公开(公告)号：US20050287415A1

公开(公告)日：2005-12-29

申请号：US11141287

申请日：2005-05-31

申请人： Kazuhito Hatoh ,  Teruhisa Kanbara ,  Soichi Shibata ,  Eiichi Yasumoto ,  Shigeyuki Unoki ,  Tatsuo Nagasaki ,  Masatoshi Teranishi ,  Tsutomu Kawashima ,  Toru Sukawa ,  Yasuo Takebe

发明人： Kazuhito Hatoh ,  Teruhisa Kanbara ,  Soichi Shibata ,  Eiichi Yasumoto ,  Shigeyuki Unoki ,  Tatsuo Nagasaki ,  Masatoshi Teranishi ,  Tsutomu Kawashima ,  Toru Sukawa ,  Yasuo Takebe

IPC分类号： G01N13/02 ,  H01M8/02 ,  H01M8/10

CPC分类号： H01M8/026 ,  G01N13/02 ,  G01N2013/0208 ,  H01M8/0213 ,  H01M8/0221 ,  H01M8/0226 ,  Y02P70/56

摘要： A separator for a polymer electrolyte fuel cell, which contains electrically conductive carbon and a binder that binds the electrically conductive carbon, comprises a reaction gas passage formed on at least a main surface thereof, wherein a water droplet falling angle of a surface the reaction gas passage is not less than 5 degrees and not more than 45 degrees when a water droplet of not less than 50 μL and not more than 80 μL is dropped under a condition in which ambient temperature is not lower than 50° C. and not higher than 90° C. and relative humidity is not less than 70% and not more than 100%.

摘要翻译： 含有导电性碳和粘合导电性碳的粘合剂的固体高分子型燃料电池用隔膜包括在至少其主面上形成的反应气体通路，其中反应气体的表面的水滴落角 当环境温度不低于50℃且不高于50℃的条件下，当不小于50微升且不超过80微升的水滴下降时，通道不得小于5度且不大于45度 90℃，相对湿度不小于70％且不大于100％。

公开(公告)号：US07220514B2

公开(公告)日：2007-05-22

申请号：US10335958

申请日：2003-01-03

申请人： Eiichi Yasumoto ,  Akihiko Yoshida ,  Makoto Uchida ,  Hisaaki Gyoten ,  Kazuhito Hatoh ,  Yasushi Sugawara ,  Junji Morita ,  Teruhisa Kanbara ,  Yasuo Takebe ,  Masato Hosaka ,  Junji Niikura

发明人： Eiichi Yasumoto ,  Akihiko Yoshida ,  Makoto Uchida ,  Hisaaki Gyoten ,  Kazuhito Hatoh ,  Yasushi Sugawara ,  Junji Morita ,  Teruhisa Kanbara ,  Yasuo Takebe ,  Masato Hosaka ,  Junji Niikura

IPC分类号： H01M4/96 ,  H01M8/10 ,  H01M4/88

CPC分类号： H01M4/8605 ,  H01M4/861 ,  H01M4/8814 ,  H01M4/8821 ,  H01M4/8828 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M2008/1095

摘要： In a polymer electrolyte fuel cell including a hydrogen ion conductive polymer electrolyte membrane; a pair of electrodes composed of catalyst layers sandwiching the hydrogen ion conductive polymer electrolyte membrane between them and gas diffusion layers in contact with the catalyst layers; a conductive separator plate having a gas flow channel for supplying a fuel gas to one of the electrodes; and a conductive separator plate having a gas flow channel for supplying an oxidant gas to the other electrode, in order to bring a hydrogen ion conductive polymer electrolyte and a catalyst metal of the catalyst layers containing the hydrogen ion conductive polymer electrolyte and conductive carbon particles carrying the catalyst metal sufficiently and uniformly into contact with each other, the polymer electrolyte is provided in pores of an agglomerate structure of the conductive carbon particles. Consequently, the reaction area inside the electrodes is increased, and higher performance is exhibited.

