料。 通过涂覆涂料形成的涂膜在其早期的耐水性，耐污染性和耐候性方面都是优异的。

    Process for preparing aromatic urethanes
    5.
    发明授权
    Process for preparing aromatic urethanes 失效
    制备芳香族聚氨酯的方法

    公开(公告)号：US4227008A

    公开(公告)日：1980-10-07

    申请号：US927779

    申请日：1978-07-25

    申请人： Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    发明人： Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    IPC分类号： C07C271/06 ,  C07C125/04

    CPC分类号： C07C271/06

    摘要： Aromatic urethanes can be produced by interacting an aromatic primary amino compound having a nitro group, a nitroso group or a carbamate group, an organic compound having at least one hydroxyl group, and carbon monoxide in the presence of a catalytic system composed of a platinum group metal and/or a compound thereof serving as catalyst and a Lewis acid and/or a compound thereof as promoter under high temperature and high pressure conditions. For instance, the interaction of 2-amino-4-nitrotoluene, ethanol and carbon monoxide in the presence of palladium chloride and a ferrous chloride-pyridine complex under high temperature and high pressure conditions can yield 2,4-diethylcarbamatetoluene.

    摘要翻译： 芳族聚氨酯可以通过在具有硝基，亚硝基或氨基甲酸酯基团的芳族伯氨基化合物，具有至少一个羟基的有机化合物和一氧化碳的相互作用下，在由铂族组成的催化体系 金属和/或其化合物作为催化剂，路易斯酸和/或其化合物作为助催化剂在高温高压条件下进行。 例如，在氯化钯和氯化亚铁 - 吡啶络合物的存在下，在高温和高压条件下，2-氨基-4-硝基甲苯，乙醇和一氧化碳的相互作用可以产生2,4-二乙基氨基甲酸甲酯。

    Process for preparing aromatic urethanes
    8.
    发明授权
    Process for preparing aromatic urethanes 失效
    制备芳香族聚氨酯的方法

    公开(公告)号：US4178455A

    公开(公告)日：1979-12-11

    申请号：US925543

    申请日：1978-07-17

    申请人： Yutaka Hirai ,  Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    发明人： Yutaka Hirai ,  Katsuharu Miyata ,  Makoto Aiga ,  Seiji Hasegawa

    IPC分类号： C07C271/06 ,  C07C125/04

    CPC分类号： C07C271/06

    摘要： In a process for preparing an aromatic urethane which comprises reacting an aromatic nitro compound, an organic compound containing at least one hydroxyl group, and carbon monoxide at elevated temperature and pressure in the presence of a catalytic system composed of a catalyst consisting of a platinum metal, a platinum metal compound, and/or a platinum metal compound-containing compound and a promoter consisting of a Lewis acid and/or a Lewis acid-containing compound, an organic primary amino compound, a urea compound, a biuret compound, an allophanate compound, or a mixture thereof is added to the reaction system whereby the reaction rate is increased and the yield of the desired product is enhanced. For example, 2,4-diethylcarbamatetoluene can be prepared in quantitatively high yield by reacting 2,4-dinitrotoluene, ethanol, carbon monoxide, and a small amount of aminonitrotoluene at elevated temperature and pressure in the presence of palladium chloride and ferrous chloride-pyridine complex.

    摘要翻译： 在制备芳族氨基甲酸酯的方法中，包括使芳族硝基化合物，含有至少一个羟基的有机化合物和一氧化碳在升高的温度和压力下，在由铂金属 ，铂金属化合物和/或含铂金属化合物的化合物和由路易斯酸和/或路易斯酸化合物，有机伯氨基化合物，脲化合物，缩二脲化合物，脲基甲酸酯组成的促进剂 化合物或其混合物加入到反应体系中，由此提高反应速率并提高所需产物的产率。 例如，2,4-二乙基氨基甲酸甲酯可以通过在升高的温度和压力下，在氯化钯和氯化亚铁 - 吡啶存在下，使2,4-二硝基甲苯，乙醇，一氧化碳和少量的氨基硝基甲苯反应，以定量高的产率制备 复杂。

    Method for producing benzoic acid derivatives
    9.
    发明授权
    Method for producing benzoic acid derivatives 失效
    苯甲酸衍生物的制备方法

    公开(公告)号：US06268527B1

    公开(公告)日：2001-07-31

    申请号：US09452945

    申请日：1999-12-02

    申请人： Makoto Koide ,  Michio Ishida ,  Yuzuru Morino ,  Seiji Hasegawa ,  Satoru Narizuka ,  Takashi Kume

