公开(公告)号：US20150111723A1

公开(公告)日：2015-04-23

申请号：US14560421

申请日：2014-12-04

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Michael Brady ,  Dennis Stamires

IPC: B01J21/16 ,  B01J23/10 ,  B01J23/26 ,  B01J23/06 ,  B01J23/78 ,  B01J23/08 ,  B01J23/02 ,  B01J23/00 ,  B01J27/18 ,  B01J23/34

CPC classification number: B01J21/16 ,  B01J21/005 ,  B01J23/005 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/1806 ,  C10B53/02 ,  C10B57/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/08 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.

Abstract translation: 本文公开了一种生物质催化裂化方法。 更具体地说，该方法是存在由式（X1O）表示的混合金属氧化物催化剂（X 2 O）a。（X 3 Y b O 4）其中X 1，X 2和X 3是选自Mg，Ca， Be，Ba及其混合物，Y是选自Al，Mn，Fe，Co，Ni，Cr，Ga，B，La，P及其混合物的金属，其中催化剂通过至少煅烧形成 一种化合物，其包含至少一种碱土金属元素和金属元素。

公开(公告)号：US09700874B2

公开(公告)日：2017-07-11

申请号：US14560421

申请日：2014-12-04

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Michael Brady ,  Dennis Stamires

IPC: B01J21/00 ,  B01J21/16 ,  C10G1/00 ,  C10G3/00 ,  B01J23/00 ,  C10L1/08 ,  C10G1/06 ,  C10G1/08 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/18 ,  C10B53/02 ,  C10B57/06

CPC classification number: B01J21/16 ,  B01J21/005 ,  B01J23/005 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/1806 ,  C10B53/02 ,  C10B57/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/08 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.

公开(公告)号：US09649624B2

公开(公告)日：2017-05-16

申请号：US14705800

申请日：2015-05-06

Applicant: KiOR, Inc.

Inventor： Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hacskaylo

IPC: C10L1/00 ,  B01J29/40 ,  C10G3/00 ,  B01J37/00 ,  B01J37/28 ,  C10L1/04

CPC classification number: B01J29/40 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/49 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02P30/20

Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

公开(公告)号：US20150291886A1

公开(公告)日：2015-10-15

申请号：US14695916

申请日：2015-04-24

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Steve Yanik

IPC: C10G1/06

CPC classification number: C10G1/06 ,  C10G1/00 ,  C10G1/08 ,  C10G1/10 ,  C10G3/42 ,  C10G2300/1011 ,  Y02P30/20

Abstract: Disclosed is a process for biomass conversion which includes co-processing the biomass with thermoplastic and non-thermoplastic polymer based materials in a catalytic pyrolysis reactor to convert such to liquid hydrocarbons; wherein hydrogen atoms originating with the polymer materials can remove oxygen from oxygenated hydrocarbons produced in the conversion of the biomass in the reactor.

Abstract translation: 公开了一种生物质转化方法，其包括在催化裂解反应器中将生物质与热塑性和非热塑性聚合物基材料共同加工以转化为液体烃; 其中源自聚合物材料的氢原子可以从反应器中的生物质转化中产生的氧化烃中除去氧气。

公开(公告)号：US20150231613A1

公开(公告)日：2015-08-20

申请号：US14705800

申请日：2015-05-06

Applicant: KiOR, Inc.

Inventor： Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hackskaylo

IPC: B01J29/40 ,  C10L1/04 ,  C10G3/00 ,  B01J37/28 ,  B01J37/00

CPC classification number: B01J29/40 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/49 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02P30/20

Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

Abstract translation: 公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。 更具体地，提供了用于生产转化催化剂的方法。 该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型成成形的状态。 这种催化剂可用于将颗粒生物质转化为液体产物如生物油的热催化转化，导致比常规催化剂更高的生物油产率和更低的焦炭。