公开(公告)号：US5543453A

公开(公告)日：1996-08-06

申请号：US469674

申请日：1995-06-06

申请人： Kengo Ito ,  Motohiro Mizumachi ,  Yoshio Fujiwara ,  Satoru Shinohara

发明人： Kengo Ito ,  Motohiro Mizumachi ,  Yoshio Fujiwara ,  Satoru Shinohara

IPC分类号： B41M5/00 ,  B41M5/382 ,  B41M5/52 ,  B41M7/00 ,  B41M7/02 ,  C08K3/34 ,  C04B14/04 ,  G03G11/00

CPC分类号： B41M5/38264 ,  B41M5/52 ,  B41M7/0027 ,  B41M7/02 ,  B41M5/5218 ,  B41M5/5254 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802

摘要： A composition for fixing water-color ink for fixing a water-color ink is disclosed. The composition for fixing a water-color ink contains an ion exchanger, such as, a clay based interlayer compound or an ion-exchange resin. The composition for fixing water-color ink contains a water absorptive resin or a heat-melting resin as a binder. A cover film for thermal transfer is formed by forming a water-color ink fixing layer consisting of the composition for fixing water-color ink peelably on a base material. An adhesive layer or a heat-melting resin layer is formed on the water-color ink fixing layer. The cover film for thermal transfer image is superposed and thermo-compression bonded onto a thermal transfer image or a thermal transfer image having a protective layer, with the water-color ink fixing layer, the adhesive layer or the heat-melting resin layer facing the thermal transfer image or the thermal transfer image having the protective layer. The water-color ink fixing layer is transferred and stacked onto the cover film for thermal transfer image.

摘要翻译： 公开了一种用于固定用于固定水彩墨水的水彩墨水的组合物。 用于固定水彩墨的组合物含有离子交换剂，例如粘土基层间化合物或离子交换树脂。 用于固定水彩墨的组合物含有吸水树脂或作为粘合剂的热熔树脂。 通过形成水溶性油墨定影层，形成用于热转印的覆盖膜，该水性油墨定影层由用于将水性油墨可剥离地固定在基材上的组合物构成。 在水彩油墨定影层上形成粘合层或热熔树脂层。 用于热转印图像的覆盖膜叠加并热压粘合到热转印图像或具有保护层的热转印图像上，水彩油墨定影层，粘合剂层或加热熔融树脂层面向 热转印图像或具有保护层的热转印图像。 将水彩墨水定影层转印并堆叠在用于热转印图像的覆盖膜上。

公开(公告)号：US5462910A

公开(公告)日：1995-10-31

申请号：US290718

申请日：1994-08-12

申请人： Kengo Ito ,  Motohiro Mizumachi ,  Yoshio Fujiwara ,  Satoru Shinohara

发明人： Kengo Ito ,  Motohiro Mizumachi ,  Yoshio Fujiwara ,  Satoru Shinohara

IPC分类号： B41M5/00 ,  B41M5/382 ,  B41M5/52 ,  B41M7/00 ,  B41M7/02 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/38264 ,  B41M5/52 ,  B41M7/0027 ,  B41M7/02 ,  B41M5/5218 ,  B41M5/5254 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802

摘要： A composition for fixing water-color ink for fixing a water-color ink is disclosed. The composition for fixing a water-color ink contains an ion exchanger, such as, a clay based interlayer compound or an ion-exchange resin. The composition for fixing water-color ink contains a water absorptive resin or a heat-melting resin as a binder. A cover film for thermal transfer is formed by forming a water-color ink fixing layer consisting of the composition for fixing water-color ink peelably on a base material. An adhesive layer or a heat-melting resin layer is formed on the water-color ink fixing layer. The cover film for thermal transfer image is superposed and thermo-compression bonded onto a thermal transfer image or a thermal transfer image having a protective layer, with the water-color ink fixing layer, the adhesive layer or the heat-melting resin layer facing the thermal transfer image or the thermal transfer image having the protective layer. The water-color ink fixing layer is transferred and stacked onto the cover film for thermal transfer image.

