公开(公告)号：US4518746A

公开(公告)日：1985-05-21

申请号：US589728

申请日：1984-03-15

申请人： Kazys Sekmakas ,  Raj Shah ,  Ronald J. Lewarchik ,  Kevin P. Murray

发明人： Kazys Sekmakas ,  Raj Shah ,  Ronald J. Lewarchik ,  Kevin P. Murray

IPC分类号： C08G63/183 ,  C09D167/02 ,  C08L61/28

CPC分类号： C08G63/183 ,  C09D167/02 ,  Y10T428/31681 ,  Y10T428/31688 ,  Y10T428/31786

摘要： An essentially linear polyester oligomer having hydroxyl and carboxyl terminal groups for subsequent cure and its production are disclosed. This polyester oligomer is produced by first adducting approximately equimolar amounts of diol carrying two primary hydroxyl groups and a dicarboxylic acid anhydride to form an hydroxy acid. The carboxyl groups of this hydroxy acid are then esterified by reaction with an approximately stoichiometric proportion of diol carrying one primary hydroxyl group and one secondary hydroxyl group, the stoichiometry being based on the total hydroxyl content of the diol and the carboxyl content of the hydroxy acid, to form an hydroxyl-terminated oligomer. This hydroxyl-terminated oligomer is then adducted with a polycarboxylic acid monoanhydride having a carboxyl functionality of at least 3, this monoanhydride being used in an amount of 0.01 to 0.15 equivalents of anhydride per hydroxyl equivalent in the hydroxyl-terminated oligomer. The resulting polyester oligomer is essentially linear and possesses low solution viscosity at high resin solids content combined with high reactivity enabling low temperature cure with aminoplast resins.

摘要翻译： 公开了具有用于随后固化的羟基和羧基端基及其生产的基本上线性的聚酯低聚物。 该聚酯低聚物通过首先加入大约等摩尔量的带有两个伯羟基的二醇和二羧酸酐形成羟基酸来制备。 然后通过与大约化学计量比例的带有一个伯羟基和一个仲羟基的二醇反应将该羟基酸的羧基酯化，化学计量是基于二醇的总羟基含量和羟基酸的羧基含量 ，以形成羟基封端的低聚物。 然后将该羟基封端的低聚物与羧基官能度至少为3的多元羧酸单酸酐加成，该单酸酐的用量为羟基封端低聚物中羟基当量的0.01至0.15当量酐。 所得的聚酯低聚物基本上是线性的，并且在高树脂固体含量下具有低溶液粘度，并且具有高反应性，能够用氨基塑料树脂进行低温固化。

公开(公告)号：US4526939A

公开(公告)日：1985-07-02

申请号：US515029

申请日：1983-07-18

申请人： Ronald J. Lewarchik ,  Kevin P. Murray ,  Marcella G. Donovan ,  Arthur T. Jones

发明人： Ronald J. Lewarchik ,  Kevin P. Murray ,  Marcella G. Donovan ,  Arthur T. Jones

IPC分类号： C08J7/04 ,  C08G18/40 ,  C08G18/64 ,  C08G18/80 ,  C08G59/16 ,  C08G63/181 ,  C09D163/00 ,  C09D163/10 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C08L67/02

CPC分类号： C09D163/10 ,  C08G18/4081 ,  C08G18/6407 ,  C08G18/8064 ,  C08G59/1455 ,  C08G63/181 ,  C09D167/02 ,  Y10S525/922 ,  Y10T428/31511 ,  Y10T428/31525 ,  Y10T428/31786

摘要： High solids thermosetting organic solvent solution coating compositions are disclosed which are particularly useful for sealing the pores in fiber reinforced plastics. These compositions contain a mixture of resins comprising (1) from 30% to 70% of one or more hydroxy functional resins having a number average molecular weight of at least about 700, a Gardner bubble viscosity less than about Z.sub.4 measured in methyl ethyl ketone at 90% solids at 25.degree. C., and at least 5% of the hydroxy groups thereof being primary hydroxy groups, (2) from 10% to 70% of low molecular weight epoxy ester made by esterifying one or more resinous polyepoxides having a 1,2-epoxy equivalency of at least 1.2 with an approximately stoichiometric proportion of monocarboxylic fatty acid to provide an essentially epoxy-free ester having a Gardner bubble viscosity less than Z.sub.4 at 75% solids in xylol at 25.degree. C., and (3) the balance of the mixture, but not less than 15% thereof, being a curing agent having a plurality of groups reactive with the hydroxy groups in the hydroxy resin and in the epoxy ester.

