摘要:
A resin composition containing (A) a thermoplastic polyurethane; (B) a polymer having a hydroxyl group at the end of the molecular main chain, the main chain principally comprising a conjugated diene compound unit (I) which may or may not be hydrogenated and an aromatic vinyl compound unit (II); and (C) a polyacetal resin, at ratios of (A), (B) and (C) being 2.5 to 90% by weight, 2.5 to 90% by weight and 5 to 95% by weight, respectively, on the basis of the total weight of the (A), (B) and (C), is excellent in terms of tensile strength and tensile elongation, and impact resistance at ambient temperature and lower temperatures.
摘要:
The present invention provides an adhesive composition containing a block copolymer, wherein the block copolymer has a polymer block (A) which is principally composed of a &agr;-methyl styrene unit, and a polymer block (B) which is principally composed of a conjugated diene unit and of which at least part of carbon-carbon unsaturated double bonds may be hydrogenated, and having a good holding power at high temperatures.
摘要:
The present invention provides an adhesive composition containing a block copolymer, wherein the block copolymer has a polymer block (A) which is principally composed of a α-methyl styrene unit, and a polymer block (B) which is principally composed of a conjugated diene unit and of which at least part of carbon-carbon unsaturated double bonds may be hydrogenated, and having a good holding power at high temperatures.
摘要:
The present invention provides an adhesive composition containing a block copolymer, wherein the block copolymer has a polymer block (A) which is principally composed of a α-methyl styrene unit, and a polymer block (B) which is principally composed of a conjugated diene unit and of which at least part of carbon-carbon unsaturated double bonds may be hydrogenated, and having a good holding power at high temperatures.
摘要:
A thermoplastic polymer composition is provided that includes 100 parts by weight of a block copolymer and/or its hydrogenate having polymer blocks of an aromatic vinyl compound and polymer blocks of a conjugated diene compound, and from 5 to 95 parts by weight of a block copolymer having polymer blocks of an aromatic vinyl compound and/or an olefinic compound and polymer blocks having a constitutional unit derived from a (meth) acrylic compound, a laminate containing a layer of the composition, and a hot-melt adhesive that includes the composition. Because it has good melt adhesiveness, the composition of the invention can firmly adhere in melt to various polar or non-polar materials. Using the composition, it is easy to produce laminates having a layer of the composition and a layer of some other material, through melt shaping or any other melt adhesion techniques. Since the composition of the invention is satisfactorily elastic and flexible, the laminates having a layer of the composition on their surface are flexible and elastic and have a good feel, and, in addition, they are safe because of their shock absorbability and cushionability.
摘要:
Herein disclosed are a block copolymer having an isobutylene-based polymer block and a vinylic aromatic hydrocarbon-based polymer block and containing a styrenic unit having a halogenated saturated aliphatic hydrocarbon group on the benzene ring at 0.01 to 2 mol % on a basis of the total structural units and being capable of markedly improving the performance of a synthetic resin when the block copolymer is blended with the synthetic resin; a process for producing the block copolymer; and a resin composition position containing the block copolymer.
摘要:
A closure or sealing element for containers, comprising a resin composition principally composed of a polyolefin resin (A) and a block copolymer (B) of a polymer block of an aromatic vinyl compound and an isobutylenic polymer block at a (A)/(B) weigh ratio within a range of 100/5 to 100/100, has so suitable pliability and excellent thermal resistance, good gas barrier properties and great oil resistance, that the closure or sealing element has good mountability onto (into) containers and excellent sealing properties of the containers in addition to good long-term shelf stability of the contents.
摘要:
A resin composition comprising (A) a polyolefin resin, (B) a vinyl alcohol copolymer and (C′) a block copolymer composed of a polymer block of an aromatic vinyl compound and an isobutylenic polymer block, the weight ratio of (A) to (B) ranging from 100/10 to 100/1000 and the weight ratio of (C′) to [(A)+(B)] ranging from 5/100 to 1000/100 is a flexible resin material having high gas barrier properties, good heat resistance and good moldability or formability so that it is useful as a material for various molded or formed articles. In addition, a closure (cap, stopper or the like) for containers or a sealing element (packing element) for the closure for containers which is formed of a resin composition comprising (A) a polyolefin resin, (B) a vinyl alcohol copolymer and (C) an elastomer, the weight ratio of (A) to (B) ranging from 100/10 to 100/1000 and the weight ratio of (C) to [(A)+(B)] ranging from 5/100 to 100/100 has good hermetical sealing properties and good mountability onto (or within) a container and is also excellent in the long-term shelf stability of contents.
摘要:
A process for the hydrogenation of conjugated diene polymers having alcoholic hydroxyl groups, is provided. In the process, reduced nickel is used as a catalyst and an ether or a mixture of an ether and a hydrocarbon is used as a solvent for the hydrogenation reaction whereby elimination of the group rarely occurs with a very high hydrogenation rate being attained.
摘要:
Pressure-sensitive adhesives for optical films exhibit high cohesion, excellent re-workability, adhesion properties, heat resistance and durability without chemical crosslinking.A pressure-sensitive adhesive contains an acrylic triblock copolymer (I) at not less than 60% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive, the acrylic triblock copolymer being represented by the formula A1-B-A2 wherein: A1 and A2 are each independently an alkyl methacrylate polymer block having Tg of not less than 100° C. and B is an acryl acrylate polymer block having Tg of not more than −20° C.; the content of the polymer block B is 50 to 95% by mass; Mw is in the range of 50,000 to 300,000; and the molecular weight distribution is in the range of 1.0 to 1.5. In a preferred embodiment, the acrylic triblock copolymer (I) is a combination of an acrylic triblock copolymer (Ia) having Mw of 50,000 to less than 100,000 and an acrylic triblock copolymer (Ib) having Mw of 100,000 to 300,000, in a mass ratio (Ia):(Ib) of 45:55 to 75:25.