摘要翻译： 公开了一种用于固定用于固定水彩墨水的水彩墨水的组合物。 用于固定水彩墨的组合物含有离子交换剂，例如粘土基层间化合物或离子交换树脂。 用于固定水彩墨的组合物含有吸水树脂或作为粘合剂的热熔树脂。 通过形成水溶性油墨定影层，形成用于热转印的覆盖膜，该水性油墨定影层由用于将水性油墨可剥离地固定在基材上的组合物构成。 在水彩油墨定影层上形成粘合层或热熔树脂层。 用于热转印图像的覆盖膜叠加并热压粘合到热转印图像或具有保护层的热转印图像上，水彩油墨定影层，粘合剂层或加热熔融树脂层面向 热转印图像或具有保护层的热转印图像。 将水彩墨水定影层转印并堆叠在用于热转印图像的覆盖膜上。

公开(公告)号：US4651645A

公开(公告)日：1987-03-24

申请号：US711464

申请日：1985-02-26

申请人： Naotake Kobayashi ,  Tetsuya Abe ,  Satoru Shinohara ,  Yoshio Fujiwara

发明人： Naotake Kobayashi ,  Tetsuya Abe ,  Satoru Shinohara ,  Yoshio Fujiwara

IPC分类号： B41M5/382 ,  B41J31/00 ,  B41M5/26 ,  B41M5/392 ,  B41M5/395

CPC分类号： B41M5/395 ,  B41M5/26 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/273

摘要： The present invention relates to a sublimation ink ribbon capable of printing on a printing paper a still picture image of various kinds of picture images such as a picture image shot by a video camera, a television picture image and the like. At least the surface of its sublimation ink layer is made of a layer containing a sublimation dye whose solubility relative to methyl ethyl ketone is not higher than 2.5g/100 ml or a layer in which a sublimation dye having a solubility higher than 2.5g/100 ml is mixed such that a ratio (P/B) of a weight P of the sublimation dye relative to a weight B of a binder is not higher than 0.5. Thus, it is possible to reduce the under layer soil characteristics.

摘要翻译： PCT No.PCT / JP84 / 00329 Sec。 371日期1985年2月26日第 102（e）1985年2月26日PCT PCT。1984年6月26日PCT公布。 公开号WO85 / 00322 日本1985年1月31日。本发明涉及一种升华色带，其能够在打印纸上打印各种图像图像的静止图像图像，例如由摄像机拍摄的图像图像，电视图像图像和 喜欢。 至少其升华油墨层的表面由含有相对于甲基乙基酮的溶解度不高于2.5g / 100ml的升华染料的层构成，或者其中溶解度高于2.5g / 100ml的升华染料的层， 将100ml混合，使得升华染料的重量P相对于粘合剂的重量B的比率（P / B）不高于0.5。 因此，可以减少下层土壤特性。

公开(公告)号：US4977136A

公开(公告)日：1990-12-11

申请号：US406196

申请日：1989-10-04

申请人： Yoshio Fujiwara ,  Naotake Kobayashi ,  Satoru Shinohara ,  Tetsuya Abe

发明人： Yoshio Fujiwara ,  Naotake Kobayashi ,  Satoru Shinohara ,  Tetsuya Abe

IPC分类号： B41M5/382 ,  B41M7/00

CPC分类号： B41M7/0027 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24868 ,  Y10T428/31533 ,  Y10T428/31739 ,  Y10T428/31743 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31855

摘要： The present invention relates to a cover film for hard copy printing paper which can easily form a colorless and transparent protecting layer on the surface of, for example, a printing paper on which a color picture image is printed. The cover film for hard copy printing paper is such one that the cover film for hard copy printing paper is formed on the surface of a hard copy printing paper on which the printing is carried out by the sublimation transfer method and the cover film is designed to include at least one layer the glass transition temperature of which is selected to be higher than 40.degree. C. and whose water absorbing ratio (ASTM D570) is selected to be lower than 2%, whereby even under high temperature and high humidity, the bad influence exerted by the movement of a dye can be removed.

