公开(公告)号：US20150203763A1

公开(公告)日：2015-07-23

申请号：US14671335

申请日：2015-03-27

Applicant: KiOR, Inc.

Inventor： Michael Brady ,  Ronald Lee Cordle ,  Peter Loezos ,  Dennis Stamires

IPC: C10G1/00 ,  B01J8/24 ,  C10G1/02

CPC classification number: C10G1/002 ,  B01J8/24 ,  B01J23/90 ,  B01J29/90 ,  B01J38/12 ,  B01J2208/00769 ,  C10B49/22 ,  C10B53/02 ,  C10B57/18 ,  C10G1/02 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/4081 ,  C10G2300/4093 ,  Y02E50/14 ,  Y02P20/133 ,  Y02P20/145 ,  Y02P30/20 ,  Y02T50/678

Abstract: A two-stage reactor is disclosed for the conversion of solid particulate biomass material. The reactor is designed to maximize conversion of the solid biomass material, while limiting excess cracking of primary reaction products. The two-stage reactor comprises a first stage rector, in which solid biomass material is thermally pyrolyzed to primary reaction products. The primary reaction products are catalytically converted in a second stage reactor.

Abstract translation: 公开了用于转化固体颗粒生物质材料的两级反应器。 设计反应器以使固体生物质材料的转化率最大化，同时限制初级反应产物的过量裂解。 两级反应器包括第一级反应器，其中固体生物质材料被热解为初级反应产物。 初级反应产物在第二级反应器中催化转化。

公开(公告)号：US20150111723A1

公开(公告)日：2015-04-23

申请号：US14560421

申请日：2014-12-04

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Michael Brady ,  Dennis Stamires

IPC: B01J21/16 ,  B01J23/10 ,  B01J23/26 ,  B01J23/06 ,  B01J23/78 ,  B01J23/08 ,  B01J23/02 ,  B01J23/00 ,  B01J27/18 ,  B01J23/34

CPC classification number: B01J21/16 ,  B01J21/005 ,  B01J23/005 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/1806 ,  C10B53/02 ,  C10B57/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/08 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.

Abstract translation: 本文公开了一种生物质催化裂化方法。 更具体地说，该方法是存在由式（X1O）表示的混合金属氧化物催化剂（X 2 O）a。（X 3 Y b O 4）其中X 1，X 2和X 3是选自Mg，Ca， Be，Ba及其混合物，Y是选自Al，Mn，Fe，Co，Ni，Cr，Ga，B，La，P及其混合物的金属，其中催化剂通过至少煅烧形成 一种化合物，其包含至少一种碱土金属元素和金属元素。

公开(公告)号：US08709239B2

公开(公告)日：2014-04-29

申请号：US13892728

申请日：2013-05-13

Applicant: KiOR, Inc.

Inventor： Paul O'Connor ,  Dennis Stamires ,  Jacob Adriaan Moulijn

IPC: C10C3/02

CPC classification number: C10G1/086 ,  C10B49/20 ,  C10G1/08 ,  C10G11/18 ,  Y02E50/14

Abstract: A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed. In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.

Abstract translation: 公开了一种将固体或高粘度碳基能量载体材料转化为液体和气态反应产物的方法，所述方法包括以下步骤：a）使碳基能量载体材料与颗粒催化剂材料接触b）将 在200℃至450℃的反应温度下，优选250℃至350℃之间的碳基能量载体材料，从而在气相中形成反应产物。 在优选实施方案中，该方法包括以下附加步骤：c）在所述反应产物形成后10秒内从气态反应产物与颗粒状催化剂材料分离。 在另一优选实施方案中，步骤c）之后是：d）将反应产物淬灭至低于200℃的温度

公开(公告)号：US20130261355A1

公开(公告)日：2013-10-03

申请号：US13788312

申请日：2013-03-07

Applicant: KIOR, INC.

