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1.发明授权公开(公告)号：US07960065B2
公开(公告)日：2011-06-14
申请号：US11916093
申请日：2006-06-16
IPC分类号： H01M8/02
CPC分类号： H01M8/0221 , H01M8/0223 , H01M8/0226 , H01M2008/1095 , Y02P70/56
摘要： The present invention provides a separator for a fuel cell comprising a resin and a conductive material as constituting components, and sulfonic acid groups imparted to at least one portion at the surface of gas channels by a treatment using a sulfuric acid-containing gas, wherein the resin and the sulfonic acid groups, which are on the surface of the gas channels, are bonded, and a ratio of sulfur atoms in the sulfonic acid groups at the surface of the gas channels as determined by energy-dispersive X-ray spectroscopy is in a range from 0.1 to 4.0 at %, and a method for producing the separator. The separator for a fuel cell of the present invention is excellent in the wettability to water, since sulfonic acid groups are imparted to the resin at the surface of gas channels in the sulfuric acid-containing gas.
摘要翻译： 本发明提供一种燃料电池用隔板，其包含作为构成成分的树脂和导电材料，以及通过使用含硫酸气体的处理在气体通道的表面赋予至少一部分的磺酸基，其中， 在气体通道的表面上的树脂和磺酸基团被结合，并且通过能量色散X射线光谱测定在气体通道表面的磺酸基中的硫原子比例在 0.1〜4.0at％的范围，以及隔膜的制造方法。 本发明的燃料电池用隔膜由于在含硫气体的气体通道的表面赋予了磺酸基，所以对水的润湿性优异。
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2.发明申请公开(公告)号：US20100015497A1
公开(公告)日：2010-01-21
申请号：US11916093
申请日：2006-06-16
CPC分类号： H01M8/0221 , H01M8/0223 , H01M8/0226 , H01M2008/1095 , Y02P70/56
摘要： The present invention provides a separator for a fuel cell comprising a resin and a conductive material as constituting components, and sulfonic acid groups imparted to at least one portion at the surface of gas channels by a treatment using a sulfuric acid-containing gas, wherein the resin and the sulfonic acid groups, which are on the surface of the gas channels, are bonded, and a ratio of sulfur atoms in the sulfonic acid groups at the surface of the gas channels as determined by energy-dispersive X-ray spectroscopy is in a range from 0.1 to 4.0 at %, and a method for producing the separator. The separator for a fuel cell of the present invention is excellent in the wettability to water, since sulfonic acid groups are imparted to the resin at the surface of gas channels in the sulfuric acid-containing gas.
摘要翻译： 本发明提供一种燃料电池用隔板，其包含作为构成成分的树脂和导电材料，以及通过使用含硫酸气体的处理在气体通道的表面赋予至少一部分的磺酸基，其中， 在气体通道的表面上的树脂和磺酸基团被结合，并且通过能量色散X射线光谱测定在气体通道表面的磺酸基中的硫原子比例在 0.1〜4.0at％的范围，以及隔膜的制造方法。 本发明的燃料电池用隔膜由于在含硫气体的气体通道的表面赋予了磺酸基，所以对水的润湿性优异。
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公开(公告)号：US20090098431A1
公开(公告)日：2009-04-16
申请号：US12092896
申请日：2006-11-08
CPC分类号： H01M8/0221 , H01M8/0213 , H01M8/0226 , H01M8/0228 , H01M8/04171 , H01M2008/1095 , Y02P70/56
摘要： The present invention provides a method of producing a fuel cell separator in which at least a portion of a premolded article composed of a thermosetting resin and a carbon material, or a thermoplastic resin and a carbon material is provided with hydrophilicity, including the steps of: (1) treating the premolded article for enhancing affinity with a solution of a radically polymerizable monomer having a hydrophilic group and/or a functional group which can be converted into a hydrophilic group; (2) coating the solution of the radically polymerizable monomer having a hydrophilic group and/or a functional group which can be converted into a hydrophilic group, on the treated surface; (3) irradiating the treated surface with ionizing radiation; and (4) cleaning the fuel cell separator obtained through steps 1 to 3; wherein steps 1 to 4 are sequentially carried out, or step 1, step 3, step 2, and step 4 are sequentially carried out.