摘要翻译： 本发明涉及一种用于硬拷贝打印纸的覆盖膜，其能够容易地在其上印刷彩色图像的打印纸的表面上形成无色透明的保护层。 用于硬拷贝打印纸的覆盖膜是这样一种用于硬拷贝打印纸的覆盖膜形成在通过升华转印方法进行打印的硬拷贝打印纸的表面上，并且覆盖膜设计成 包括玻璃化转变温度选择为高于40℃的至少一层，其吸水率（ASTM D570）选择为低于2％，由此即使在高温高湿下也不好 可以去除染料运动所产生的影响。

公开(公告)号：US4599259A

公开(公告)日：1986-07-08

申请号：US624683

申请日：1984-06-22

申请人： Naotake Kobayashi ,  Tetsuya Abe ,  Satoru Shinohara ,  Yoshio Fujiwara

发明人： Naotake Kobayashi ,  Tetsuya Abe ,  Satoru Shinohara ,  Yoshio Fujiwara

IPC分类号： B41M7/00 ,  B41M5/26

CPC分类号： B41M7/0054 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24851 ,  Y10T428/24868 ,  Y10T428/24876 ,  Y10T428/24901 ,  Y10T428/265 ,  Y10T428/31511 ,  Y10T428/31739 ,  Y10T428/31783 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/31906 ,  Y10T428/31935 ,  Y10T428/31986

摘要： A cover film for a sublimation transfer type hard copy of the present invention is a cover film which is melt bonded by heat on the surface of a hard copy printing paper in which a picture image is formed on the surface thereof by selectively transferring a sublimation dye. The cover film includes a resinous layer containing a metal compound selected from Al, Mg, Ca and Sn. This cover film is capable of producing magenta color of high color saturation by arbitrarily controlling the coloring of reddish dye to be shifted to the blue side and can also protect the surface of the printing paper.Furthermore, the present invention relates to a cover film which is melt bonded by heat on the surface of a hard copy printing paper in which a picture image is formed on the surface thereof by selectively transferring a sublimation dye. This cover film includes a layer mainly formed of a phosphor whitener and a resin to increase a whiteness degree of a portion which is not colored so that a picture image is made clear and which can prevent the color of dye from being faded.

摘要翻译： PCT No.PCT / JP83 / 00374 Sec。 371日期1984年6月22日第 102（e）日期1984年6月22日PCT提交1983年10月25日PCT公布。 出版物WO84 / 01745 日本公报1984年5月10日。本发明的升华转印型硬拷贝用覆盖膜是在其表面形成有图像的硬拷贝印刷纸的表面上通过热熔融粘结的覆盖膜 通过选择性地转移升华染料。 覆盖膜包括含有选自Al，Mg，Ca和Sn的金属化合物的树脂层。 该覆盖膜能够通过任意地控制偏移到蓝色侧的红色染料的着色而产生高色饱和度的品红色，并且还可以保护打印纸的表面。 此外，本发明涉及一种通过加热熔融粘结在其上通过选择性转移升华染料而在其表面上形成图像的硬拷贝印刷纸的表面覆盖膜。 该覆盖膜包括主要由荧光增白剂和树脂形成的层，以增加未着色的部分的白度，使得图像图像清晰，并且可以防止染料的颜色褪色。

公开(公告)号：US5277992A

公开(公告)日：1994-01-11

申请号：US913624

申请日：1992-07-16

申请人： Satoru Shinohara ,  Hiroshi Nakano ,  Yoshio Fujiwara ,  Tetsuya Abe

发明人： Satoru Shinohara ,  Hiroshi Nakano ,  Yoshio Fujiwara ,  Tetsuya Abe

IPC分类号： B41M5/42 ,  B41M5/00

CPC分类号： B41M5/423 ,  Y10S428/913

摘要： A thermal transfer ink sheet composed of a substrate, a thermal transfer ink layer formed on one side of the substrate, and a back coat layer formed on the other side of the substrate, characterized in that the back coat layer has a kinetic friction coefficient smaller than 0.25 (with respect to the thermal head) which varies depending on whether printing is going on or not, such that it has a value of .mu..sub.1 when printing is going on and a value of .mu..sub.2 when printing is not going on, with the ratio of .mu..sub.1 /.mu..sub.2 being from 0.8 to 1.2. The kinetic friction coefficient in the specified range can be obtained by employing a slip agent which does not greatly change the kinetic friction coefficient of the back coat layer depending on whether printing is going on or not, or by employing two slip agents in combination, one giving the back coat layer a kinetic friction coefficient which is higher when printing is going on than when printing is not going on, the other giving the back coat layer a kinetic friction coefficient which is lower when printing is going on than when printing is not going on. The thermal transfer ink sheet runs smoothly without imposing unnecessary loads to the thermal head and hence gives rise to a high-quality print image free of printing pitch fluctuation.

