Method for producing aqueous solution of polymer having phosphorylcholine groups
    1.
    发明授权
    Method for producing aqueous solution of polymer having phosphorylcholine groups 失效
    制备具有磷酸胆碱基团的聚合物水溶液的方法

    公开(公告)号:US06204324B1

    公开(公告)日:2001-03-20

    申请号:US08750102

    申请日:1996-12-02

    IPC分类号: C08L4300

    CPC分类号: C08F30/02 C08F6/003 C08F6/06

    摘要: A method for producing an aqueous solution of a polymer having a phosphorylcholine group in which a polymerizable composition containing a polymerizable monomer having the phosphorylcholine group represented by the formula (1) is polymerized in the presence of a non-metal polymerization initiator soluble in a water-containing medium, to obtain a crude polymer aqueous solution, and the crude polymer aqueous solution is purified with a separation membrane, and an aqueous solution of the polymer having the phosphorylcholine group obtained by the method and having not more than 2000 ppm of impurities. (X: a divalent organic residue, Y: an alkyleneoxy group having C1 to 6, Z: H, R5—O—CO—(R5: an alkyl group of C1 to 10), R1:H, CH3, R2, R3, R4: H, a hydrocarbon group or a hydroxy substituted hydrocarbon group of C1 to 6, m; 0 or 1)

    摘要翻译: 一种具有磷酸胆碱基团的聚合物的水溶液的制备方法,其中含有具有式(1)表示的磷酸胆碱基的可聚合单体的可聚合组合物在可溶于水的非金属聚合引发剂存在下聚合 以获得粗聚合物水溶液,并且用分离膜纯化粗聚合物水溶液,并且通过该方法获得具有磷酸胆碱基的聚合物的水溶液,并且具有不超过2000ppm的杂质。 (X:二价有机残基,Y:具有C1〜6的亚烷基氧基,Z:H,R5-O-CO-(R5:C1〜10的烷基),R1:H,CH3,R2,R3, R4:H,C 1-6的烃基或羟基取代的烃基,m; 0或1)

    Polymer material, medical material and liquid high molecular composition
    2.
    发明授权
    Polymer material, medical material and liquid high molecular composition 失效
    高分子材料,医药材料和液体高分子组成

    公开(公告)号:US5977257A

    公开(公告)日:1999-11-02

    申请号:US945741

    申请日:1997-10-28

    摘要: A high molecular material and a medical material which is a mixed material containing a copolymer A produced by copolymerization of a monomer composition containing a monomer having a side chain represented by the formula (1) ##STR1## (R.sup.1, R.sup.2, R.sup.3 ; H or a C1-4 alkyl group) and a hydrophobic monomer, and one or more sorts of hydrophobic polymer B other than the copolymer A; wherein structure of said mixed material shows phase separation in which domains of several hundred micrometers or less in size consisting of the copolymer A are uniformly distributed in a phase consisting of said hydrophobic polymer B. A liquid high molecular composition in which the copolymer A and the hydrophobic polymer B are dissolved in a mixed solvent consisting of a halogenated hydrocarbon solvent and a lower alcohol solvent, which has turbidity of 60% or less.

    摘要翻译: PCT No.PCT / JP96 / 00769 Sec。 371日期1997年10月28日第 102(e)日期1997年10月28日PCT 1996年3月25日PCT公布。 公开号WO96 / 34061 日期:1996年10月31日高分子材料和医用材料是含有共聚物A的混合材料,共聚物A是通过含有具有由式(1)表示的侧链的单体的单体组合物(R1,R2,R3, H或C 1-4烷基)和疏水单体,以及一种或多种除共聚物A以外的疏水性聚合物B; 其中所述混合材料的结构显示相分离,其中由共聚物A组成的尺寸为几百微米或更小的畴在由所述疏水性聚合物B组成的相中均匀分布。一种液体高分子组合物,其中共聚物A和 疏水性聚合物B溶解在由卤化烃溶剂和低级醇溶剂组成的混合溶剂中,该混合溶剂的浊度为60%以下。

    Peroxyesters of sorbic acid
    3.
    发明授权
    Peroxyesters of sorbic acid 失效
    山梨酸过氧化物

    公开(公告)号:US4045463A

    公开(公告)日:1977-08-30

    申请号:US671553

    申请日:1976-03-29

    摘要: Stable peroxyesters containing both conjugated diene and peroxidic groups in their molecule; e.g., t-butylperoxysorbate, t-hexylperoxysorbate, 1,1,3,3-tetra-methylbutylperoxysorbate, are copolymerizable with other polymerizable monomers and the said compounds are useful for polymerizing monomers as free radical initiators.