摘要翻译： 在具有氢离子导电性高分子电解质膜的固体高分子型燃料电池中， 由催化剂层构成的一对电极，夹在其间的氢离子导电性高分子电解质膜和与催化剂层接触的气体扩散层; 具有用于将燃料气体供给到所述电极之一的气体流路的导电性隔板; 以及具有用于向另一个电极供给氧化剂气体的气体流动通道的导电隔板，以便使氢离子导电聚合物电解质和含有氢离子导电聚合物电解质的催化剂层和催化剂层的催化剂金属携带 催化剂金属彼此充分均匀地接触，聚合物电解质被提供在导电碳颗粒的附聚结构的孔中。 因此，电极内的反应区域增加，表现出更高的性能。

公开(公告)号：US20050100780A1

公开(公告)日：2005-05-12

申请号：US10981530

申请日：2004-11-05

申请人： Shigeyuki Unoki ,  Teruhisa Kanbara ,  Eiichi Yasumoto ,  Hisaaki Gyoten ,  Yasuo Takebe ,  Yasuhiro Seki

发明人： Shigeyuki Unoki ,  Teruhisa Kanbara ,  Eiichi Yasumoto ,  Hisaaki Gyoten ,  Yasuo Takebe ,  Yasuhiro Seki

IPC分类号： H01M8/02 ,  H01M8/04 ,  H01M8/10 ,  H01M4/94

CPC分类号： H01M8/026 ,  H01M8/023 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0245 ,  H01M8/04126 ,  H01M8/04179 ,  H01M8/04291 ,  H01M8/1007 ,  H01M2008/1095

摘要： A fuel cell includes an electrolyte membrane, a pair of anode-side and cathode-side catalyst layers, a pair of an anode gas diffusion layer and a cathode gas diffusion layer, and a pair of an anode-side separator and a cathode-side separator. Also adjusted in the fuel cell is at least one of a fine pore diameter and a content of a water repellent agent in the anode gas diffusion layer and the cathode gas diffusion layer, so as to satisfy the following equation (1): −0.07≦(Ya−Xa)/((Ya−Xa)+(Yc−Xc))≦0.15  (1) wherein Xa represents a water feeding amount in the fuel gas thus fed, Ya represents a water discharging amount in the discharged fuel gas, Xc represents a water feeding amount in the oxidizing gas thus fed, and Yc represents a water discharging amount in the discharged oxidizing gas.

摘要翻译： 燃料电池包括电解质膜，一对阳极侧和阴极侧催化剂层，一对阳极气体扩散层和阴极气体扩散层，以及一对阳极侧隔板和阴极侧 分隔器。 在燃料电池中也调整为在阳极气体扩散层和阴极气体扩散层中的细孔径和防水剂的含量中的至少一个，以满足下式（1）：<α -line-formula description =“In-line Formulas”end =“lead”？> - 0.07 <=（Ya-Xa）/（（Ya-Xa）+（Yc-Xc））<= 0.15（1） in-line-formula description =“In-line Formulas”end =“tail”？>其中Xa表示如此供给的燃料气体中的给水量，Ya表示排出的燃料气体中的排水量，Xc表示水 所供给的氧化气体的供给量，Yc表示排出的氧化气体中的排水量。

公开(公告)号：US06746793B1

公开(公告)日：2004-06-08

申请号：US09719664

申请日：2000-12-15

申请人： Hisaaki Gyoten ,  Eiichi Yasumoto ,  Kazuhito Hatoh ,  Makoto Uchida ,  Yasushi Sugawara ,  Teruhisa Kanbara ,  Junji Morita ,  Hideo Ohara ,  Kazufumi Nishida ,  Osamu Sakai ,  Yukiyoshi Ono ,  Yasuo Takebe

发明人： Hisaaki Gyoten ,  Eiichi Yasumoto ,  Kazuhito Hatoh ,  Makoto Uchida ,  Yasushi Sugawara ,  Teruhisa Kanbara ,  Junji Morita ,  Hideo Ohara ,  Kazufumi Nishida ,  Osamu Sakai ,  Yukiyoshi Ono ,  Yasuo Takebe

IPC分类号： H01M802

CPC分类号： H01M4/8642 ,  H01M4/8605 ,  H01M4/926 ,  H01M8/1004 ,  H01M2300/0082

摘要： The polymer electrolyte fuel cell of the present invention exhibits an excellent performance with an efficient electrode reaction; by providing a layer comprising an electroconductive fine particle between the catalytic reaction layer and the gas diffusion layer in the electrodes; by providing a hydrogen ion diffusion layer on at least either surface of the catalyst particle or the carrier, which carries the catalyst particle in the catalytic reaction layer; or by constituting the catalytic reaction layer with at least a catalyst comprising a hydrophilic carbon material with catalyst particles carried thereon and a water repellent carbon material.

