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    Pigment dispersions containing dispersants prepared by controlled radical polymerization
    1.
    发明授权
    Pigment dispersions containing dispersants prepared by controlled radical polymerization 失效
    含有通过控制自由基聚合制备的分散剂的颜料分散体

    公开(公告)号：US06326420B1

    公开(公告)日：2001-12-04

    申请号：US09464947

    申请日：1999-12-16

    申请人： Kevin C. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Karl F. Schimmel

    发明人： Kevin C. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Karl F. Schimmel

    IPC分类号： C08L300

    CPC分类号： C09B67/009 ,  C09D17/001

    摘要： A pigment dispersion which includes a pigment, an aqueous carrier and a pigment dispersant. The pigment dispersant is prepared by controlled radical polymerization initiated in the presence of a monomeric initiator having at least two radically transferable groups. The pigment dispersant has at least one of the following polymer chain structures: &phgr;-[(G)p—(E)s—T]z and &phgr;-[(E)3—(G)p—T]z where G is a hydrophobic residue of at least one radically polymerizable ethylenically unsaturated monomer; E is a hydrophilic residue of at least one radically polymerizable ethylenically unsaturated monomer; &phgr; is a residue of or derived from the initiator, and is free of the radically transferable group; T is or is derived from the radically transferable group of the initiator; z is 2 to 10; p and s are at least one and are selected such that the pigment dispersant has a number average molecular weight of at least 500.

    摘要翻译： 颜料分散体，其包含颜料，水性载体和颜料分散剂。 在具有至少两个可自由基转移基团的单体引发剂的存在下引发的受控自由基聚合来制备颜料分散剂。 颜料分散剂具有以下聚合物链结构中的至少一种：其中G是至少一个可自由基聚合的烯属不饱和单体的疏水残基; E是至少一种可自由基聚合的烯属不饱和单体的亲水性残基; phi是引发剂的残基或衍生自起始物，不含可自由基转移基团; T衍生自引发剂的可自由转移基团; z为2〜10; p和s是至少一个，并且被选择为使得颜料分散剂的数均分子量为至少500。

    Multi-functional initiators for atom transfer radical (Co)polymerization
    2.
    发明授权
    Multi-functional initiators for atom transfer radical (Co)polymerization 失效
    用于原子转移自由基（Co）聚合的多官能引发剂

    公开(公告)号：US06590049B1

    公开(公告)日：2003-07-08

    申请号：US09687026

    申请日：2000-10-13

    申请人： James B. O'Dwyer ,  Kevin C. Olson ,  Simion Coca ,  Brian E. Woodworth

    发明人： James B. O'Dwyer ,  Kevin C. Olson ,  Simion Coca ,  Brian E. Woodworth

    IPC分类号： C08F200

    CPC分类号： C09D17/001 ,  C08F4/00 ,  C09B67/009

    摘要： The present invention is directed to novel compounds that can serve as highly efficient initiators for controlled radical (co)polymerization processes including atom transfer radical (co)polymerization processes. These compounds include di-(trimethylolpropane)-tetra-(2-haloisobutyrate) compounds. The present invention also is directed to controlled radical (co)polymerization processes in which novel (co)polymers are prepared using the novel compounds, as well as to the novel (co)polymer products of the process.

    摘要翻译： 本发明涉及可用作用于受控自由基（共）聚合方法的高效引发剂的新型化合物，包括原子转移自由基（共）聚合方法。 这些化合物包括二（三羟甲基丙烷） - 四 - （2-卤代异丁酸酯）化合物。 本发明还涉及使用新化合物以及该方法的新型（共）聚合物产物制备新型（共）聚合物的受控自由基（共）聚合方法。

    Copolymers comprising low surface tension (meth) acrylates
    3.
    发明授权
    Copolymers comprising low surface tension (meth) acrylates 失效
    包含低表面张力（甲基）丙烯酸酯的共聚物

    公开(公告)号：US06841641B2

    公开(公告)日：2005-01-11

    申请号：US10237357

    申请日：2002-09-09

    申请人： Kurt G. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Joanne H. Smith

    发明人： Kurt G. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Joanne H. Smith

    IPC分类号： C08F220/10 ,  C08F20/22 ,  C08F220/22 ,  C08F230/08

    CPC分类号： C08F220/10

    摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.

    摘要翻译： 本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。 共聚物的多分散指数小于2.5。 本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。 该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。

    Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments
    4.
    发明授权
    Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments 有权
    含有通过具有亲水和疏水链段的受控自由基聚合制备的分散剂的颜料分散体

    公开(公告)号：US06642301B2

    公开(公告)日：2003-11-04

    申请号：US10217621

    申请日：2002-08-13

    申请人： Daniela White ,  Simion Coca ,  James B. O'Dwyer

    发明人： Daniela White ,  Simion Coca ,  James B. O'Dwyer

    IPC分类号： C08J3100

    CPC分类号： C09D17/001 ,  C09B67/009

    摘要： A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, and has polymer chain structure represented by the following general formula I, &phgr;-(G)p-(E)s-T  I In general formula I, G is a residue of at least one radically polymerizable ethylenically unsaturated monomer; E is a hydrophilic residue of at least one radically polymerizable ethylenically unsaturated monomer; G and E are different from one another; &phgr; is a hydrophobic residue of or derived from the initiator, and is free of said radically transferable group; T is or is derived from the radically transferable group of the initiator; p and s represent average numbers of residues occurring in a block of residues; p and s are each individually selected such that the pigment dispersant has a number average molecular weight of at least 250.