    摘要翻译: 在其分子中含有共轭二烯和过氧化物基团的稳定的过氧酯; 例如过氧化硫酸叔丁酯,过氧化硫酸叔己酯,1,1,3,3-四甲基丁基过氧化硫酸盐,可与其它可聚合单体共聚,所述化合物可用于将单体作为自由基引发剂进行聚合。

    HYDROGEL PARTICLES
    4.
    发明申请
    HYDROGEL PARTICLES 失效
    水凝胶颗粒

    公开(公告)号:US20120288457A1

    公开(公告)日:2012-11-15

    申请号:US13519002

    申请日:2010-12-16

    IPC分类号: A61K8/92 A61Q17/04 A61K8/04

    摘要: Hydrogel particles include: a continuous phase of non-crosslinked hydrogel; and a dispersed phase dispersed in the continuous phase. The dispersed phase includes a crystalline organic UV absorber and a solid fat having an organic value (OV) of 310 or more and an inorganic value (IV) of 130 or more on an organic conceptual diagram. The content of the crystalline organic UV absorber in the dispersed phase is 15-70 mass %.

    摘要翻译: 水凝胶颗粒包括:非交联水凝胶的连续相; 分散在连续相中的分散相。 在有机概念图中,分散相包括结晶有机UV吸收剂和有机值(OV)为310以上且无机值(IV)为130以上的固体脂肪。 分散相中的结晶性有机紫外线吸收剂的含量为15〜70质量%。

    FLAME-RETARDANT SPUN-DYED POLYSETE FIBER, FLAME- RETARDANT MATERIAL COMPRISING THE SAME, AND PROCESS FOR PRODUCING FLAME-RETARDANT SPUN-DYED POLYESTER FIBER
    5.
    发明申请
    FLAME-RETARDANT SPUN-DYED POLYSETE FIBER, FLAME- RETARDANT MATERIAL COMPRISING THE SAME, AND PROCESS FOR PRODUCING FLAME-RETARDANT SPUN-DYED POLYESTER FIBER 审中-公开
    阻燃SPUN-DEDED POLYSETE纤维,包含其的阻燃材料以及制造阻燃SPUN-DYED聚酯纤维的方法

    公开(公告)号:US20110086225A1

    公开(公告)日:2011-04-14

    申请号:US12918485

    申请日:2009-07-02

    摘要: [Problem]A method by which a flame proofing property can easily be provided to polyester fiber having long-term stable color and excellent mechanical properties, particularly, a resin composition and a flame proofing method needed for flame retardant spun-dyed polyester fiber which is excellent in light resistance and durability, and is capable of coloring any of various colors, and also, is environment-friendly, are strongly desired.□Solution□There is provided a flame retardant spun-dyed polyester fiber obtained by melt-spinning a flame retardant polyester resin composition comprising a flame retardant comprising at least one inorganic phosphorus-nitrogen based compound selected from the group consisting of ammonium polyphosphate, melamine polyphosphate and phosphazenes; colorant; and thermoplastic polyester resin, characterized in that content of said inorganic phosphorus-nitrogen based compound is 0.1 to 12% by mass, content of said colorant is 0.01 to 5% by mass, and content of said thermoplastic polyester resin is 83 to 99.89% by mass, based on the total weight of said polyester resin composition. Particularly, when disposed polyester is used as the thermoplastic polyester resin, it contributes to material recycle as well.