Inventor： Dennis Stamires

IPC: B01J29/82 ,  B01J29/04 ,  C10G1/08

CPC classification number: B01J29/82 ,  B01J29/04 ,  B01J29/08 ,  B01J29/40 ,  B01J29/90 ,  B01J35/08 ,  B01J35/1014 ,  B01J37/0045 ,  B01J2229/186 ,  C10G1/02 ,  C10G1/086 ,  C10G3/49 ,  C10G2300/1011 ,  Y02P30/20 ,  Y10T428/27

Abstract: Aspects of the invention relate to a catalyst system for the conversion of biomass material. In an exemplary embodiment, the catalyst system has a specific combined mesoporous and macroporous surface area in the range of from about 1 m2/g to about 100 m2/g. The catalyst system can be used in a two-stage reactor assembly unit for the catalytic thermoconversion of biomass material wherein the thermolysis process and the catalytic conversion process are optimally conducted separately.

Abstract translation: 本发明的方面涉及用于生物质材料转化的催化剂体系。 在一个示例性实施方案中，催化剂体系具有在约1m 2 / g至约100m 2 / g范围内的特定组合介孔和大孔表面积。 催化剂体系可用于生物质材料的催化热转换的两级反应器组装单元，其中热分解过程和催化转化过程分别是最佳进行的。

公开(公告)号：US09700874B2

公开(公告)日：2017-07-11

申请号：US14560421

申请日：2014-12-04

Applicant: KiOR, Inc.

Inventor： Robert Bartek ,  Michael Brady ,  Dennis Stamires

IPC: B01J21/00 ,  B01J21/16 ,  C10G1/00 ,  C10G3/00 ,  B01J23/00 ,  C10L1/08 ,  C10G1/06 ,  C10G1/08 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/18 ,  C10B53/02 ,  C10B57/06

CPC classification number: B01J21/16 ,  B01J21/005 ,  B01J23/005 ,  B01J23/007 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/78 ,  B01J27/1806 ,  C10B53/02 ,  C10B57/06 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G3/44 ,  C10G3/45 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10L1/08 ,  Y02E50/13 ,  Y02E50/14 ,  Y02E50/15 ,  Y02E50/32 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for biomass catalytic cracking is disclosed herein. More specifically, the process is in presence of is a mixed metal oxide catalyst represented by the formula (X1O).(X2O)a.(X3YbO4) wherein X1, X2 and X3 are alkaline earth elements selected from the group of Mg, Ca, Be, Ba, and mixture thereof, and Y is a metal selected from the group of Al, Mn, Fe, Co, Ni, Cr, Ga, B, La, P and mixture thereof, wherein the catalyst is formed by calcining at least one compound comprising at least one alkaline earth element and a metal element.

公开(公告)号：US20130245346A1

公开(公告)日：2013-09-19

申请号：US13892728

申请日：2013-05-13

Applicant: KIOR, INC.

Inventor： Paul O'Connor ,  Dennis Stamires ,  Jacob Adriaan Moulijn

IPC: C10G1/08

CPC classification number: C10G1/086 ,  C10B49/20 ,  C10G1/08 ,  C10G11/18 ,  Y02E50/14

Abstract: A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed. In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.

Abstract translation: 公开了一种将固体或高粘度碳基能量载体材料转化为液体和气态反应产物的方法，所述方法包括以下步骤：a）使碳基能量载体材料与颗粒催化剂材料接触b）将 在200℃至450℃的反应温度下，优选250℃至350℃之间的碳基能量载体材料，从而在气相中形成反应产物。 在优选实施方案中，该方法包括以下附加步骤：c）在所述反应产物形成后10秒内从气态反应产物与颗粒状催化剂材料分离。 在另一优选实施方案中，步骤c）之后是：d）将反应产物淬灭至低于200℃的温度

公开(公告)号：US20160017238A1

公开(公告)日：2016-01-21

申请号：US14378779

申请日：2013-02-15

Applicant: KIOR, INC.

Inventor： Dennis Stamires ,  Michael Brady

IPC: C10G3/00 ,  B01J29/70 ,  B01J29/82 ,  B01J29/40

CPC classification number: C10G3/49 ,  B01J21/16 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/82 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  Y02P30/20

Abstract: Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel of specialty chemical products are described. The catalyst system may comprise a non-zeolitic matrix and an in situ grown zeolite, such as MFI-type zeolite, with a meso-micro hierarchical pore structure. In some embodiments, the non-zeolitic matrix has a meso-macro hierarchical pore structure.