    发明人： Makoto Koide ,  Michio Ishida ,  Yuzuru Morino ,  Seiji Hasegawa ,  Satoru Narizuka ,  Takashi Kume

    IPC分类号： C07C5110

    CPC分类号： C07C51/10 ,  C07C63/70

    摘要： The invention relates to a method for producing a benzoic acid derivative represented by the general formula (1). The method includes the step of reacting an aromatic compound represented by the general formula (2), with carbon monoxide and a hydroxy compound (i.e., water or an alcohol), in the presence of (a) a metal compound containing a metal of 8, 9 and 10 groups of periodic table, (b) a first phosphine derivative represented by the general formula (R1)2P—Q—P(R1)2, and (c) a base, It is possible to easily and efficiently produce the benzoic acid derivative by the method.

    摘要翻译： 本发明涉及通式（1）表示的苯甲酸衍生物的制造方法。 该方法包括在（a）含有金属8的金属化合物的存在下使由通式（2）表示的芳族化合物与一氧化碳和羟基化合物（即水或醇）反应的步骤 ，9组和10组周期表，（b）由通式（R1）2P-QP（R1）2表示的第一膦衍生物和（c）碱，可以容易且有效地制备苯甲酸 衍生的方法。

    Low stress polyimide composition and precursor composition solution of same
    10.
    发明授权
    Low stress polyimide composition and precursor composition solution of same 失效
    低应力聚酰亚胺组合物和前体组合物溶液相同

    公开(公告)号：US5478918A

    公开(公告)日：1995-12-26

    申请号：US189774

    申请日：1994-02-01

    申请人： Masamichi Maruta ,  Hidehisa Nanai ,  Yoshihiro Moroi ,  Hiroshi Takahashi ,  Seiji Hasegawa

    发明人： Masamichi Maruta ,  Hidehisa Nanai ,  Yoshihiro Moroi ,  Hiroshi Takahashi ,  Seiji Hasegawa

    IPC分类号： C08G73/10 ,  C08G73/12 ,  C08L79/04 ,  C08L79/08

    CPC分类号： C08G73/106 ,  C08G73/1039 ,  C08G73/121 ,  C08L79/08 ,  C08L79/085

    摘要： A polyimide precursor composition solution includes a tetracarboxylic acid component containing not less than 70 mol % of at least one selected from the group consisting of benzenetetracarboxylic acid and its reactive derivatives; a maleimide compound; and a diamine component containing not less than 70 mol % of 2,2'-substituted-4,4'-benzidine represented by the general formula (I) and siloxydiamine amounting to from 1 to 10 mol %. The tetracarboxylic acid component, the maleimide compound and the diamine component are dissolved in a solvent which is consisting essentially of .gamma.-butyrolactone. The amount of the tetracarboxylic acid component is substantially equivalent to that of the diamine component. The amount of the maleimide compound is from 5 to 30 wt % of the total weight of the tetracarboxylic acid and the diamine component. A polyimide coating film prepared from the polyamide precursor solution is very low in residual stress and superior in adhesion to a substrate, has a very flat surface and can be desirably treated by wet etching process with an etching solution which is not hazardous. ##STR1## wherein R are the same or different ones selected from the group consisting of CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, OCH.sub.3, OC.sub.2 H.sub.5, Cl, Br and phenyl group.

    摘要翻译： 聚酰亚胺前体组合物溶液包括含有不少于70mol％的选自苯四甲酸及其活性衍生物中的至少一种的四羧酸组分; 马来酰亚胺化合物; 和含有不少于70摩尔％的由通式（I）表示的2,2'-取代-4,4'-联苯胺和1〜10摩尔％的硅氧酰胺的二胺成分。 将四羧酸组分，马来酰亚胺化合物和二胺组分溶解在基本上由γ-丁内酯组成的溶剂中。 四羧酸组分的量基本上等于二胺组分的量。 马来酰亚胺化合物的量为四羧酸和二胺成分总重量的5〜30重量％。 由聚酰胺前体溶液制备的聚酰亚胺涂膜的残留应力非常低，并且对基材的粘合性优异，具有非常平坦的表面，并且可以通过湿法蚀刻工艺优选用不危险的蚀刻溶液处理。 （I）其中R是选自CF 3，CH 3，C 2 H 5，OCH 3，OC 2 H 5，Cl，Br和苯基的相同或不同的基团。