摘要翻译： 公开了高固含量的热固性有机溶剂溶液涂料组合物，其特别用于密封纤维增强塑料中的孔隙。 这些组合物包含树脂混合物，其包含（1）30％至70％的一种或多种数均分子量为至少约700的羟基官能树脂，在甲基乙基酮中测量的加德纳气泡粘度小于约Z4 在25℃下固含量为90％，其羟基中至少5％为主要羟基，（2）10％至70％的低分子量环氧酯，其通过酯化一种或多种具有1个羟基的树脂状聚环氧化物 至少1.2的2-环氧当量与大约化学计量比例的单羧酸脂肪酸反应，以提供在25℃下在二羟甲基中75％固体含量的Gardner气泡粘度小于Z4的基本上无环氧的酯，和（3） 混合物的余量，但不小于15％，是具有与羟基树脂和环氧酯中的羟基反应的多个基团的固化剂。

公开(公告)号：US5484842A

公开(公告)日：1996-01-16

申请号：US247799

申请日：1994-05-23

申请人： Ronald J. Lewarchik ,  Marc L. Smith ,  Michael R. Sestrick

发明人： Ronald J. Lewarchik ,  Marc L. Smith ,  Michael R. Sestrick

IPC分类号： C08G63/60 ,  C08J3/03 ,  C08L67/00 ,  C09D167/00 ,  C08F22/00 ,  C08G63/00

CPC分类号： C08G63/60 ,  C08J3/03 ,  C09D167/00 ,  C08J2367/00

摘要： Aqueous dispersions having low VOCs are dispersions or solutions of polyesters. The polyesters useful are formed from A) between about 30 and about 60 mole percent polycarboxylic acids, of which at least about 80 mole percent comprises cyclohexanedicarboxylic acids, B) between about 35 and about 70 mole percent polyols of which at least about 95 mole percent comprises diols, and between about 40 and about 100 mole percent of the polyol content comprising cycloaliphatic diols, and C) between about 5 and about 25 mole percent of a monomer having dihydroxy, monocarboxylic acid functionality. The molar ratio of (B+C)/A is between about 1.01 and about 1.30, whereby the polyester is hydroxyl-terminated having hydroxyl numbers of between about 20 and about 150 and acid numbers between about 30 and about 100. The weight average molecular weight of the polyester is between about 1000 and about 20,000. In aqueous dispersions or solutions, the acid functionality of the polyester is neutralized with base to at least about 40%.

摘要翻译： 具有低VOC的水性分散体是聚酯的分散体或溶液。 可用的聚酯由A）约30-约60摩尔％的多元羧酸形成，其中至少约80摩尔％包括环己烷二羧酸，B）约35-约70摩尔％多元醇，其中至少约95摩尔％ 包含二醇，以及约40至约100摩尔％的包含脂环族二醇的多元醇含量，和C）约5至约25摩尔％的具有二羟基单羧酸官能团的单体。 （B + C）/ A的摩尔比在约1.01至约1.30之间，由此聚酯是羟基封端的，羟值为约20至约150，酸值为约30至约100.重均分子量 聚酯的重量为约1000至约20,000。 在水分散体或溶液中，聚酯的酸官能度用碱中和至少约40％。

公开(公告)号：US5262494A

公开(公告)日：1993-11-16

申请号：US813221

申请日：1991-12-23

申请人： Marc L. Smith ,  Edward J. Holzrichter ,  Ronald J. Lewarchik

发明人： Marc L. Smith ,  Edward J. Holzrichter ,  Ronald J. Lewarchik

IPC分类号： C08G63/199 ,  C08G63/52 ,  C09D167/00 ,  C09D167/02 ,  C08F20/08 ,  C08L61/20

CPC分类号： C09D167/00 ,  C08G63/199 ,  C09D167/02 ,  Y10T428/31681

摘要： A low cost, high performance coating for sheet metal which is to be formed into siding for houses and automobile panels is made from a polyester prepared by the condensation of hexahydrophthalic acid and a mixture of 1,4-cyclohexanedimethanol and an acyclic polyol wherein the mole percent of acyclic polyol is from 50 to 60; and a crosslinking agent containing the --N--CH.sub.2 --OR moiety wherein R is hydrogen or an alkyl group having from 1 to 4 carbon atoms and the unsatisfied valence is attached to an organic group capable of incorporation into a film.