摘要翻译： 本发明提供一种燃料电池用隔板的制造方法，其中至少一部分由热固性树脂和碳材料构成的预成型制品，或热塑性树脂和碳材料具有亲水性，包括以下步骤： （1）用可亲水性基团和/或官能团的可自由基聚合的单体溶液处理预成型制品以增强亲和性，该单体可以转化为亲水基团; （2）在经处理的表面上涂布具有亲水基团和/或可转化成亲水基团的官能团的自由基聚合单体的溶液; （3）用电离辐射照射处理过的表面; 和（4）清洗通过步骤1至3获得的燃料电池分离器; 其中依次执行步骤1至4，或者依次执行步骤1，步骤3，步骤2和步骤4。
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4.发明授权Conductive resin composition, process for production thereof, and fuel cell separators 失效导电树脂组合物，其制造方法和燃料电池隔板公开(公告)号：US07858696B2
公开(公告)日：2010-12-28
申请号：US10532084
申请日：2004-03-05
申请人： Takashi Yasumura , Toshiya Kato , Kenichi Hamada , Tetsuya Harada
发明人： Takashi Yasumura , Toshiya Kato , Kenichi Hamada , Tetsuya Harada
CPC分类号： C08F290/067 , H01B1/20 , H01M8/0221 , H01M8/0226 , H01M2008/1095 , Y02P70/56
摘要： An object of the present invention is to provide a conductive resin composition which does not cause problems with regard to moldability such as occurrence of separation between a resin component and a conductive filler, voids and warp on molding, and is excellent in filling of a resin into a mold, and is also capable of being used for various electrical and electronic materials, including a separator for a fuel cell having excellent properties. To achieve the above object, the present invention provides a conductive resin composition comprising a conductive filler (A); a urethane-modified epoxy (meth)acrylate (B) obtained by reacting an epoxy (meth)acrylate (b-1), which is obtained by the addition reaction of an epoxy resin having an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and a (meth)acrylic acid, with a polyisocyanate (b-2); a (meth)acrylate (C) having a number average molecular weight of 500 to 10,000, which contains 20 to 80% by weight of an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and contains no active hydrogen atom; and the other ethylenically unsaturated monomer (D) which is copolymerizable with the urethane-modified epoxy (meth)acrylate (B) and the (meth)acrylate (C).
摘要翻译： 本发明的目的是提供一种导电性树脂组合物，其不会引起树脂成分与导电性填料的分离发生等成型性，成型后的空隙和翘曲等问题，树脂的填充性优异 并且还能够用于各种电气和电子材料，包括具有优异性能的燃料电池用隔板。 为了实现上述目的，本发明提供一种包含导电填料（A）的导电树脂组合物。 通过使具有芳香族环状结构单元的环氧树脂和/或脂肪族环状结构单元的加成反应得到的环氧（甲基）丙烯酸酯（b-1）与环氧（甲基）丙烯酸酯 结构单元和（甲基）丙烯酸，与多异氰酸酯（b-2）; 数均分子量为500〜10000的（甲基）丙烯酸酯（C），含有20〜80重量％的芳香族环状结构单元和/或脂肪族环状结构单元，不含有活性氢原子; 和可与氨基甲酸酯改性的环氧（甲基）丙烯酸酯（B）和（甲基）丙烯酸酯（C））共聚的其它烯属不饱和单体（D）。
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5.发明申请Conductive resin composition, process for production thereof, and fuel cell separators 失效导电树脂组合物，其制造方法和燃料电池隔板公开(公告)号：US20060060824A1
公开(公告)日：2006-03-23
申请号：US10532084
申请日：2004-03-05
申请人： Takashi Yasumura , Toshiya Kato , Kenichi Hamada , Tetsuya Harada
发明人： Takashi Yasumura , Toshiya Kato , Kenichi Hamada , Tetsuya Harada
CPC分类号： C08F290/067 , H01B1/20 , H01M8/0221 , H01M8/0226 , H01M2008/1095 , Y02P70/56
摘要： An object of the present invention is to provide a conductive resin composition which does not cause problems with regard to moldability such as occurrence of separation between a resin component and a conductive filler, voids and warp on molding, and is excellent in filling of a resin into a mold, and is also capable of being used for various electrical and electronic materials, including a separator for a fuel cell having excellent properties. To achieve the above object, the present invention provides a conductive resin composition comprising a conductive filler (A); a urethane-modified epoxy (meth)acrylate (B) obtained by reacting an epoxy (meth)acrylate (b-1), which is obtained by the addition reaction of an epoxy resin having an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and a (meth)acrylic acid, with a polyisocyanate (b-2); a (meth)acrylate (C) having a number average molecular weight of 500 to 10,000, which contains 20 to 80% by weight of an aromatic cyclic structural unit and/or an aliphatic cyclic structural unit and contains no active hydrogen atom; and the other ethylenically unsaturated monomer (D) which is copolymerizable with the urethane-modified epoxy (meth)acrylate (B) and the (meth)acrylate (C).