摘要翻译： 本发明的高分子电解质型燃料电池具有优异的电极反应性能， 通过在催化反应层和电极中的气体扩散层之间提供包含导电细颗粒的层; 通过在催化剂颗粒或载体的至少任一个表面上提供氢离子扩散层，其在催化反应层中承载催化剂颗粒; 或者通过使至少包含亲水性碳材料的催化剂与承载有催化剂颗粒的催化反应层和防水性碳材料构成。

公开(公告)号：US06660424B1

公开(公告)日：2003-12-09

申请号：US09763263

申请日：2001-02-20

申请人： Hisaaki Gyoten ,  Eiichi Yasumoto ,  Makoto Uchida ,  Yasushi Sugawara ,  Kazufumi Nishida ,  Kazuhito Hatoh ,  Yukiyoshi Ono ,  Hideo Ohara ,  Junji Morita ,  Yasuo Takebe ,  Teruhisa Kanbara ,  Osamu Sakai

发明人： Hisaaki Gyoten ,  Eiichi Yasumoto ,  Makoto Uchida ,  Yasushi Sugawara ,  Kazufumi Nishida ,  Kazuhito Hatoh ,  Yukiyoshi Ono ,  Hideo Ohara ,  Junji Morita ,  Yasuo Takebe ,  Teruhisa Kanbara ,  Osamu Sakai

IPC分类号： H01M214

CPC分类号： H01M8/0221 ,  H01M8/0223 ,  H01M8/0239 ,  H01M8/0241 ,  H01M8/1004 ,  H01M8/1007 ,  H01M8/2404 ,  H01M8/241 ,  H01M8/2457 ,  H01M2300/0082 ,  Y02P70/56 ,  Y10T29/49115

摘要： The specification discloses a fuel cell comprising stacked unit cells, each of the unit cells including a pair of electrodes having a catalytic reaction layer and a gas diffusion layer, an electrolyte layer disposed between the pair of electrodes, a separator having a flow path for supplying a fuel gas to one electrode and a separator having a flow path for supplying an oxidant gas to the other electrode, the separators being placed on the outer side of the electrodes and the unit cells being stacked with the separators placed therebetween, wherein at least the catalytic reaction layer, the gas diffusion layer or the flow path has water-repelling properties. Thereby, a fuel cell having a superior cell performance is obtained.

摘要翻译： 本说明书公开了一种燃料电池，其包括堆叠的单元电池，每个单元电池包括具有催化反应层和气体扩散层的一对电极，设置在该对电极之间的电解质层，具有用于供给的流路的隔板 一个电极的燃料气体和一个具有用于向另一个电极供应氧化剂气体的流动路径的隔板，隔板被放置在电极的外侧上，并且单元电池被堆叠在一起，隔板之间放置有至少 催化反应层，气体扩散层或流路具有防水性。 由此，获得具有优异的电池性能的燃料电池。

公开(公告)号：US07943261B2

公开(公告)日：2011-05-17

申请号：US10696505

申请日：2003-10-30

申请人： Yasuo Takebe ,  Kazuhito Hatoh ,  Hiroki Kusakabe ,  Teruhisa Kanbara ,  Makoto Uchida ,  Shinya Kosako ,  Yoichiro Tsuji ,  Yasushi Sugawara

发明人： Yasuo Takebe ,  Kazuhito Hatoh ,  Hiroki Kusakabe ,  Teruhisa Kanbara ,  Makoto Uchida ,  Shinya Kosako ,  Yoichiro Tsuji ,  Yasushi Sugawara

IPC分类号： H01M8/04

CPC分类号： H01M8/0488 ,  H01M8/0271 ,  H01M8/04082 ,  H01M8/04223 ,  H01M8/04231 ,  H01M8/04302 ,  H01M8/04303 ,  H01M8/04365 ,  H01M8/04559 ,  H01M8/04753 ,  H01M8/0494 ,  H01M2008/1095

摘要： A method of operating a fuel cell capable of suppressing degradation of a fuel cell caused by starting and stopping of the fuel cell, including carrying out a restoring operation by decreasing a voltage of the cathode following termination of the fuel cell.

