Ink compositions
    4.
    发明授权
    Ink compositions 失效
    油墨组合物

    公开(公告)号:US5587405A

    公开(公告)日:1996-12-24

    申请号:US471449

    申请日:1995-06-06

    摘要: A radiation-curable ink composition contains a vehicle mixture comprising: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and free of a polymerizable double bond in a molecule, wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid wherein the acid has at least one acid group, and/or carboxylic ester of the said acid, and/or carboxylic amide of the said acid, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester, wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100, is provided. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

    摘要翻译: 可辐射固化油墨组合物含有载体混合物,其包含:(A)至少一种基本上不含酸基并且在分子中不含可聚合双键的直链聚酯低聚物和/或聚合物,其中1至10个双键是侧链 和/或其混合物,(B)至少一种含有至少一个酸基团的单双键的羧酸,和/或所述酸的羧酸酯和/或羧酸酰胺 的所述酸和/或其混合物,(C)含双键的多元羧酸酯,其中存在2至10个酸基团,并且至少2个双键从具有2至10个酸基团的酯(D )至少一种含双键的氟化羧酸酯和/或包含含氟烷基的聚合物链段和(甲基)丙烯酸类聚合物链段的嵌段共聚物,和/或包含含硅氧烷基团的聚合物链段和/ (甲基)丙烯酸酯 (E)具有至少2个双键并且不含酸基团的双键的羧酸酯,其不包括在上述成分(A)中,和 (F)至少一种含有单个含双键的羧酸酯和/或不含酸基团的酰胺和/或酰亚胺,和/或其混合物,其中车辆混合物的酸值为5至100。 油墨可用于在特定的热塑性产品上显示和装饰商品名称,设计,注释,条形码等,并且固化的油墨膜易于与碱性水溶液分离。

    Printed thermoplastic resin products and method for printing such
products
    5.
    发明授权
    Printed thermoplastic resin products and method for printing such products 失效
    印刷热塑性树脂产品及印刷方法

    公开(公告)号:US5712022A

    公开(公告)日:1998-01-27

    申请号:US488408

    申请日:1995-06-07

    IPC分类号: B41M1/30 C09D11/10 B32B27/00

    摘要: An easily regeneratable printed thermoplastic resin product is provided by printing it with a specific radiation-curable ink composition and curing the printed ink with radiation to form a cured ink film thereon. The ink composition comprises a vehicle mixture containing: (A) at least one linear polyester oligomer and/or polymer substantially free of an acid group and a polymerizable double bond on the linear polyester chain wherein 1 to 10 double bonds are pendent from the linear polyester chain, and/or mixture thereof, (B) at least one single double bond-containing carboxylic acid and/or ester and/or amide wherein the acid has at least one acid group, and/or mixture thereof, (C) a double bond-containing polycarboxylic ester wherein 2 to 10 acid groups are present and at least 2 double bonds are pendent from the carboxylic ester having 2 to 10 acid groups, (D) at least one double bond-containing fluorinated carboxylic ester, and/or block copolymer comprising a fluorinated alkyl group-containing polymer segment and a (meth)acrylic polymer segment, and/or block copolymer comprising a siloxane group-containing polymer segment and a (meth)acrylic polymer segment, and/or mixture thereof, (E) a double bond-containing carboxylic ester, having at least 2 double bonds and free of an acid group, provided that it is excluded from the above-mentioned ingredient (A), and (F) at least one single double bond-containing carboxylic ester and/or amide and/or imide free of an acid group, and/or mixture thereof, wherein the acid value of the vehicle mixture is from 5 to 100. The ink is useful in displaying and decorating trade names, designs, explanatory notes, bar code, etc. on specific thermoplastic products and the cured ink film is easily detachable with an aqueous alkali solution.