摘要翻译： 本发明的目的是提供一种导电性树脂组合物，其不会引起树脂成分与导电性填料的分离发生等成型性，成型后的空隙和翘曲等问题，树脂的填充性优异 并且还能够用于各种电气和电子材料，包括具有优异性能的燃料电池用隔板。 为了实现上述目的，本发明提供一种包含导电填料（A）的导电树脂组合物。 通过使具有芳香族环状结构单元的环氧树脂和/或脂肪族环状结构单元的加成反应得到的环氧（甲基）丙烯酸酯（b-1）与环氧（甲基）丙烯酸酯 结构单元和（甲基）丙烯酸，与多异氰酸酯（b-2）; 数均分子量为500〜10000的（甲基）丙烯酸酯（C），含有20〜80重量％的芳香族环状结构单元和/或脂肪族环状结构单元，不含有活性氢原子; 和可与氨基甲酸酯改性的环氧（甲基）丙烯酸酯（B）和（甲基）丙烯酸酯（C））共聚的其它烯属不饱和单体（D）。
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6.发明授权Modified microfibrillated cellulose and resin composite material containing the same 有权改性微纤化纤维素和含有它的树脂复合材料公开(公告)号：US08420735B2
公开(公告)日：2013-04-16
申请号：US13517330
申请日：2010-12-21
申请人： Kenichi Hamada , Tetsuya Harada
发明人： Kenichi Hamada , Tetsuya Harada
CPC分类号： C08L1/02 , C08B15/05 , C08F8/12 , C08J5/045 , C08J5/06 , C08L33/14 , C08L2205/16 , C08L101/10 , C08F2220/1858 , C08F2220/325 , C08F230/08
摘要： A modified microfibrillated cellulose, a resin composition and a resin composite material that contain the modified microfibrillated cellulose are provided. In a modified microfibrillated cellulose according to the present invention, a hydrolyzable-silyl-group-containing resin (A) bonds to or adheres to a cellulose surface and a silicon atom content is 0.01 to 0.5 atomic percent. A resin composition containing 0.1% to 10% by weight of the modified microfibrillated cellulose is also provided.
摘要翻译： 提供了改性微纤化纤维素，含有改性微纤化纤维素的树脂组合物和树脂复合材料。 在本发明的改性微纤化纤维素中，含有水解性甲硅烷基的树脂（A）与纤维素表面结合或附着，硅原子含量为0.01〜0.5原子％。 还提供了含有0.1重量％至10重量％的改性微纤化纤维素的树脂组合物。
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7.发明申请MODIFIED MICROFIBRILLATED CELLULOSE AND RESIN COMPOSITE MATERIAL CONTAINING THE SAME 有权改性微晶纤维素和含有它的树脂复合材料公开(公告)号：US20120309898A1
公开(公告)日：2012-12-06
申请号：US13517330
申请日：2010-12-21
申请人： Kenichi Hamada , Tetsuya Harada
发明人： Kenichi Hamada , Tetsuya Harada
IPC分类号： C08F230/08 , C08L83/07
CPC分类号： C08L1/02 , C08B15/05 , C08F8/12 , C08J5/045 , C08J5/06 , C08L33/14 , C08L2205/16 , C08L101/10 , C08F2220/1858 , C08F2220/325 , C08F230/08
摘要： A modified microfibrillated cellulose, a resin composition and a resin composite material that contain the modified microfibrillated cellulose are provided. In a modified microfibrillated cellulose according to the present invention, a hydrolyzable-silyl-group-containing resin (A) bonds to or adheres to a cellulose surface and a silicon atom content is 0.01 to 0.5 atomic percent. A resin composition containing 0.1% to 10% by weight of the modified microfibrillated cellulose is also provided.
摘要翻译： 提供了改性微纤化纤维素，含有改性微纤化纤维素的树脂组合物和树脂复合材料。 在本发明的改性微纤化纤维素中，含有水解性甲硅烷基的树脂（A）与纤维素表面结合或附着，硅原子含量为0.01〜0.5原子％。 还提供了含有0.1重量％至10重量％的改性微纤化纤维素的树脂组合物。
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公开(公告)号：US09527994B2
公开(公告)日：2016-12-27
申请号：US13881310
申请日：2011-10-24
申请人： Hiroshi Ozawa , Toru Takahashi , Atsushi Matsumura , Kenichi Hamada , Yoshihiro Morishita , Toyoaki Kurihara
发明人： Hiroshi Ozawa , Toru Takahashi , Atsushi Matsumura , Kenichi Hamada , Yoshihiro Morishita , Toyoaki Kurihara
IPC分类号： C08L33/12 , C08L53/00 , C08L33/08 , C08F297/02 , C08F220/18
CPC分类号： C08L53/00 , B29K2233/12 , C08F297/026 , C08F2220/185 , C08L33/08 , C08F220/14 , C08F2220/1825 , C08L33/12
摘要： An object of the present invention is to provide a methacrylic resin composition which exhibits excellent flexibility, elasticity, impact resistance, and plasticity and moldability while transparency inherent to methacrylic resins is maintained. A methacrylic resin composition to be produced is composed of 10 to 99 parts by mass of a methacrylic resin (A) containing not less than 80 mass % of a methyl methacrylate unit and 90 to 1 part by mass of a block copolymer (B) containing 10 to 60 mass % of a methyl methacrylate polymer block (b1) and 90 to 40 mass % of an acrylate polymer block (b2) and having a refractive index of 1.485 to 1.495 (the total of (A) and (B) is 100 parts by mass).