摘要翻译： 一种操作燃料电池的方法，该燃料电池能够抑制燃料电池的启动和停止引起的燃料电池的劣化，包括通过在燃料电池终止之后降低阴极的电压来进行恢复操作。

公开(公告)号：US06855178B2

公开(公告)日：2005-02-15

申请号：US10069459

申请日：2001-07-05

申请人： Makoto Uchida ,  Junji Niikura ,  Hisaaki Gyoten ,  Yasuo Takebe ,  Kazuhito Hatoh ,  Masato Hosaka ,  Teruhisa Kanbara ,  Atsushi Mukoyama ,  Hiroshi Shimoda ,  Shinji Kinoshita

发明人： Makoto Uchida ,  Junji Niikura ,  Hisaaki Gyoten ,  Yasuo Takebe ,  Kazuhito Hatoh ,  Masato Hosaka ,  Teruhisa Kanbara ,  Atsushi Mukoyama ,  Hiroshi Shimoda ,  Shinji Kinoshita

IPC分类号： H01M4/88 ,  H01M8/10 ,  H01M6/00

CPC分类号： H01M8/1004 ,  H01M4/8828 ,  Y02P70/56 ,  Y10T29/49115

摘要： A method for producing a membrane electrode assembly 1 for solid polymer electrolyte fuel cell, the membrane electrode assembly 1 including a solid polymer electrolyte membrane 2 comprising an ion exchange membrane, a first electrode 3 having a first catalyst layer 31, and a second electrode 4 having a second catalyst layer 41, the first electrode 3 and the second electrode 4 being disposed so as to be opposed to each other via the ion exchange membrane, the method including: applying a coating solution containing a catalyst onto a base film 101 to form a first catalyst layer 31; applying a coating solution containing an ion exchange resin dissolved or dispersed in a liquid onto the first catalyst layer 31 to form an ion exchange membrane; then applying a coating solution containing a catalyst onto the ion exchange membrane to form a second catalyst layer 41; and finally, peeling off the base film 101 from a resulting laminate. According to this method, it is possible to produce membrane electrode assembly 1 for high-performance solid polymer electrolyte fuel cell having catalyst layers each having a uniform thickness efficiently and continuously.

摘要翻译： 一种固体聚合物电解质燃料电池用的膜电极接合体1的制造方法，该膜电极接合体1包括固体高分子电解质膜2，该固体高分子电解质膜2具有离子交换膜，具有第一催化剂层31的第一电极3和第二电极4 具有第二催化剂层41，第一电极3和第二电极4经由离子交换膜彼此相对配置，该方法包括：将含有催化剂的涂布溶液涂布在基膜101上以形成 第一催化剂层31; 将含有溶解或分散在液体中的离子交换树脂的涂布溶液涂布到第一催化剂层31上以形成离子交换膜; 然后将含有催化剂的涂布溶液涂布到离子交换膜上以形成第二催化剂层41; 最后，从得到的层叠体剥离基膜101。 根据该方法，可以有效且连续地制造具有均匀厚度的催化剂层的高性能固体高分子电解质型燃料电池用膜电极接合体1。

公开(公告)号：US07494737B2

公开(公告)日：2009-02-24

申请号：US11296688

申请日：2005-12-08

申请人： Shinichi Arisaka ,  Yasuo Takebe ,  Hideo Ohara ,  Kazuhito Hatoh ,  Eiichi Yasumoto

发明人： Shinichi Arisaka ,  Yasuo Takebe ,  Hideo Ohara ,  Kazuhito Hatoh ,  Eiichi Yasumoto

IPC分类号： H01M2/14 ,  H01M8/10

CPC分类号： H01M8/0247 ,  H01M8/0256 ,  H01M8/1007

摘要： The present invention is intended to enable efficient assembly of a fuel cell stack without causing any damage to the conductive separator. In a fuel cell including an anode, a cathode, an electrolyte membrane interposed between the anode and the cathode, and conductive separators each having manifold apertures 12 and a flow channel 16 for supplying a gas to the anode or the cathode, manifold aperture connecting portions 15 are formed at an inlet-side end and an outlet-side end of the flow channel 16, respectively. Each of the manifold aperture connecting portions 15 is recessed below the upper surface of the conductive separator 11. Cover plates are fitted and fixed to the recessed portions, respectively.