    摘要翻译: [问题]能够容易地提供具有长期稳定的颜色和优异的机械性能的聚酯纤维的阻燃性的方法,特别是阻燃纺色涤纶纤维所需的树脂组合物和阻燃方法,其为 优异的耐光性和耐久性,并且能够着色各种颜色,并且也是环保的,是强烈期望的。 □溶液□提供通过将阻燃聚酯树脂组合物熔融纺丝而获得的阻燃纺色聚酯纤维,其包含阻燃剂,所述阻燃剂包含至少一种选自多磷酸铵,多磷酸三聚氰胺, 和磷腈; 着色剂 和热塑性聚酯树脂,其特征在于,所述无机磷 - 氮化合物的含量为0.1〜12质量%,所述着色剂的含量为0.01〜5质量%,所述热塑性聚酯树脂的含量为83〜99.89% 基于所述聚酯树脂组合物的总重量。 特别地,当使用聚酯作为热塑性聚酯树脂时,它也有助于材料再循环。

    Cowl-top cover
    6.
    发明申请
    Cowl-top cover 有权
    顶盖

    公开(公告)号:US20060186704A1

    公开(公告)日:2006-08-24

    申请号:US11064699

    申请日:2005-02-23

    IPC分类号: B62D25/08

    摘要: A cowl-top cover for a vehicle having a bonnet hood, a windshield and a well disposed therebetween, is provided with a fixation portion fixed to a body panel of the vehicle on a side of the bonnet hood; an engaging portion including a bottom, the engaging portion being configured to conceal and slidably pinch an end portion of the windshield so that a space portion is defined by the end portion and the bottom; and a main body portion linking the fixation portion with the engaging portion and covering the well, the main body being configured to be deformed by an applied impact force and allow sliding movement of the engaging portion in a direction where the bottom moves toward the end portion of the windshield.

    摘要翻译: 一种用于车辆的顶盖,具有发动罩罩,挡风玻璃和设置在其间的井,具有固定在发动罩罩侧面上的车辆车身板的固定部分; 包括底部的接合部分,所述接合部分被构造成隐藏和可滑动地夹住所述挡风玻璃的端部,使得空间部分由所述端部和所述底部限定; 以及主体部分,其将固定部分与接合部分连接并覆盖该井,该主体构造成通过施加的冲击力而变形,并允许接合部分在底部向端部移动的方向上的滑动运动 的挡风玻璃

    Process for producing (meth)acrylate derivatives
    7.
    发明授权
    Process for producing (meth)acrylate derivatives 有权
    (甲基)丙烯酸酯衍生物的制造方法

    公开(公告)号:US5981786A

    公开(公告)日:1999-11-09

    申请号:US230605

    申请日:1999-01-27

    IPC分类号: C07F9/09 C07F9/6574 C07F9/10

    CPC分类号: C07F9/65742 C07F9/091

    摘要: A process for producing a (meth)acrylate derivative including reacting a compound of formula (1) (wherein R.sup.1 is H or CH.sub.3 ; A is C.sub.1 -C.sub.10 alkylene; and p is 1 to 10) with a chloro-dioxaphosphorus compound of formula (2) (wherein q is 0 or 1) in the presence of a secondary amine of formula (3) (wherein R.sup.2 and R.sub.3 are each C.sub.3 -C.sub.8 alkyl, cycloalkyl, C.sub.6 -C.sub.9 aryl, arylalkyl, etc.) to produce a (meth)acrylate derivative of formula (4) and further reacting the same with a tertiary amine of formula (5) (wherein R.sup.4, R.sup.5 and R.sup.6 are each C.sub.1 -C.sub.4 alkyl etc.) to provide a (meth)acrylate derivative of formula (6). ##STR1##

    摘要翻译: PCT No.PCT / JP98 / 02357 Sec。 371日期1999年1月27日第 102(e)日期1999年1月27日PCT提交1998年5月28日PCT公布。 公开号WO98 / 54194 日期:1988年12月3日一种制备(甲基)丙烯酸酯衍生物的方法,包括使式(1)的化合物(其中R 1为H或CH 3; A为C 1 -C 10亚烷基; p为1至10) 式(2)的二氧杂磷化合物(其中q为0或1)在式(3)的仲胺存在下(其中R 2和R 3各自为C 3 -C 8烷基,环烷基,C 6 -C 9芳基,芳基烷基等) )以制备式(4)的(甲基)丙烯酸酯衍生物,并使其与式(5)的叔胺进一步反应(其中R 4,R 5和R 6各自为C 1 -C 4烷基等),以提供(甲基) 丙烯酸酯衍生物(6)。