公开(公告)号：US4560728A

公开(公告)日：1985-12-24

申请号：US537694

申请日：1983-09-30

申请人： Ronald J. Lewarchik ,  Jeffrey W. Thompson

发明人： Ronald J. Lewarchik ,  Jeffrey W. Thompson

IPC分类号： C08G18/00 ,  C08G18/62 ,  C09D175/00 ,  C09D3/72

CPC分类号： C08G18/6266 ,  C08G18/6283

摘要： A coating composition adapted to adhere to a chrome surface is disclosed in which a solvent soluble hydroxy-functional acrylic copolymer, including a copolymerized tertiary amine monomer in an amount of from 5% to 40% of the weight of the copolymer, is combined with an organic polyisocyanate curing agent for the soluble copolymer, this composition containing the copolymer and the polyisocyanate curing agent in amounts to provide an equivalent ratio of NCO:OH of from 1.2:1 to 0.5:1. The two components are provided as a two package system which is mixed prior to application.

摘要翻译： 公开了一种适于粘附到铬表面的涂料组合物，其中溶剂可溶的羟基官能丙烯酸共聚物，包括共聚物的5重量％至40重量％的共聚叔胺单体，与 用于可溶性共聚物的有机多异氰酸酯固化剂，该组合物含有共聚物和多异氰酸酯固化剂，其用量提供的NCO:OH当量比为1.2:1至0.5:1。 这两个组件被提供为在应用之前混合的两个包装系统。

公开(公告)号：US5688598A

公开(公告)日：1997-11-18

申请号：US672280

申请日：1996-06-28

申请人： Mitchell T. Keck ,  Ronald J. Lewarchik ,  Jack C. Allman

发明人： Mitchell T. Keck ,  Ronald J. Lewarchik ,  Jack C. Allman

IPC分类号： C08G18/69 ,  C08G18/80 ,  C09D167/00 ,  C09D175/14 ,  H01B3/30 ,  H01B3/42 ,  C08L23/26 ,  C08L33/02 ,  C08L61/28 ,  C08L67/02

CPC分类号： H01B3/421 ,  C08G18/698 ,  C08G18/807 ,  C09D167/00 ,  C09D175/14 ,  H01B3/302 ,  Y10T428/3154 ,  Y10T428/31681 ,  Y10T428/31688 ,  Y10T428/31692 ,  Y10T428/31696 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31928 ,  Y10T428/31942

摘要： A thermosetting, organic solvent-based, primer coating composition for protecting metal surfaces which includes a solvent solution of: (a) a hydroxy-functional polyester resin; (b) a thermosetting acrylic resin; (c) a hydroxy-terminal polybutadiene resin, a hydroxy-terminal epoxidized polybutadiene resin, or mixtures thereof; (d) a blocked isocyanate crosslinker including at least one dimethyl pyrazole blocked isocyanate; (e) an aminoplast crosslinker including at least one melamine-formaldehyde condensate; (f) a catalyst; and, (g) a pigment. The primer exhibits excellent flexibility after curing to allow the primer to be coil coated onto metals as a thicker film and to have the metal subsequently formed without film fracture or loss of adhesion. The primer also has improved solvent release properties during curing to allow volatiles to readily escape therefrom, which facilitates coil coating of the primer onto metals as thicker films that, when cured into thick film hardened surface finishes, do not exhibit the typical blisters, craters, pops, voids and other surface defects. The primer can be cured as well at reduced temperatures which contributes to the reduction in surface defects. A fluorocarbon topcoat is usually coil coated and cured over the non-blistering primer coating, to yield a composite coated metal substrate having a surface finish that is free of blisters, craters, pops, and voids, and other surface defects.