摘要翻译： 一种由基板，形成在基板的一侧上的热转印油墨层和形成在该基板的另一侧上的背涂层构成的热转印油墨纸，其特征在于，所述背涂层的动摩擦系数较小 大于0.25（相对于热敏头），其取决于打印是否进行变化，使得当打印不正常时它具有值（I）1，当打印不是 （我的）1 /（我）2的比例为0.8到1.2。 在规定范围内的动摩擦系数可以通过使用根据是否进行印刷而不会大大改变背涂层的动力学摩擦系数的滑爽剂，或者通过组合使用两种滑爽剂来获得， 使背涂层的印刷时的动摩擦系数高于印刷不进行时的动摩擦系数，另一方面给印刷后的印刷后的动摩擦系数低于印刷不进行时的动摩擦系数 上。 热转印油墨纸顺利运行，而不会对热敏头施加不必要的负荷，因此产生了无印刷色调波动的高质量打印图像。

公开(公告)号：US5547739A

公开(公告)日：1996-08-20

申请号：US316607

申请日：1994-09-30

申请人： Kengo Ito ,  Yoshio Fujiwara

发明人： Kengo Ito ,  Yoshio Fujiwara

IPC分类号： B32B7/12 ,  B41M5/42 ,  B41M5/44 ,  C08G63/698 ,  C08L77/00 ,  C09J167/00 ,  C09J177/00 ,  C09J185/04 ,  B32B5/16 ,  B32B27/34

CPC分类号： B41M5/44 ,  B32B7/12 ,  B41M5/426 ,  C08G63/6986 ,  C09J167/00 ,  C09J177/00 ,  C09J185/04 ,  C08L77/00 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31725 ,  Y10T428/31736

摘要： The present invention relates to an adhesive composition utilized to adhere an ink layer to a first substrate of a recording medium used for heat-sensitive transfer printing. The adhesive composition comprises polyamide and organo boron polymer. The organo boron polymer is a polyester which includes acidic chelate complex residue by reaction of polyol and boric acid. The adhesive composition provides a sufficient adhesive force between the ink layer and the first substrate of the recording medium such that the ink layer does not peel off from the first substrate and stick to a dye acceptor layer of a second substrate during the heat-sensitive transfer printing process.

摘要翻译： 本发明涉及用于将油墨层粘附到用于热敏转印的记录介质的第一基板上的粘合剂组合物。 粘合剂组合物包含聚酰胺和有机硼聚合物。 有机硼聚合物是通过多元醇与硼酸反应而含有酸性螯合络合物残基的聚酯。 粘合剂组合物在墨层和记录介质的第一基底之间提供足够的粘合力，使得油墨层在热敏转印期间不会从第一基底剥离并粘附到第二基底的染料受体层 打印过程。

公开(公告)号：US5883232A

公开(公告)日：1999-03-16

申请号：US114980

申请日：1998-07-14

申请人： Masanobu Hida ,  Kengo Ito ,  Yoshio Fujiwara ,  Nobuo Suzuki ,  Hiroyoshi Yamaga ,  Junichi Hagiwara

发明人： Masanobu Hida ,  Kengo Ito ,  Yoshio Fujiwara ,  Nobuo Suzuki ,  Hiroyoshi Yamaga ,  Junichi Hagiwara

IPC分类号： B41J31/00 ,  B41M3/12 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  C04B9/02 ,  C09B44/02 ,  C09B44/04 ,  C09B44/18 ,  C09B69/06 ,  D06P5/13 ,  G03C1/73 ,  G03C1/735

CPC分类号： B41M5/388 ,  C09B44/18 ,  C09B69/065 ,  Y10S534/02

摘要： Disclosed are diazahemicyanine hydrophobic cationic dyes represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are lower alkyl groups having not more than 5 carbon atoms, R.sup.5 is a lower alkyl group having not more than 5 carbon atoms or a lower alkoxy lower alkyl group having not more than 6 carbon atoms, and Z.sup.- is a counter ion having a hydrophobic organic group, and a thermal transfer ink ribbon having a substrate and and ink layer laminated thereon containing said cationic dye.