    Organic peroxide having a polymerization-regulating ability
    8.
    发明授权
    Organic peroxide having a polymerization-regulating ability 失效
    具有聚合调节能力的有机过氧化物

    公开(公告)号:US5210164A

    公开(公告)日:1993-05-11

    申请号:US401244

    申请日:1989-09-27

    IPC分类号: C07C409/38

    CPC分类号: C08F4/34 C08F2/38

    摘要: A novel peroxy aryl carbonate which has the both properties of polymerization-initiating and regulating abilities, can be used as a radical polymerization initiator to regulate the polymerization rate, the polymerization degree and molecular weight distribution of the polymer and the like, and therefore produce superior styrene resin and methyl methacrylate syrup.

    摘要翻译: 具有聚合引发和调节能力两者性质的新型过氧化芳基碳酸酯可用作自由基聚合引发剂以调节聚合物的聚合速率,聚合度和分子量分布等,因此产生优异的 苯乙烯树脂和甲基丙烯酸甲酯糖浆。

    Polyolefin-based plastic composition and automotive molded article
formed thereof
    10.
    发明授权
    Polyolefin-based plastic composition and automotive molded article formed thereof 失效
    聚烯烃类塑料组合物和由其形成的汽车模塑制品

    公开(公告)号:US5965654A

    公开(公告)日:1999-10-12

    申请号:US838986

    申请日:1997-04-23

    CPC分类号: C08L53/00

    摘要: A polyolefin-based plastic composition suitable for an automotive molded pillar member such as a pillar garnish. The plastic composition comprises (A) block copolymer in an amount ranging from 53 to 68 parts by weight, the block copolymer having a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) ranging from 20 to 50 g/10 min. and containing crystalline polypropylene section in an amount ranging from 90 to 95% by weight, having a density of not lower than 0.908 g/cm.sup.3, and propylene-ethylene random copolymer section in an amount ranging from 5 to 10% by weight, the propylene-ethylene random copolymer section having an ethylene content ranging from 35 to 45% by weight; (B) ethylene-1-butene copolymer rubber in an amount ranging from 12 to 20 parts by weight and having a density ranging from 0.85 to 0.87 g/cm.sup.3 and a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) ranging from 0.2 to 5 g/10 min., the copolymer rubber containing 1-butene in an amount ranging from 30 to 40% by weight; and (C) talc in an amount ranging from 22 to 30 parts by weight and having a length not more than 15 .mu.m and an average particle size ranging from 1.5 to 6 .mu.m, the talc having an average aspect ratio not lower than 5. The polyolefin-based plastic composition has a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) not lower than 8 g/10 min., a Flexural Elastic Modulus not lower than 1960 MPa when molded, and an IZOD not lower than 0.088 KJ/m when molded, and a Rockwell hardness (in R scale) not lower than 65 when molded.

    摘要翻译: 适合汽车模制支柱构件如支柱装饰的聚烯烃基塑料组合物。 塑料组合物包含(A)53至68重量份的嵌段共聚物,嵌段共聚物具有20至50g / 10min的熔体流动速率(230℃和2.16kg)。 并且含有90至95重量%的结晶聚丙烯截面,其密度不低于0.908g / cm3,丙烯 - 乙烯无规共聚物部分的量为5至10重量%,丙烯 乙烯无规共聚物部分,其乙烯含量为35至45重量%; (B)乙烯-1-丁烯共聚物橡胶,其量为12至20重量份,密度范围为0.85至0.87g / cm 3,熔体流动速率(230℃和2.16kg)范围内 0.2〜5g / 10分钟,含有1-40重量%的1-丁烯的共聚物橡胶; 和(C)滑石,其量为22〜30重量份,长度不大于15μm,平均粒径为1.5〜6μm,滑石的平均纵横比不小于5 聚烯烃类塑料组合物的熔体流动速率(230℃,2.16kg以下)不低于8g / 10min,模塑时的挠曲弹性模量不低于1960MPa,IZOD不低于 成型时为0.088KJ / m,成型时的洛氏硬度(R刻度)不低于65。