摘要:
A method for producing an aqueous solution of a polymer having a phosphorylcholine group in which a polymerizable composition containing a polymerizable monomer having the phosphorylcholine group represented by the formula (1) is polymerized in the presence of a non-metal polymerization initiator soluble in a water-containing medium, to obtain a crude polymer aqueous solution, and the crude polymer aqueous solution is purified with a separation membrane, and an aqueous solution of the polymer having the phosphorylcholine group obtained by the method and having not more than 2000 ppm of impurities. (X: a divalent organic residue, Y: an alkyleneoxy group having C1 to 6, Z: H, R5—O—CO—(R5: an alkyl group of C1 to 10), R1:H, CH3, R2, R3, R4: H, a hydrocarbon group or a hydroxy substituted hydrocarbon group of C1 to 6, m; 0 or 1)
摘要:
A high molecular material and a medical material which is a mixed material containing a copolymer A produced by copolymerization of a monomer composition containing a monomer having a side chain represented by the formula (1) ##STR1## (R.sup.1, R.sup.2, R.sup.3 ; H or a C1-4 alkyl group) and a hydrophobic monomer, and one or more sorts of hydrophobic polymer B other than the copolymer A; wherein structure of said mixed material shows phase separation in which domains of several hundred micrometers or less in size consisting of the copolymer A are uniformly distributed in a phase consisting of said hydrophobic polymer B. A liquid high molecular composition in which the copolymer A and the hydrophobic polymer B are dissolved in a mixed solvent consisting of a halogenated hydrocarbon solvent and a lower alcohol solvent, which has turbidity of 60% or less.
摘要:
Stable peroxyesters containing both conjugated diene and peroxidic groups in their molecule; e.g., t-butylperoxysorbate, t-hexylperoxysorbate, 1,1,3,3-tetra-methylbutylperoxysorbate, are copolymerizable with other polymerizable monomers and the said compounds are useful for polymerizing monomers as free radical initiators.
摘要:
Hydrogel particles include: a continuous phase of non-crosslinked hydrogel; and a dispersed phase dispersed in the continuous phase. The dispersed phase includes a crystalline organic UV absorber and a solid fat having an organic value (OV) of 310 or more and an inorganic value (IV) of 130 or more on an organic conceptual diagram. The content of the crystalline organic UV absorber in the dispersed phase is 15-70 mass %.
摘要:
[Problem]A method by which a flame proofing property can easily be provided to polyester fiber having long-term stable color and excellent mechanical properties, particularly, a resin composition and a flame proofing method needed for flame retardant spun-dyed polyester fiber which is excellent in light resistance and durability, and is capable of coloring any of various colors, and also, is environment-friendly, are strongly desired.□Solution□There is provided a flame retardant spun-dyed polyester fiber obtained by melt-spinning a flame retardant polyester resin composition comprising a flame retardant comprising at least one inorganic phosphorus-nitrogen based compound selected from the group consisting of ammonium polyphosphate, melamine polyphosphate and phosphazenes; colorant; and thermoplastic polyester resin, characterized in that content of said inorganic phosphorus-nitrogen based compound is 0.1 to 12% by mass, content of said colorant is 0.01 to 5% by mass, and content of said thermoplastic polyester resin is 83 to 99.89% by mass, based on the total weight of said polyester resin composition. Particularly, when disposed polyester is used as the thermoplastic polyester resin, it contributes to material recycle as well.
摘要:
A cowl-top cover for a vehicle having a bonnet hood, a windshield and a well disposed therebetween, is provided with a fixation portion fixed to a body panel of the vehicle on a side of the bonnet hood; an engaging portion including a bottom, the engaging portion being configured to conceal and slidably pinch an end portion of the windshield so that a space portion is defined by the end portion and the bottom; and a main body portion linking the fixation portion with the engaging portion and covering the well, the main body being configured to be deformed by an applied impact force and allow sliding movement of the engaging portion in a direction where the bottom moves toward the end portion of the windshield.
摘要:
A process for producing a (meth)acrylate derivative including reacting a compound of formula (1) (wherein R.sup.1 is H or CH.sub.3 ; A is C.sub.1 -C.sub.10 alkylene; and p is 1 to 10) with a chloro-dioxaphosphorus compound of formula (2) (wherein q is 0 or 1) in the presence of a secondary amine of formula (3) (wherein R.sup.2 and R.sub.3 are each C.sub.3 -C.sub.8 alkyl, cycloalkyl, C.sub.6 -C.sub.9 aryl, arylalkyl, etc.) to produce a (meth)acrylate derivative of formula (4) and further reacting the same with a tertiary amine of formula (5) (wherein R.sup.4, R.sup.5 and R.sup.6 are each C.sub.1 -C.sub.4 alkyl etc.) to provide a (meth)acrylate derivative of formula (6). ##STR1##
摘要:
A novel peroxy aryl carbonate which has the both properties of polymerization-initiating and regulating abilities, can be used as a radical polymerization initiator to regulate the polymerization rate, the polymerization degree and molecular weight distribution of the polymer and the like, and therefore produce superior styrene resin and methyl methacrylate syrup.
摘要:
An aqueous suspension of a solid organic peroxide is produced by mixing a solid organic peroxide having a difference of at least 5.degree. C. between the melting point and the thermal decomposition temperature thereof with a protective colloid, a surface active agent, and water thereby forming an aqueous emulsion and subsequently cooling this aqueous emulsion.
摘要:
A polyolefin-based plastic composition suitable for an automotive molded pillar member such as a pillar garnish. The plastic composition comprises (A) block copolymer in an amount ranging from 53 to 68 parts by weight, the block copolymer having a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) ranging from 20 to 50 g/10 min. and containing crystalline polypropylene section in an amount ranging from 90 to 95% by weight, having a density of not lower than 0.908 g/cm.sup.3, and propylene-ethylene random copolymer section in an amount ranging from 5 to 10% by weight, the propylene-ethylene random copolymer section having an ethylene content ranging from 35 to 45% by weight; (B) ethylene-1-butene copolymer rubber in an amount ranging from 12 to 20 parts by weight and having a density ranging from 0.85 to 0.87 g/cm.sup.3 and a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) ranging from 0.2 to 5 g/10 min., the copolymer rubber containing 1-butene in an amount ranging from 30 to 40% by weight; and (C) talc in an amount ranging from 22 to 30 parts by weight and having a length not more than 15 .mu.m and an average particle size ranging from 1.5 to 6 .mu.m, the talc having an average aspect ratio not lower than 5. The polyolefin-based plastic composition has a Melt Flow Rate (at 230.degree. C. and under 2.16 kg) not lower than 8 g/10 min., a Flexural Elastic Modulus not lower than 1960 MPa when molded, and an IZOD not lower than 0.088 KJ/m when molded, and a Rockwell hardness (in R scale) not lower than 65 when molded.