Abstract translation: 描述了制备用于将固体生物质转化为特种化学产品的燃料的催化体系和催化体系的方法。 催化剂体系可以包含非沸石基质和原位生长的沸石，例如MFI型沸石，具有中等微观层次的孔结构。 在一些实施方案中，非沸石基质具有中等 - 宏分级孔结构。

公开(公告)号：US09649624B2

公开(公告)日：2017-05-16

申请号：US14705800

申请日：2015-05-06

Applicant: KiOR, Inc.

Inventor： Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hacskaylo

IPC: C10L1/00 ,  B01J29/40 ,  C10G3/00 ,  B01J37/00 ,  B01J37/28 ,  C10L1/04

CPC classification number: B01J29/40 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/49 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02P30/20

Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

公开(公告)号：US20150231613A1

公开(公告)日：2015-08-20

申请号：US14705800

申请日：2015-05-06

Applicant: KiOR, Inc.

Inventor： Bruce Adkins ,  Dennis Stamires ,  Robert Bartek ,  Michael Brady ,  John Hackskaylo

IPC: B01J29/40 ,  C10L1/04 ,  C10G3/00 ,  B01J37/28 ,  B01J37/00

CPC classification number: B01J29/40 ,  B01J37/0009 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/42 ,  C10G3/49 ,  C10G3/57 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02P30/20

Abstract: Catalyst compositions comprising a phosphorous-promoted ZSM-5 component and a silica-containing binder, and methods for making and using same, are disclosed. More, specifically, processes for making a catalyst for biomass conversion are provided. The process includes: treating a ZSM-5 zeolite with a phosphorous-containing compound to form a phosphorous-promoted ZSM-5 component; preparing a slurry comprising the phosphorous-promoted ZSM-5 component and a silica-containing binder; and shaping the slurry into shaped bodes. Such catalysts can be used for the Thermocatalytic conversion of particulate biomass to liquid products such as bio-oil, resulting in higher bio-oil yields and lower coke than conventional catalysts.

Abstract translation: 公开了包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的催化剂组合物及其制备和使用方法。 更具体地，提供了用于生产转化催化剂的方法。 该方法包括：用含磷化合物处理ZSM-5沸石以形成磷促进的ZSM-5组分; 制备包含磷促进的ZSM-5组分和含二氧化硅的粘合剂的浆料; 并将浆料成型成成形的状态。 这种催化剂可用于将颗粒生物质转化为液体产物如生物油的热催化转化，导致比常规催化剂更高的生物油产率和更低的焦炭。

公开(公告)号：US20150027871A1

公开(公告)日：2015-01-29

申请号：US14378749

申请日：2013-02-15

Applicant: KiOR, Inc.

Inventor： Dennis Stamires ,  Michael Brady

IPC: B01J29/40 ,  C10L1/00 ,  C10G1/00 ,  C10B53/02 ,  B01J21/16

CPC classification number: B01J29/40 ,  B01J21/16 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7057 ,  B01J29/7615 ,  B01J29/7815 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J2029/062 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/38 ,  B01J2229/42 ,  C01B39/38 ,  C10B53/02 ,  C10G1/002 ,  C10G3/49 ,  C10L1/00 ,  C10L2200/0469 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

Abstract: A process for making a catalytic system for converting solid biomass into fuel of specialty chemical products is disclosed. The process includes preparing a slurry precursor mixture by mixing an aluminosilicate clay material with a pore regulating agent and optionally a binder, shaping the mixture into shaped bodies; removing the pore regulating agent to form porous shaped bodies, preparing an aqueous reaction mixture comprising the porous shaped bodies in presence of a zeolite seeding material, and thermally treating the aqueous reaction mixture to form the catalyst system. The catalyst system can comprise, for example, a MFI-type zeolite.

Abstract translation: 公开了一种制备用于将固体生物质转化为特种化学产品的燃料的催化体系的方法。 该方法包括通过将铝硅酸盐粘土材料与孔调节剂和任选的粘合剂混合来制备浆料前体混合物，将混合物成形为成型体; 除去孔调节剂以形成多孔成形体，在沸石种子材料存在下制备包含多孔成形体的水性反应混合物，并热处理含水反应混合物以形成催化剂体系。 催化剂体系可以包括例如MFI型沸石。