摘要翻译： 一种用于保护金属表面的热固性有机溶剂型底漆涂料组合物，其包括以下溶剂溶液：（a）羟基官能聚酯树脂; （b）热固性丙烯酸树脂; （c）羟基末端聚丁二烯树脂，羟基末端环氧化聚丁二烯树脂或其混合物; （d）包含至少一个二甲基吡唑封端异氰酸酯的封端异氰酸酯交联剂; （e）包含至少一种三聚氰胺 - 甲醛缩合物的氨基塑料交联剂; （f）催化剂; 和（g）颜料。 该底漆在固化后显示出优异的柔韧性，以使底漆作为更厚的膜被卷绕在金属上，并且随后形成金属，而不会发生膜断裂或粘合丧失。 该底漆还具有改善的固化过程中的溶剂释放性能，以使挥发物容易从其中逸出，这有利于底漆在金属上卷绕涂层，因为当固化成厚膜硬化表面处理时，较薄的膜不会出现典型的起泡， 弹出，空隙等表面缺陷。 底漆也可以在降低的温度下固化，这有助于减少表面缺陷。 氟碳面漆通常在非起泡底漆涂层上卷曲涂覆并固化，得到具有表面光洁度的复合涂覆金属基材，其表面没有水泡，凹坑，气泡和空隙以及其它表面缺陷。

公开(公告)号：US5623027A

公开(公告)日：1997-04-22

申请号：US394022

申请日：1995-02-21

申请人： Ronald J. Lewarchik ,  Marc L. Smith ,  Edward J. Holzrichter

发明人： Ronald J. Lewarchik ,  Marc L. Smith ,  Edward J. Holzrichter

IPC分类号： C08G63/695

CPC分类号： C08G63/6954

摘要： A silicone/polyester adduct comprises between about 5 and about 30 wt % of silicone adducted to between about 70 and about 95% polyester chains formed from polyfunctional acids plus polyfunctional acids and/or anhydrides. At least about 50 mole percent of the polyfunctional acids and/or anhydrides are cycloaliphatic.

摘要翻译： 聚硅氧烷/聚酯加合物包含约5-约30重量％的硅氧烷，其加入到由多官能酸加多官能酸和/或酸酐形成的约70-约95％的聚酯链之间。 至少约50摩尔％的多官能酸和/或酸酐是脂环族的。

公开(公告)号：US4530977A

公开(公告)日：1985-07-23

申请号：US636020

申请日：1984-07-30

申请人： Ronald J. Lewarchik ,  Gerry K. Noren ,  Ronald Metcalfe ,  Demetrius J. Bonin ,  Erwin S. Poklacki

发明人： Ronald J. Lewarchik ,  Gerry K. Noren ,  Ronald Metcalfe ,  Demetrius J. Bonin ,  Erwin S. Poklacki

IPC分类号： C08G18/00 ,  C08G18/10 ,  C08G18/42 ,  C09D175/06 ,  C08G18/32 ,  C08G63/76

CPC分类号： C08G18/10 ,  C08G18/4238 ,  C09D175/06

摘要： An hydroxy-functional polyurethane reaction product is disclosed which enables the provision of thermosetting solution coating compositions which cure at low temperature to form flexible coatings. These polyurethanes are provided by the reaction of an organic diisocyanate with a stoichiometric excess of an essentially linear hydroxy-functional polyester which is the polyesterification reaction product of C.sub.4 -C.sub.10 aliphatic dicarboxylic acid or anhydride thereof with a stoichiometric excess of C.sub.3 -C.sub.8 aliphatic diol providing an alcohol/acid molar ratio of 3/2 to 6/5. The reaction is substantially complete as indicated by an acid number less than 10, and the diisocyanate is used in an amount providing an NCO/OH ratio of from 2/3 to 12/13. The thermosetting solution coating composition is provided by an organic solvent having dissolved therein from 5-50% of total resin solids of a curing agent reactive with hydroxy groups together with the polyurethane which has been described. The preferred curing agent is a partially methylolated melamine which contains from about 5 mol percent to about 40 mol percent of the methylol group.