摘要翻译： 本发明的目的是提供一种在保持甲基丙烯酸树脂固有的透明性的同时表现出优异的柔软性，弹性，耐冲击性，塑性和成型性的甲基丙烯酸系树脂组合物。 所生产的甲基丙烯酸系树脂组合物由含有80质量％以上甲基丙烯酸甲酯单元的甲基丙烯酸系树脂（A）10〜99质量份，嵌段共聚物（B）90〜1质量份构成， 10〜60质量％的甲基丙烯酸甲酯聚合物嵌段（b1）和90〜40质量％的丙烯酸酯聚合物嵌段（b2），折射率为1.485〜1.495（（A）和（B）的总计）为100 质量份）。
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9.发明申请RADIATION SENSITIVE RESIN COMPOSITION AND METHOD OF FORMING AN INTERLAYER INSULATING FILM 有权辐射敏感性树脂组合物和形成层间绝缘膜的方法公开(公告)号：US20120270151A1
公开(公告)日：2012-10-25
申请号：US13502211
申请日：2010-10-14
申请人： Katsuhiro Kikuchi , Kentaro Usui , Masakazu Shibasaki , Takashi Ochi , Tatsuro Kato , Kenichi Hamada , Masashi Arai , Megumi Murata , Hideaki Takase
发明人： Katsuhiro Kikuchi , Kentaro Usui , Masakazu Shibasaki , Takashi Ochi , Tatsuro Kato , Kenichi Hamada , Masashi Arai , Megumi Murata , Hideaki Takase
CPC分类号： G03F7/0233 , G03F7/0226 , G03F7/40
摘要： The present invention relates to a radiation sensitive resin composition comprising [A] an alkali-soluble resin, [B] a 1,2-quinonediazide compound and [C] a radical trapping agent.The radiation sensitive resin composition can provide an interlayer insulating film which satisfies general requirements for an interlayer insulating film such as high light transmittance and has excellent heat-resistant dimensional stability, heat discoloration resistance and adhesion to a substrate along with the improvement of process efficiency for improving product yield at a high resolution and has excellent storage stability.
摘要翻译： 本发明涉及一种辐射敏感性树脂组合物，其包含[A]碱溶性树脂，[B] 1,2-醌二叠氮化合物和[C]基团捕获剂。 辐射敏感性树脂组合物可以提供层间绝缘膜，其满足诸如高透光率的层间绝缘膜的一般要求，并且具有优异的耐热尺寸稳定性，耐热变色性和对基材的粘附性，同时提高了工艺效率 以高分辨率提高产品收率，并具有优良的储存稳定性。
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公开(公告)号：US20120195838A1
公开(公告)日：2012-08-02
申请号：US13392905
申请日：2010-09-02
CPC分类号： A01N65/00 , A01N65/40 , A61K8/97 , A61Q11/02 , A61Q17/005
摘要： Provided is an oral composition for denture wearers, which includes an antimicrobial substance of biological origin, is biocompatible, and has an antimicrobial activity. Specifically, provided is an antimicrobial oral composition for denture wearers including a component of common rush origin. The oral composition for denture wearers is placed in the mouth, and hence the oral composition for denture wearers including a component of common rush origin, which may also be used as a food additive, is safe for a living body and useful.
摘要翻译： 提供了一种用于假牙佩戴者的口服组合物，其包括生物来源的抗微生物物质，是生物相容的并且具有抗微生物活性。 具体地，提供了一种用于义齿穿着者的抗微生物口服组合物，其包括共同急起的组分。 将义齿佩戴者的口腔用组合物置于口中，因此也可以作为食品添加剂使用的包括共同急起的成分的假牙佩戴者的口腔用组合物对于生物体是安全的并且是有用的。
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