摘要翻译： 本发明旨在使得能够有效地组装燃料电池堆而不会对导电隔板造成任何损坏。 在包括阳极，阴极，插在阳极和阴极之间的电解质膜的燃料电池中，以及各自具有歧管孔12和用于向阳极或阴极供给气体的流路16的导电隔板，歧管孔连接部 15分别形成在流路16的入口侧端部和出口侧端部。 歧管孔连接部15中的每一个在导电性隔板11的上表面下方凹陷。盖板分别嵌合固定在凹部上。

公开(公告)号：US20070134541A1

公开(公告)日：2007-06-14

申请号：US11296688

申请日：2005-12-08

申请人： Shinichi Arisaka ,  Yasuo Takebe ,  Hideo Ohara ,  Kazuhito Hatoh ,  Eiichi Yasumoto

发明人： Shinichi Arisaka ,  Yasuo Takebe ,  Hideo Ohara ,  Kazuhito Hatoh ,  Eiichi Yasumoto

IPC分类号： H01M8/02 ,  H01M8/10

CPC分类号： H01M8/0247 ,  H01M8/0256 ,  H01M8/1007

摘要： The present invention is intended to enable efficient assembly of a fuel cell stack without causing any damage to the conductive separator. In a fuel cell including an anode, a cathode, an electrolyte membrane interposed between the anode and the cathode, and conductive separators each having manifold apertures 12 and a flow channel 16 for supplying a gas to the anode or the cathode, manifold aperture connecting portions 15 are formed at an inlet-side end and an outlet-side end of the flow channel 16, respectively. Each of the manifold aperture connecting portions 15 is recessed below the upper surface of the conductive separator 11. Cover plates are fitted and fixed to the recessed portions, respectively.

摘要翻译： 本发明旨在使得能够有效地组装燃料电池堆而不会对导电隔板造成任何损坏。 在包括阳极，阴极，插在阳极和阴极之间的电解质膜的燃料电池中，以及各自具有歧管孔12和用于向阳极或阴极供给气体的流路16的导电隔板，歧管孔连接部 15分别形成在流路16的入口侧端部和出口侧端部。 每个歧管孔连接部15在导电性隔离体11的上表面下方凹陷。 盖板分别安装并固定到凹部。

公开(公告)号：US20050064252A1

公开(公告)日：2005-03-24

申请号：US10825217

申请日：2004-04-16

申请人： Hiroki Kusakabe ,  Kazuhito Hatoh ,  Hideo Ohara ,  Shinsuke Takeguchi ,  Soichi Shibata ,  Shinichi Arisaka ,  Yasuo Takebe

发明人： Hiroki Kusakabe ,  Kazuhito Hatoh ,  Hideo Ohara ,  Shinsuke Takeguchi ,  Soichi Shibata ,  Shinichi Arisaka ,  Yasuo Takebe

IPC分类号： H01M8/00 ,  H01M8/02 ,  H01M8/04 ,  H01M8/10 ,  H01M10/42

CPC分类号： H01M8/04089 ,  H01M8/04552 ,  H01M8/04671 ,  H01M8/1007

摘要： A method for easily, quickly and accurately detecting a cross leak or a micro short-circuit in a unit cell or group of cells of a fuel cell stack is provided by determining an electric output of the unit cell or group of cells after stoppage of fuel and/or oxidant and preferably during the introduction of a non-fuel and non-oxidant gas to the cell.

摘要翻译： 通过在停止燃料之后确定单元电池或电池组的电输出来提供用于容易，快速和准确地检测燃料电池堆的单体电池或电池组中的交叉泄漏或微短路的方法 和/或氧化剂，优选在将非燃料和非氧化剂气体引入电池期间。