公开(公告)号：US20050048591A1

公开(公告)日：2005-03-03

申请号：US10924980

申请日：2004-08-25

申请人： Kenji Kitaoka ,  Masashi Yamada ,  Seiji Kawaguchi

发明人： Kenji Kitaoka ,  Masashi Yamada ,  Seiji Kawaguchi

IPC分类号： G01N21/78 ,  C09K11/07 ,  G01N33/58 ,  G01N33/53 ,  C07D493/02 ,  G01N33/537 ,  G01N33/543

CPC分类号： G01N33/582 ,  C09K11/07 ,  C09K2211/1007 ,  Y10S435/968 ,  Y10S436/904

摘要： A chemiluminescence method characterized in that when a 1,2-dioxetane derivative of the formula 1: wherein each of R1, R2, R3, R4 and R5 which are independent of one another, is a hydrogen atom, an alkyl group or an aryl group, or each pair of R2 and R3, and R4 and R5, which are independent of each other, may form together a cyclic alkyl group, R6 is a hydroxyl group, an alkoxyl group, an aralkyloxy group, a group represented by —OSi(R8R9R10) (provided that each of R8, R9 and R10 which are independent of one another, is an alkyl group or an aryl group), a phosphate group or a group represented by S(C═O)R11 (provided that R11 is an alkyl group or an aryl group), and R7 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxyl group, is let generate chemiluminescence by means of an activator selected from the group consisting of a base, an acid, a salt, a fluorine compound, an enzyme, a catalyst and an amine compound, a cationic surfactant and a fluorescent material are made to coexist.

摘要翻译： 一种化学发光法，其特征在于当式1的1,2-二氧环乙烷衍生物：其中R 1，R 2，R 3，R 4和R 5各自独立地为 相互独立的是氢原子，烷基或芳基，或者R 2和R 3的每一对以及R 4和R 5彼此独立地形成 一起是环状烷基，R 6是羟基，烷氧基，芳烷氧基，-OSi（R 8 R 9 R 10）表示的基团（条件是R“ R 8，R 9和R 10彼此独立，是烷基或芳基），磷酸基或由S（C = O）R 11表示的基团（条件是 R 11是烷基或芳基），并且R 7是氢原子，卤原子，烷基或烷氧基，通过选自以下的活化剂产生化学发光： 的碱，酸，盐，氟化合物，酶，催化剂和胺化合物，阳离子表面活性剂和 使荧光材料共存。

公开(公告)号：US07091051B2

公开(公告)日：2006-08-15

申请号：US10924980

申请日：2004-08-25

申请人： Kenji Kitaoka ,  Masashi Yamada ,  Seiji Kawaguchi

发明人： Kenji Kitaoka ,  Masashi Yamada ,  Seiji Kawaguchi

IPC分类号： G01N33/532 ,  G01N21/76 ,  C12Q1/42 ,  C12Q1/28

CPC分类号： G01N33/582 ,  C09K11/07 ,  C09K2211/1007 ,  Y10S435/968 ,  Y10S436/904

摘要： A chemiluminescence method characterized in that when a 1,2-dioxetane derivative of the formula 1: wherein each of R1, R2, R3, R4 and R5 which are independent of one another, is a hydrogen atom, an alkyl group or an aryl group, or each pair of R2 and R3, and R4 and R5, which are independent of each other, may form together a cyclic alkyl group, R6 is a hydroxyl group, an alkoxyl group, an aralkyloxy group, a group represented by —OSi(R8R9R10) (provided that each of R8, R9 and R10 which are independent of one another, is an alkyl group or an aryl group), a phosphate group or a group represented by S(C═O)R11 (provided that R11 is an alkyl group or an aryl group), and R7 is a hydrogen atom, a halogen atom, an alkyl group or an alkoxyl group, is let generate chemiluminescence by means of an activator selected from the group consisting of a base, an acid, a salt, a fluorine compound, an enzyme, a catalyst and an amine compound, a cationic surfactant and a fluorescent material are made to coexist.