    摘要翻译: 通过用特定的可辐射固化油墨组合物印刷并通过辐射固化印刷油墨以在其上形成固化的油墨膜来提供易于再生的印刷热塑性树脂产品。 油墨组合物包含载体混合物,其包含:(A)至少一种线性聚酯链上基本上不含酸基团和可聚合双键的线性聚酯低聚物和/或聚合物,其中1至10个双键与直链聚酯 链和/或其混合物,(B)至少一种含单个双键的羧酸和/或酯和/或酰胺,其中酸具有至少一个酸基,和/或其混合物,(C)双 含有2〜10个酸基且至少2个双键与具有2〜10个酸基的羧酸酯侧基,(D)至少一个含双键的氟化羧酸酯和/或嵌段 包含含氟基烷基的聚合物链段和(甲基)丙烯酸类聚合物链段的共聚物和/或包含含硅氧烷基团的聚合物链段和(甲基)丙烯酸类聚合物链段的嵌段共聚物和/或其混合物,(E) 一个双重的 具有至少2个双键且不含酸基团的含L键的羧酸酯,条件是其不包括在上述成分(A)中,和(F)至少一种含有单个双键的羧酸酯和 /或不含酸基的酰胺和/或酰亚胺,和/或其混合物,其中车辆混合物的酸值为5至100.油墨可用于显示和装饰商品名称,设计,说明注释,条 代码等,并且固化的油墨膜易于与碱性水溶液分离。

    Collapsable tube
    6.
    发明授权
    Collapsable tube 失效
    可折叠管

    公开(公告)号:US3958721A

    公开(公告)日:1976-05-25

    申请号:US323982

    申请日:1973-01-15

    摘要: A collapsable tube of synthetic resin materials and adapted to prevent oxidization of the substance contained therein. The body of the tube is constructed of a laminated sheet which, in one embodiment, comprises a polyethylene film an oriented polypropylene film, a polyvinyl alcohol film and a polyethylene film in the order named. Due to the provision of the polyvinyl alcohol film the sheet has an extremely low permeability to oxygen gas and odour and is highly resistant to oil. The oriented polypropylene film provides for the sheet increased rigidity as well as improved printability. A non-return valve is provided at the tube orifice in order to prevent the entrance of air thereinto thus causing substantially no oxidization of the substance contained.

    摘要翻译: 合成树脂材料的可塌缩管,适用于防止其中所含物质的氧化。 管的主体由层压片构成,在一个实施例中,层压片包括聚乙烯膜,定向聚丙烯膜,聚乙烯醇膜和聚乙烯膜。 由于提供聚乙烯醇膜,该片材对氧气和气味的渗透性极低,并且对油具有高度的耐受性。 定向聚丙烯薄膜提供了增加的刚性以及改进的可印刷性。 在管孔处设置止回阀,以防止空气入口,从而基本上不含有所含物质的氧化。

    Saturated polyester bottle-shaped container with hard coating and method
of fabricating the same
    8.
    发明授权
    Saturated polyester bottle-shaped container with hard coating and method of fabricating the same 失效
    具有硬涂层的饱和聚酯瓶形容器及其制造方法

    公开(公告)号:US4569869A

    公开(公告)日:1986-02-11

    申请号:US263509

    申请日:1981-05-14

    摘要: This invention relates to a saturated polyester bottle-shaped container and a method of fabricating the same from a material such as polyethylene terephthalate incorporating high transparency and superior mechanical surface strength. The hard coating is formed by the steps of coating an ultraviolet curable coating of methyl methacrylate resin on the surface of the body and irradiating ultraviolet rays over the surface of the body coated with the hard coating. Thus, the bottle-shaped container can largely enhance the wear resistance and extreme smoothness of the surface to eliminate dirt adherence onto the surface. In a second embodiment, an ultraviolet ray curable coating is coated onto the bottle, followed by a transparent resin coating which is cross linked with the ultraviolet ray curable coating.

    摘要翻译: 本发明涉及一种饱和聚酯瓶形容器及其制造方法,该材料由诸如聚对苯二甲酸乙二醇酯的材料制成,其具有高透明度和优异的机械表面强度。 通过以下步骤形成硬涂层:在身体表面涂覆甲基丙烯酸甲酯树脂的紫外线固化涂层,并在涂覆有硬涂层的主体表面上照射紫外线。 因此,瓶形容器可以大大增强表面的耐磨性和极端平滑度,以消除粘附在表面上的污垢。 在第二实施方案中,将紫外线固化涂料涂覆到瓶子上,然后与紫外线固化涂层交联的透明树脂涂层。