摘要翻译： 公开了一种羟基官能聚氨酯反应产物，其能够提供在低温下固化以形成柔性涂层的热固性溶液涂料组合物。 这些聚氨酯通过有机二异氰酸酯与化学计量过量的基本上线性的羟基官能聚酯的反应来提供，所述聚酯是C4-C10脂族二羧酸或其酸酐与化学计量过量的C 3 -C 8脂族二醇的聚酯化反应产物，其提供 醇/酸的摩尔比为3/2〜6/5。 反应基本上完成，酸值小于10表示，二异氰酸酯的使用量为NCO / OH比为2/3至12/13。 热固性溶剂涂料组合物由其中溶解有有机溶剂的有机溶剂由与已经描述的聚氨酯一起的5-羟基树脂固体的总树脂固体的羟基提供。 优选的固化剂是部分羟甲基化的三聚氰胺，其含有约5mol％至约40mol％的羟甲基。

公开(公告)号：US4504374A

公开(公告)日：1985-03-12

申请号：US473547

申请日：1983-03-09

申请人： Ronald J. Lewarchik ,  Edward J. Murphy ,  Elaine C. Beeks

发明人： Ronald J. Lewarchik ,  Edward J. Murphy ,  Elaine C. Beeks

IPC分类号： B05D1/00 ,  B05D3/06 ,  B05D5/00 ,  B05D7/00 ,  B05D7/14 ,  B05D7/16 ,  C08F2/48 ,  C09D163/00 ,  C25D13/08

CPC分类号： B05D7/16 ,  B05D7/54 ,  B05D1/007 ,  B05D3/067

摘要： A method of providing a stone chip-resistant finish to the undersurface of an automobile is disclosed in which the undersurface is coated with a cationically initiated liquid mixture of cationically curable polyepoxide, polyhydric alcohol, and a photoinitiator for an ultraviolet-activated cationic cure. The liquid mixture is applied at a resin solids content of at least about 50% and in a thickness to provide a cured coating of at least 2 mils thick, and the wet coating is cured by exposing it to ultraviolet light. The automobile undersurface is desirably primed with a cross-linked amine-functional polymer primer, and the coating includes from 1% to 8% of a finely divided silica which prevents running but does not interfere with the ultraviolet cure.

摘要翻译： 公开了一种向汽车底面提供防石材防滑涂层的方法，其中下表面涂有阳离子引发的阳离子可固化聚环氧化物，多元醇和用于紫外线活化阳离子固化的光引发剂的液体混合物。 以至少约50％和厚度的树脂固体含量施加液体混合物以提供至少2密耳厚的固化涂层，并且湿涂层通过将其暴露于紫外光而固化。 汽车下表面优选用交联的胺官能聚合物底漆涂布，并且涂层包含1％至8％的细碎二氧化硅，其防止流动但不干扰紫外线固化。

公开(公告)号：US4416750A

公开(公告)日：1983-11-22

申请号：US311057

申请日：1981-10-13

申请人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

发明人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

IPC分类号： C08F2/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/00 ,  C08F299/02 ,  C08F299/06 ,  C08J3/28 ,  C08J7/04 ,  C08J7/18 ,  C09D175/14 ,  C08G18/00 ,  C08G63/00

CPC分类号： C08F299/065 ,  C08J7/18 ,  Y10S525/92

摘要： An ultraviolet light-curable liquid coating composition for molded plastic objects is disclosed. The composition is a liquid mixture of a polyurethane oligomer polyacrylate and an hydroxy-functional polyacrylate ester. The polyacrylate ester is present in an amount of 5% to 95% of total polyacrylate. The composition is preferably in solution in alcoholic solvent having a solids content of from 40% to 90%. A photoinitiator is included to render the composition curable upon exposure to ultraviolet light.

摘要翻译： 公开了一种用于模制塑料物体的紫外线可光固化液体涂料组合物。 该组合物是聚氨酯低聚物聚丙烯酸酯和羟基官能聚丙烯酸酯的液体混合物。 聚丙烯酸酯以总聚丙烯酸酯的5％至95％的量存在。 该组合物优选在固体含量为40％至90％的醇溶剂中的溶液中。 包括光引发剂以使组合物在暴露于紫外线下时可固化。