摘要翻译： 一种化学发光法，其特征在于当式1的1,2-二氧环乙烷衍生物：其中R 1，R 2，R 3， R 4，R 4和R 5彼此独立的是氢原子，烷基或芳基，或每对R 2 R 3和R 3和R 4和R 5彼此独立地可以一起形成环烷基 R 6是羟基，烷氧基，芳烷氧基，-OSi表示的基团（R 8，R 9，R 9， SUP> 10）（条件是彼此独立的R 8，R 9和R 10中的每一个是 烷基或芳基），磷酸酯基或由S（CO）R 11表示的基团（条件是R 11是烷基或芳基） ）和R 7是氢原子，卤素原子，烷基或烷氧基，通过手段产生化学发光 选自碱，酸，盐，氟化合物，酶，催化剂和胺化合物的活化剂，阳离子表面活性剂和荧光材料共存。

公开(公告)号：US06342177B1

公开(公告)日：2002-01-29

申请号：US09280647

申请日：1999-03-29

申请人： Kenji Kitaoka

发明人： Kenji Kitaoka

IPC分类号： C04B35624

CPC分类号： C23C18/1254 ,  C04B35/472 ,  C04B35/624 ,  C23C18/1208 ,  C23C18/1295

摘要： The present invention relates to a method for production of a metal oxide thin film and a method for production of an arrayed metal oxide functional device, comprising the steps of: preparing a sol containing a material and a solvent; gelating the sol to give a gel member; processing the gel member under a pressure of not less than 0.2 MPa at 100 to 400° C. in a water-vapor-containing atmosphere; and conducting a heat treatment on the water-vapor-processed gel member at 200 to 400° C.

摘要翻译： 金属氧化物薄膜的制造方法及其制造方法本发明涉及金属氧化物薄膜的制造方法及其制造方法，其特征在于，包括以下步骤：制备含有材料和溶剂的溶胶，凝胶化所述溶胶，得到凝胶 在含水蒸气的气氛中，在100〜400℃下，在不低于0.2MPa的压力下加工凝胶体; 并在200〜400℃下对水蒸气处理的凝胶部件进行热处理。

公开(公告)号：US08207074B2

公开(公告)日：2012-06-26

申请号：US12767109

申请日：2010-04-26

申请人： Kenji Kitaoka

发明人： Kenji Kitaoka

IPC分类号： C03C3/16

CPC分类号： C03C3/21 ,  C03C3/19

摘要： The present invention relates to an optical glass containing, in terms of mass % on an oxide basis, P2O5: from 10 to 18%; Bi2O3: from 37 to 64%; Nb2O5: from 5 to 25%; Na2O: from more than 4.1 to 10%; K2O: from 0 to 2%; Li2O: from 0 to 0.2%; WO3: from 0 to less than 20%; TiO2: from 0 to 3%; and B2O3: from 0 to 2%, and having a refractive index nd of 1.98 or more and an Abbe's number νd of 20 or less.

摘要翻译： 本发明涉及以氧化物为基准的质量％为P 2 O 5：10〜18％的光学玻璃。 Bi2O3：37〜64％ Nb2O5：5〜25％ Na2O：从4.1％到10％; K2O：0〜2％ Li2O：0〜0.2％ WO3：0〜小于20％; TiO 2：0〜3％ B 2 O 3：0〜2％，折射率nd为1.98以上，阿贝值n为20以下。

公开(公告)号：US6110441A

公开(公告)日：2000-08-29

申请号：US76626

申请日：1998-05-12

申请人： Kenji Kitaoka

发明人： Kenji Kitaoka

IPC分类号： G02B6/00 ,  C03B19/12 ,  C03B37/01 ,  C03B37/016 ,  C04B35/49 ,  C04B35/491 ,  C04B35/495 ,  C04B35/622 ,  D01F9/08 ,  D06M11/00 ,  D06M11/05 ,  D06M101/00 ,  H01B3/00 ,  C01G49/00

