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    Preparation of saturated imidazolinium salts and related compounds
    1.
    发明授权
    Preparation of saturated imidazolinium salts and related compounds 有权
    饱和咪唑啉盐和相关化合物的制备

    公开(公告)号：US08703965B2

    公开(公告)日：2014-04-22

    申请号：US12741568

    申请日：2008-11-10

    申请人： Kevin Kuhn ,  Robert H. Grubbs

    发明人： Kevin Kuhn ,  Robert H. Grubbs

    IPC分类号： C07D233/06

    CPC分类号： C07D233/06 ,  C07D239/06

    摘要： Methods for the preparation of saturated imidazolinium salts and related compounds that comprises reaction of formamidines with compounds such as dihaloethane and an optional base are disclosed. Alternatively, the imidazolinium salts and related compounds can be prepared in a one-step process without purification of the formamidine reactant. These methods make it possible to obtain numerous imidazolinium salts and related compounds under solvent-free reaction conditions and in excellent yields.

    摘要翻译： 公开了制备饱和咪唑啉盐和相关化合物的方法，其包括甲酰胺与诸如二卤代乙烷和任选碱的化合物的反应。 或者，咪唑啉鎓盐和相关化合物可以以一步法制备而不净化甲脒反应物。 这些方法使得可以在无溶剂反应条件下以优异的产率获得许多咪唑啉鎓盐和相关化合物。

    PREPARATION OF SATURATED IMIDAZOLINIUM SALTS AND RELATED COMPOUNDS
    2.
    发明申请
    PREPARATION OF SATURATED IMIDAZOLINIUM SALTS AND RELATED COMPOUNDS 有权
    饱和脂肪酸钠盐及相关化合物的制备

    公开(公告)号：US20110087032A1

    公开(公告)日：2011-04-14

    申请号：US12741568

    申请日：2008-11-10

    申请人： Kevin Kuhn ,  Robert H. Grubbs

    发明人： Kevin Kuhn ,  Robert H. Grubbs

    IPC分类号： C07D233/06

    CPC分类号： C07D233/06 ,  C07D239/06

    摘要： Methods for the preparation of saturated imidazolinium salts and related compounds that comprises reaction of formamidines with compounds such as dihaloethane and an optional base are disclosed. Alternatively, the imidazolinium salts and related compounds can be prepared in a one-step process without purification of the formamidine reactant. These methods make it possible to obtain numerous imidazolinium salts and related compounds under solvent-free reaction conditions and in excellent yields.

    摘要翻译： 公开了制备饱和咪唑啉盐和相关化合物的方法，其包括甲酰胺与诸如二卤代乙烷和任选碱的化合物的反应。 或者，咪唑啉鎓盐和相关化合物可以以一步法制备而不净化甲脒反应物。 这些方法使得可以在无溶剂反应条件下以优异的产率获得许多咪唑啉鎓盐和相关化合物。

    Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins
    7.
    发明授权
    Organometallic ruthenium complexes and related methods for the preparation of tetra-substituted and other hindered olefins 有权
    有机金属钌络合物及制备四取代的和其他受阻烯烃的相关方法

    公开(公告)号：US08008224B2

    公开(公告)日：2011-08-30

    申请号：US11640400

    申请日：2006-12-18

    申请人： Jacob Berlin ,  Robert H. Grubbs ,  Yann Schrodi ,  Ian C. Stewart

    发明人： Jacob Berlin ,  Robert H. Grubbs ,  Yann Schrodi ,  Ian C. Stewart

    IPC分类号： B01J31/00 ,  C07F17/02

    CPC分类号： C07F15/0046 ,  B01J31/2265 ,  B01J31/2404 ,  B01J2231/543 ,  B01J2531/821 ,  C08G61/08

    摘要： The invention relates to ruthenium alkylidene complexes having an N-heterocyclic carbene ligand comprising a 5-membered heterocyclic ring having a carbenic carbon atom and at least one nitrogen atom contained within the 5-membered heterocyclic ring, wherein the nitrogen atom is directly attached to the carbenic carbon atom and is substituted by a phenyl ring, and wherein the phenyl ring has a hydrogen at either or both ortho positions and is substituted at at least one ortho or meta position. The invention also relates to an olefin metathesis reactions and particularly to the preparation of tetra-substituted cyclic olefins via a ring-closing metathesis.

    摘要翻译： 本发明涉及具有N-杂环卡宾配位体的钌亚烷基配合物，其包括具有碳原子数为5元的五元杂环和至少一个含有5元杂环的氮原子，其中氮原子直接连接到 碳原子并被苯环取代，并且其中苯环在一个或两个邻位具有氢，并且在至少一个邻位或间位取代。 本发明还涉及烯烃复分解反应，特别涉及通过闭环复分解制备四取代环烯烃。

    High metathesis activity ruthenium and osmium carbene complexes
    8.
    发明授权
    High metathesis activity ruthenium and osmium carbene complexes 失效
    高复分解活性钌和咔唑络合物

    公开(公告)号：US07750172B2

    公开(公告)日：2010-07-06

    申请号：US11929358

    申请日：2007-10-30

    申请人： Robert H. Grubbs ,  Peter Schwab ,  Sonbinh T. Nguyen

    发明人： Robert H. Grubbs ,  Peter Schwab ,  Sonbinh T. Nguyen

    IPC分类号： C07F15/00 ,  B01J31/00 ,  C08F4/42

    CPC分类号： C08F4/80 ,  B01J31/18 ,  B01J31/2265 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07F15/002 ,  C07F15/0046 ,  C08F32/00 ,  C08G61/08

    摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.

    摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。