    摘要翻译： 描述了包含颜料，选自水和水与至少一种有机溶剂的混合物的水性载体和颜料分散剂的颜料分散体。 颜料分散剂是通过控制自由基聚合制备的，例如原子转移自由基聚合，并具有由以下通式I表示的聚合物链结构。通式I中，G是至少一个可自由基聚合的烯属不饱和单体的残基; E是至少一种可自由基聚合的烯属不饱和单体的亲水性残基; G和E是不同的; phi是引发剂的疏水性残基或衍生自引发剂，并且不含所述可自由基转移基团; T衍生自引发剂的可自由转移基团; p和s表示残基块中发生的残基的平均数; p和s各自独立选择，使得颜料分散剂的数均分子量至少为250。

    Copolymers comprising low surface tension (meth)acrylates
    5.
    发明申请
    Copolymers comprising low surface tension (meth)acrylates 审中-公开
    包含低表面张力（甲基）丙烯酸酯的共聚物

    公开(公告)号：US20080255307A1

    公开(公告)日：2008-10-16

    申请号：US12132928

    申请日：2008-06-04

    申请人： Kurt G. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Joanne H. Smith

    发明人： Kurt G. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Joanne H. Smith

    IPC分类号： C08G63/00

    CPC分类号： C08F220/10

    摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.

    摘要翻译： 本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。 共聚物的多分散指数小于2.5。 本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。 该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。

    Method of making alternating copolymers of isobutylene type monomers
    9.
    发明授权
    Method of making alternating copolymers of isobutylene type monomers 失效
    制备异丁烯型单体的交替共聚物的方法

    公开(公告)号：US06677422B2

    公开(公告)日：2004-01-13

    申请号：US10077559

    申请日：2002-02-15

    申请人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

    发明人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

    IPC分类号： C08F1000

    CPC分类号： C08F220/12

    摘要： A method of making a copolymer composition containing a copolymer, which includes the steps of (a) providing a donor monomer composition that includes an isobutylene type monomer; (b) mixing the donor monomer composition with an ethylenically unsaturated monomer composition that includes one or more ethylenically unsaturated acceptor monomers, and is substantially free of maleate type monomers and fumarate type monomers, and (c) polymerizing the mixture resulting from step (b) in the presence of a free radical polymerization initiator. The polymerization is carried out in the substantial absence of Lewis acids and/or transition metals. The isobutylene type monomer is present at a molar excess of at least 10 mol % based on the molar concentration of monomers in the ethylenically unsaturated monomer composition. The ethylenically unsaturated acceptor monomers are present in an amount of at least 15 mol % of the total monomer composition.

    摘要翻译： 一种制备含有共聚物的共聚物组合物的方法，其包括以下步骤：（a）提供包含异丁烯型单体的供体单体组合物; （b）将供体单体组合物与包含一种或多种烯键式不饱和受体单体的烯属不饱和单体组合物混合，并且基本上不含马来酸盐型单体和富马酸盐型单体，和（c）将由步骤（b）得到的混合物聚合， 在自由基聚合引发剂存在下进行。 基本上不存在路易斯酸和/或过渡金属进行聚合。 基于烯属不饱和单体组合物中单体的摩尔浓度，异丁烯型单体的摩尔过量为至少10摩尔％。 烯属不饱和受体单体的存在量为总单体组合物的至少15摩尔％。

    Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments
    10.
    发明授权
    Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments 失效
    含有通过具有亲水和疏水链段的受控自由基聚合制备的分散剂的颜料分散体

    公开(公告)号：US06462125B1

    公开(公告)日：2002-10-08

    申请号：US09464946

    申请日：1999-12-16

    申请人： Daniela White ,  Simion Coca ,  James B. O'Dwyer

    发明人： Daniela White ,  Simion Coca ,  James B. O'Dwyer

    IPC分类号： C08J3100

    CPC分类号： C09D17/001 ,  C09B67/009

    摘要： A pigment dispersion that includes a pigment, an aqueous carrier, and a pigment dispersant. The pigment dispersant is prepared by atom transfer radical polymerization initiated and has the polymer chain structure: &phgr;—(G)p—(E)a—T where G is a residue of at least One ethylenically unsaturated monomer; E is a hydrophilic residue of at least one ethylenically unsaturated monomer; &phgr; is a hydrophobic residue of or derived from an initiator; T is or is derived from a radically transferable group from the initiator, p and s represent average numbers of residues occurring in a block of residues; p and s are each individually selected such that said pigment dispersant has a number average molecular weight of at least 250.

    摘要翻译： 包含颜料，水性载体和颜料分散剂的颜料分散体。 颜料分散剂通过引发原子转移自由基聚合制备，并具有聚合物链结构：其中G是至少一个烯属不饱和单体的残基; E是至少一种烯属不饱和单体的亲水性残基; phi是引发剂的疏水残基或衍生自引发剂; T是衍生自起始基团的可自由转移的基团，p和s代表在残基块中发生的残基的平均数; p和s各自单独选择，使得所述颜料分散剂的数均分子量为至少250。