CPC分类号： C04B35/62231 ,  C03B37/011 ,  C04B35/491 ,  C04B35/495 ,  Y02P40/57

摘要： A method of producing a homogeneous metal oxide fiber having high denseness and free of voids that may adversely affect the electro-optic characteristic of the fiber, and a metal oxide fiber produced according to the method. The method comprises:a first step of forming a gel-form fiber from a sol obtained by concentrating a solution composed of a metallic compound, water and a solvent to the extent that the solution exhibits a spinnable behavior;a second step of decomposing and eliminating organic components out of the gel-form fiber obtained at the first step; anda third step of solidifying the gel-form fiber obtained at the second step;the second step and/or the third step being carried out while heating is made in a water vapor atmosphere.

摘要翻译： 一种制造均匀的金属氧化物纤维的方法，该均匀金属氧化物纤维具有高密度且无空隙，可能不利地影响纤维的电光特性，以及根据该方法生产的金属氧化物纤维。 该方法包括：通过将由金属化合物，水和溶剂组成的溶液浓缩得到的溶胶形成凝胶型纤维至溶液呈现可纺性的程度的第一步骤; 从第一步骤获得的凝胶型纤维中分解除去有机成分的第二步骤; 和在第二步骤中获得的凝胶状纤维凝固的第三步骤; 在水蒸汽气氛中加热的同时进行第二步骤和/或第三步骤。

公开(公告)号：US5911944A

公开(公告)日：1999-06-15

申请号：US886040

申请日：1997-06-30

申请人： Kenji Kitaoka

发明人： Kenji Kitaoka

IPC分类号： D01F9/08 ,  C04B35/622 ,  C04B35/624

CPC分类号： C04B35/6225 ,  C04B35/62231 ,  C04B35/62259 ,  C04B35/624 ,  Y10S264/19

摘要： A method for the production of a fiber comprises a first step of dispersing a raw material containing at least one of a metal hydrate and a hydrated metal compound in an alcohol-based solvent having a boiling point of not lower than 70.degree. C. thereby preparing a sol solution, a second step of heating the sol solution obtained in the first step at a temperature of not higher than 100.degree. C. thereby polymerizing the raw material and effecting conversion thereof to a complex and subsequently concentrating the complex until it manifests spinnability, a third step of stretching the sol solution obtained at the end of the second step into a fiber precursor thereby effecting gelation thereof, and a fourth step of heating the gelatinized fiber precursor thereby producing a fiber.By this method of production, a fiber of homogeneous and dense metal oxide having a high assay is obtained without inducing such impurities as precipitate in the course of manufacture. The fiber of such material as PLZT possessed of an optoelectronic property which is produced by the method mentioned above is utilized for the manufacture of a compact and highly integrated optoelectronic modulator.

摘要翻译： 制造纤维的方法包括将含有金属水合物和水合金属化合物中的至少一种的原料分散在沸点不低于70℃的醇类溶剂中的第一步骤，由此制备 溶胶溶液，第二步骤，在不高于100℃的温度下加热第一步骤获得的溶胶溶液，由此使原料聚合并将其转化成复合物，随后浓缩该复合物直到其具有可纺性， 将在第二步骤中得到的溶胶溶液拉伸到纤维前体中进行凝胶化的第三步骤，以及加热凝胶化纤维前体从而产生纤维的第四步骤。 通过这种生产方法，在制造过程中不会引起诸如沉淀物之类的杂质，而获得具有高测定的均匀且致密的金属氧化物的纤维。 具有通过上述方法制造的具有光电特性的PLZT材料的光纤用于制造紧凑且高度集成的光电调制器。

公开(公告)号：US08501649B2

公开(公告)日：2013-08-06

申请号：US13198040

申请日：2011-08-04

申请人： Kenji Kitaoka

发明人： Kenji Kitaoka

IPC分类号： C03C3/068

CPC分类号： C03C3/068 ,  C03C3/19

摘要： The present invention provides an optical glass, containing, in % by weight on an oxide basis, 30 to 50% of P2O5, 18 to 43% of BaO, 2 to 12% of B2O3, 1.4 to 5% of Al2O3, more than 0 to 6% of Li2O, more than 0 to 9% of La2O3, 0.1 to 8% of MgO, 0 to 10% of CaO, 0 to 15% of SrO, 0 to 5% of ZnO, 0 to 7% of Gd2O3, and 0 to 3% of SiO2, and having optical constants of a refractive index nd of 1.59 to 1.63 and an Abbe number νd of 63 to 68.