摘要翻译： 公开了由式（1）表示的二氮杂氨酸疏水性阳离子染料：其中R1，R2，R3和R4是不大于5个碳原子的低级烷基，R5是不大于 5个碳原子或具有不超过6个碳原子的低级烷氧基低级烷基，Z-是具有疏水性有机基团的抗衡离子，和具有基材的热转印墨带和层压在其上的含有所述阳离子染料的墨层 。

公开(公告)号：US5589435A

公开(公告)日：1996-12-31

申请号：US471767

申请日：1995-06-06

申请人： Kengo Ito ,  Kaori Isaji ,  Yoshio Fujiwara ,  Mitsuhiro Isogai ,  Masanobu Hida

发明人： Kengo Ito ,  Kaori Isaji ,  Yoshio Fujiwara ,  Mitsuhiro Isogai ,  Masanobu Hida

IPC分类号： B41M5/382 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/5218 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/259

摘要： A sheet of the type which comprises a release base sheet and a thermal transfer image-receiving layer formed on the release base sheet and which is capable of releasing the thermal transfer image-receiving layer from the base sheet is described. The receiving layer is made of a dispersion, in a resin binder, of a layer compound capable of fixing cationic dyes through ion exchange reaction therewith. The receiving layer can be readily formed on a desired type of substrate by superposing the receiving layer on the substrate, after which the release base sheet is peeled off from the receiving layer. A thermal transfer image can be formed on the receiving layer by superposition with an ink ribbon containing a cationic dye and application of image information to the ink ribbon or by re-transfer of a cationic dye image from a printing paper. The thermal transfer image may be formed prior to the transfer of the receiving layer on the substrate. Owing to the fixing of the cationic dye through ion exchange reaction, the fixing properties of the dye in the receiving layer can be significantly improved.

摘要翻译： 描述了一种包括释放基片和形成在释放基片上并且能够从基片释放热转印图像接收层的热转印图像接收层的类型。 接收层由树脂粘合剂中的能够通过离子交换反应固定阳离子染料的层化合物的分散体制成。 接收层可以通过将接收层叠置在基板上而容易地形成在期望类型的基板上，然后将释放基片从接收层剥离。 可以通过与含有阳离子染料的墨带和向墨带施加图像信息或通过从印刷纸重新转移阳离子染料图像叠加在接收层上形成热转印图像。 热转印图像可以在接收层在基板上传送之前形成。 由于通过离子交换反应固定阳离子染料，染料在接收层中的定影性能可以显着提高。

公开(公告)号：US06281270B1

公开(公告)日：2001-08-28

申请号：US08967912

申请日：1997-11-12

申请人： Kengo Ito ,  Yoshio Fujiwara

发明人： Kengo Ito ,  Yoshio Fujiwara

IPC分类号： C09D1110

CPC分类号： B41M5/5218 ,  B41M2205/12 ,  C09D11/328 ,  Y10S260/38 ,  Y10T428/24893 ,  Y10T428/24917 ,  Y10T428/259 ,  Y10T428/31855 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31971 ,  Y10T428/31978 ,  Y10T428/31982 ,  Y10T428/31986

摘要： Color images with high fixation comparable to that of silver salt photographic images are formed on printing papers, using aqueous ink compositions by ink jet recording. Color images thus formed have high saturation and high resolution. An intercalated compound capable of fixing water-soluble dyes to a printing paper due to the intercalation based on ion-exchanging between them is incorporated into the dye-receiving layer 2 of the paper, on which color images are formed by ink jet recording using an aqueous ink composition containing a water-soluble dye. The content of the intercalated compound in the layer 2 is from 10 to 90% by weight. As the intercalated compound, montmorillonoids are preferred when water-soluble cationic dyes are used while hydrotalcite-group minerals are preferred when water-soluble anionic dyes are used. FIG. 1 is selected.

摘要翻译： 使用水性墨水组合物通过喷墨记录在印刷纸上形成具有与银盐照相图像相当的高固色度的彩色图像。 如此形成的彩色图像具有高饱和度和高分辨率。 通过基于它们之间的离子交换的嵌入，能够将水溶性染料固定在印刷纸上的嵌入化合物被并入到纸的染料接收层2中，在该染料接受层2中通过喷墨记录形成彩色图像， 含有水溶性染料的水性油墨组合物。 层2中的插层化合物的含量为10〜90重量％。 作为插层化合物，当使用水溶性阳离子染料时，优选蒙脱石，而当使用水溶性阴离子染料时，优选水滑石族矿物。 图。 选择1。