摘要翻译： 本发明提供一种光学玻璃，其以氧化物为基准，含有30-50％的P 2 O 5，18至43％的BaO，2至12％的B 2 O 3，1.4至5％的Al 2 O 3，大于0 至6％的Li 2 O，0至9％的La 2 O 3，0.1至8％的MgO，0至10％的CaO，0至15％的SrO，0至5％的ZnO，0至7％的Gd 2 O 3， 和0〜3％的SiO 2，折射率nd的光学常数为1.59〜1.63，阿贝数nud为63〜68。

公开(公告)号：US20070220744A1

公开(公告)日：2007-09-27

申请号：US11587439

申请日：2005-07-21

申请人： Kenji Kitaoka ,  Takayoshi Fujimoto

发明人： Kenji Kitaoka ,  Takayoshi Fujimoto

IPC分类号： H05K3/10 ,  H01K3/10

CPC分类号： H05K3/4007 ,  H05K1/0284 ,  H05K3/107 ,  H05K3/1258 ,  H05K3/182 ,  H05K3/246 ,  H05K3/3436 ,  H05K3/4614 ,  H05K2201/0347 ,  H05K2201/0367 ,  H05K2201/0373 ,  H05K2201/09036 ,  H05K2201/09045 ,  H05K2201/09472 ,  H05K2203/0709 ,  H05K2203/1173 ,  H05K2203/1189 ,  H05K2203/1476 ,  Y10T29/49155 ,  Y10T29/49165

摘要： A wiring circuit board and a method of producing the same are provided in which a desired pattern of wiring is provided at higher density while permitting no overflow from the grooves of an electroless plating catalyst containing solution and an electric conductor forming liquid such as silver ink. The pattern of electric conductor is deposited by applying the electric conductor forming liquid into the grooves provided in a substrate and distributing the same along the grooves with the action of capillarity. The method starts with patterning the grooves in the surface of the substrate (S1), applying the electric conductor forming liquid into the grooves (S2), and coating the surface of the substrate with a layer of repellent liquid which is lower in the affinity with the electric conductor forming liquid (S3). This is followed by cleaning at least the grooves (S4) and then filling the grooves with the electric conductor forming liquid once again (S5). The electric conductor forming liquid applied into the grooves is then distributed throughout the grooves by the action of capillarity. When silver ink is used, the pattern of electric conductor is produced by repeating an action of applying and drying a number of times. Alternatively, the patter of electric conductor can be produced by an electroless plating technique or a combination of an electroless plating technique and an electro-plating technique for separating an electrical conductive material form the electric conductor forming liquid.

摘要翻译： 提供一种布线电路板及其制造方法，其中以更高的密度提供所需的布线图案，同时不允许来自含化学镀电镀催化剂溶液的槽和诸如银墨的电导体形成液体的槽溢出。 通过将导电剂形成液体施加到设置在基板中的凹槽中并通过毛细管作用沿着凹槽分布而将电导体的图案沉积。 该方法开始于图案化基板表面（S 1）中的凹槽，将导电体形成液体施加到凹槽（S 2）中，并且在基板的表面中涂覆一层较低的驱避液体 与导电体形成液体的亲合力（S 3）。 然后，至少清洗槽（S 4），然后再次用导电体形成液填充槽（S 5）。 然后通过毛细作用的作用将施加到槽中的导电体形成液体分布在整个槽中。 当使用银墨时，通过重复施加和干燥多次的作用产生电导体的图案。 或者，电导体的图案可以通过化学镀技术或化学镀技术和电镀技术的组合来制造，用于从形成电导体的液体中分离导电材料。